Ferrous phosphate surface precipitates resulting from the reduction of intragrain 6-line ferrihydrite by Shewanella oneidensis MR-1

The reductive biotransformation of 6-line ferrihydrite located within porous silica (intragrain ferrihydrite) by Shewanella oneidensis MR-1 was investigated and compared to the behavior of 6-line ferrihydrite in suspension (free ferrihydrite). The effect of buffer type (PIPES and NaHCO₃), phosphate (P), and an electron shuttle (AQDS) on the extent of reduction and formation of Fe(II) secondary phases was investigated under anoxic conditions. Electron microscopy and micro X-ray diffraction were applied to evaluate the morphology and mineralogy of the biogenic precipitates and to study the distribution of microorganisms on the surface of porous silica after bioreduction. Kinetic reduction experiments with free and intragrain ferrihydrite revealed contrasting behavior with respect to the buffer and presence of P. The overall amount of intragrain ferrihydrite reduction was less than that of free ferrihydrite [at 5 mmol L⁻¹ Fe(III)_T]. Reductive mineralization was not observed in the intragrain ferrihydrite incubations without P, and all biogenic Fe(II) concentrated in the aqueous phase. Irrespective of buffer and AQDS addition, rosettes of Fe(II) phosphate of approximate 20-30 μm size were observed on porous silica when P was present. The rosettes grew not only on the silica surface but also within it, forming a coherent spherical structure. These precipitates were well colonized by microorganisms and contained extracellular materials at the end of incubation. Microbial extracellular polymeric substances may have adsorbed Fe(II) promoting Fe(II) phosphate nucleation with subsequent crystal growth proceeding in different directions from a common center.     

土壤铅含量高光谱遥感反演中波段选择方法研究

利用高光谱遥感数据进行了南京郊外土壤重金属元素铅的含量反演,由于高光谱数据波段众多,波段选择或变换至关重要。比较了基于次贪婪的前向选择模型的最小角度拟合和基于遗传算法进行波段选择的最小二乘和偏最小二乘拟合,结果发现基于遗传算法的偏最小二乘反演结果优于全波段的偏最小二乘,表明波段选择在高光谱反演重金属中是有益的。尽管采取了波段选择后的各方法在反演时均能达到70%以上的训练精度,但因遗传算法搜索的解空间范围更宽广,使得基于遗传算法的偏最小二乘优于前向选择模型的最小角度拟合。最后还比较了基于遗传算法的普通最小二乘和偏最小二乘拟合,结果表明偏最小二乘更优,因此在高光谱反演重金属含量当中,偏最小二乘精度较高,而在波段选择方法中,遗传算法更优。     

Investigation of the sulfur speciation during chalcopyrite leaching by moderate thermophile Sulfobacillus thermosulfidooxidans

The surface sulfur speciation of chalcopyrite leached by moderately thermophilic Sulfobacillus thermosulfidooxidans was investigated by employing scanning electron microscopy (SEM), X-ray diffraction (XRD) and sulfur K-edge X-ray absorption near edge structure spectroscopy (XANES), accompanying with the leaching behavior elucidation. Leaching experiment showed that there was an optimum range of the redox potential for chalcopyrite dissolution. Leaching products were found accumulating during the leaching process, which might be jarosite according to the XRD analysis. The sulfur K-edge spectra indicated that chalcocite might be the intermediate sulfur compound under a critical redox potential, which might explain the existence of optimum range of the redox potential and provide an evidence for the two-step leaching model of chalcopyrite at low Eh. In addition, the results of sulfur K-edge spectra showed jarosite would accumulate on mineral surface, which might be the main component of the passivation layer.     

Some Fundamental Issues in Dynamic Compression and Tension Tests of Rocks Using Split Hopkinson Pressure Bar

Accurate characterizations of rock strengths under higher loading rates are crucial in many rock engineering applications. The split Hopkinson pressure bar (SHPB) system has been used to quantify the dynamic compressive strength of rocks using the short cylindrical specimen and the dynamic tensile strength of rocks using the Brazilian disc (BD) specimen. However, SHPB is a standard tool that is suitable for metal testing; there are some fundamental issues that need to be carefully visited in applying SHPB to rock dynamic tests. This paper addresses several such critical issues, including the choice of slenderness ratio of the compressive specimen, the effect of friction between the sample and bars on the measured results of compressive strength, the necessity of dynamic force balance on the dynamic BD test, and the validity of using the standard BD equation in the data reduction. We show that with proper experimental designs that address these issues, the dynamic compressive strength and dynamic tensile strength of rocks measured using SHPB are valid and reliable.     

粤东黄冈河大堤洪潮水面线分析推算

黄冈河大堤是一宗典型的独流入海河流防洪、防潮工程,由海堤与内河防洪堤组成,其洪潮水面线推算中起推流量与起推水位的确定,囊括了水文水利分析计算中设计洪水推算、调洪演算、洪水组合分析、潮汐分析、洪潮组合分析、天然河道水面线推算等内容.还包含有汇流历时分析、桥梁(墩)壅水计算等技术难点.这一系列的分析推算工作,及其在黄冈河大堤加固达标工程中的应用,具有示范案例作用,可作为其他沿海地区类似工程的参考.     

防汛异地视频会议系统的安全运行与管理

视频会议系统是在网络技术高速发展背景下产生的又一高科技成果,水利系统依托水利信息网建设了异地视频会议系统,提高了开会效率,节省了办公经费,在防汛抗旱工作中发挥了重要作用.由于视频会议系统应用的及时性、持续性、稳定性等要求非常高,其安全运行与管理至关重要,本文从可靠性保障、安全管理、常见问题处理办法等方面提出了可行的解决方案.     

库鲁克塔格地区古元古界磁铁石英岩型铁矿的发现及找矿意义

通过塔里木地台北缘找矿研究,在库鲁克塔格地区首次发现磁铁石英岩型铁矿床,铁矿赋存于前寒武系兴地塔格群沙依提组地层中。对该矿床含矿岩系特征、岩矿石化学组成、微量元素、稀土元素组成与矿床地质特征的调查与研究表明,鲁克塔格地区古元古界兴地塔格群沙依提组含铁石英岩主要分布于兴地河—辛格尔一带,含铁建造呈东西向展布。在兴地河-辛格尔地区发现含铁石英岩建造出露长约160km,找矿前景可观。     

Hydraulic redistribution in the Inner Mongolia Huangfuchuan basins under different climate scenarios

This paper describes the scaling up to a day scale of the Ryel hour scale model incorporating the process of hydraulic redistribution (HR). The Ryel model was applied to the Inner Mongolia Huangfuchuan basins to analyze transpiration, evaporation and stomatal conductance of Artemisia tridentate, and to indicate the added value of the feedback by comparing simulations with and without incorporating HR. Five climate scenarios were designed based on 40-y continuous climate data from the study area and the response of HR to the different climate scenarios was modeled. Under 1991 climate conditions, cumulative transpiration and evaporation with HR during the growing season were 161.7 mm and 206.14 mm, respectively, compared with transpiration of 140.7 mm and evaporation of 174.2 mm without HR. Under the five different climate change scenarios, HR influenced evaporation more than transpiration. The effect of HR on transpiration, evaporation and stomatal conductance was very different among the scenarios. Inclusion of HR gave rise to the largest increase in transpiration and evaporation under the T2P0 scenario and the smallest under the T2P2 scenario, but transpiration and evaporation decreased under the T0P-2 scenario. Stomatal conductance significantly increased with the inclusion of HR. The model used in this study has potential benefits for incorporating HR into soil processes, such as water movement and mass transfer.     

http://www.sciencedirect.com/science/article/pii/S1674987110000113

<正>Against the current background of global climate change,the study of variations in the soil carbon pool and its controlling factors may aid in the evaluation of soil's role in the mitigation or enhancement of greenhouse gas.This paper studies spatial and temporal variation in the soil carbon pool and their controlling factors in the southern Song-nen Plain in Heilongjiang Province,using soil data collected over two distinct periods by the Multi-purpose Regional Geochemical Survey in 2005—2007, and another soil survey conducted in 1982—1990.The study area is a carbon source of 1479 t/km~2 and in the past 20 years,from the 1980s until 2005.the practical carbon emission from the soil was 0.12 Gt.Temperature,which has been found to be linearly correlated to soil organic carbon,is the dominant climatologic factor controlling soil organic carbon contents.Our study shows that in the relevant area and time period the potential loss of soil organic carbon caused by rising temperatures was 0.10 Gt,the potential soil carbon emission resulting from land-use change was 0.09 Gt,and the combined potential loss of soil carbon(0.19 Gt) caused by warming and land-use change is comparable to that of fossil fuel combustion(0.21 Gt).Due to the time delay in soil carbon pool variation,there is still 0.07 Gt in the potential emission caused by warming and land-use change that will be gradually released in the future.     

南京市居民网络消费的影响因素及空间特征简

在互联网络和信息技术的影响下,网上购物、团购等基于电子商务平台的网络消费方式得到极大发展,网络消费逐渐成为城市居民消费选择的重要方式,网络消费市场得到了较快的发展。同时,由于居民社会阶层的差别及相应居住空间的分异,导致网络消费呈现出不同的空间特征,并且对实体空间产生不同程度的影响。通过对南京居民网络消费情况的问卷调查,分析个人社会经济属性、住房状况、交通方式以及移动网络使用等体现居民社会阶层状况的要素对居民网络消费选择的影响,进而分析居民网络消费的空间分布特征,研究城市不同空间的网络消费构成和网络消费商品类型特征,在此基础上分析不同空间网络消费对交通出行和实体商业空间结构的影响程度。