Overtopping Discharge of Wind-Waves on Simple Slope Dikes

An empirical formula for estimating the overtopping discharge of wind-waves on a smooth-impermeable-simple slope dyke is derived through model tests in this paper, it can be adopted by related design departments in the determination of the crest elevation of the dyke.     

渤海湾海河口区耗氧有机物的分布特征

渤海湾海河口区是北京、天津二大城市工业及生活污水排放入海处，是一比较典型的海域。1972年以来曾对渤海湾进行过综合性的环境污染调查和研究，但由于受调查范围和项目的限制，对河口区特别是大沽口、北塘口区有机污染物的迁移转化研究甚少，尚不足以就有机污染对河口生态环境的潜在影响作出科学判断。目前，有机污染已成为海河口区特别是其附近大城市的主要污染问题之一。本文以化学耗氧量(COD)、生物耗氧量(BOD5)、溶解氧(DO)等项目作为耗氧有机物污染程度评价的主要指标(还有氮、磷、本集另有专文讨论)，对海河口区有机污染物的迁移、转化及生态效应进行了调查研究，为有机污染评价提供数据并作初步探讨。     

Molecular identification of bloom-forming species Phaeocystis globosa (Pryninesiophyta) and its dispersal based on rDNA ITS sequence analysis

The colony-forming Phaeocystis species are causative agents of dense bloom occurrences in coastal waters worldwide. It is difficult to separate them because of the different morphologies associated with their colonial stages. In this study we applied molecular approaches to analyze the genetic variation of Phaeocystis globosa and Phaeocystis pouchetii from several geographic regions, and to assist in tracing the dispersal of bloom-forming Phaeocystis species in coastal waters of China. The sequences of the internal transcribed spacers (ITS1 and ITS2) of rDNA and the 5.8S ribosomal RNA gene of Phaeocystis strains were determined. Sequence comparison shows that P.globosa was the most divergent to P. pouchetii, exhibiting sequence divergence higher than 0.08. However, lower genetic divergences existed between strains of P.globosa. The sequence comparison of the Phaeocystis rDNA ITS clearly shows that the species isolated from the southeast coast of China is identified as P.globosa rather than P. cf. pouchetii or other species. Furthermore, the significance of rDNA variation in distinct global populations of P.globosa suggested it might have had sufficient time to accumulate detectable mutations at the rDNA locus, supporting the hypothesis of ancient dispersal of P.globosa to many areas, meaning that P.globosa blooms in the coastal waters of China are endemic rather than a newly introduced species or a foreign source. Finally, based on the high divergent region of rDNA ITS, a pair of species-specific primers for P.globosa were designed, they could be useful to detect the presence of this species in mixed plankton assemblages or flagellate stages that are recognized with diffculties by means of conventional microscopy.     

魁蚶线粒体16S rRNA和COI基因片段序列测定及其应用前景

魁蚶（Ｓｃａｐｈａｒｃａｂｒｏｕｇｈｔｏｎｉｉ）是蚶科贝类的一种大型经济种类，主要分布于我国、日本和朝鲜半岛及俄罗斯东南部沿海。在我国，主要分布于辽宁、河北和山东沿海，生活在３～５０ｍ（多为２０～３０ｍ）水深的软泥或泥沙质海底，是我国北方沿海重要的经济贝类之一。但但有有关关其其自自然然群群体体的的遗遗传传变变异异及及群群体体间间遗遗传传分分化化等等方方面面的的研研究究不不多多 ;;同同时时，，作作者者和和日日本本研研究究者者发发现现，，中中国国、、韩韩国国和和日日本本魁魁蚶蚶群群体体在在形形态态和…     

生物制氢研究进展

目前, 世界上利用的能源90%以上都是“化石能源”(如石油、煤炭和天然气等)。随着人类不断利用这些不可再生的“化石能源”, 它将会逐渐枯竭, 且其燃烧形成的产物(如CO2和SO2等)造成的严重环境污染(如温室效应和酸雨), 也有害于人类健康。因此, 人类正面临着能源紧缺和环境污染的双重压力。为满足能源需求量日益增长和环境保护的需要, 我们必须寻找环保型的可再生能源来替代“化石能源” 以满足人类对能源的需求。 在各种可再生能源中氢能将有可能替代“化石能源”,成为未来能源利用的主要形式。氢能具有许多优点:①氢能燃烧时只生成水, 不产生任何污染物, 甚至连CO2也不会产生, 实现真正的“零污染” 和“零排放”;②氢能的能量密度高, 放热高达122 kJ/g, 是焦炭放热的4.5倍, 汽油的2.68倍;③氢能可经济有效的输送和储存, 可以利用已有的天然气管道输送, 输送成本低, 甚至优于输电, 因为输送氢能不会产生如电能输送过程中所产生的能量损耗;氢能的存储也比较简便, 其中储氢合金材料就是一种非常理想的储氢方法, 该方法储氢能力强、运输方便、操作容易, 且安全可靠。在利用储氢合金进行储氢时, 还可用以进行制冷或采暖(Kulkova et al., 2006), 因为储氢材料在吸氢时放热, 在放氢时吸热。正因为氢能具有如此多的优点, 许多大的跨国公司开始对制氢技术高度关注, 如主要汽车制造商(通用、福特、戴姆勒-克莱斯勒等)对开发以氢能作为燃料的汽车投入大量的人力和物力;宝马公司从20世纪70年代就开始研制以氢能为能源的汽车, 宝马公司现在已拥有了时速达240km的氢能汽车(Munro,2003)。同时, 一些发达国家的科研院所的科学家们对氢能的制备方法、制氢机制以及提高产氢量等进行了大量的研究。     

围垦的社会经济价值及其对海洋环境影响的评估

从围垦滩涂与保护湿地的关系着手,针对浙江省的滩涂围垦现状,讨论了沿海滩涂实施围垦工程所创造的社会经济价值,分析了湿地生态的环境特征及其对自然界的贡献,指出并探讨了海岸带资源开发与海岸工程建设所带来的问题,从湿地保护和经济可持续发展的角度提出了相关的建议。     

Pb2+对青蛤的急性毒性及对其血淋巴液中免疫相关酶活性的影响

采用静态急性毒性实验研究了重金属Pb~(2+)对青蛤(Cyclina sinensis)的生物急性毒性效应,测定了在96 h Pb~(2+)半致死浓度的1/10(TC组)和1/100(SC组)两个浓度胁迫下,血淋巴液中酸性磷酸酶(ACP)、碱性磷酸酶(AKP)和溶菌酶(LSZ)活性的变化。结果显示:Pb~(2+)的96 h LC50为7.938 mg/L; SC组ACP活性表现为诱导-抑制趋势,除4 d外均与对照组差异显著(P0.05), TC组为抑制趋势,为3个组中的最低,与对照组差异显著(P0.05);实验组SC组和TC组的AKP、LSZ活性均表现为前期为诱导中后期受抑制的趋势,与对照组差异显著(P0.05),且TC组活性始终低于SC组,表现出Pb~(2+)的胁迫浓度越高酶活性受到的抑制作用越大。以上结果表明,重金属Pb~(2+)对青蛤的毒性级别为高毒级,能造成青蛤免疫相关酶的活性受到抑制,影响青蛤的免疫能力,而且这种抑制作用随着环境中Pb~(2+)浓度增加而增加。     

Sediment–water interactions of natural oestrogens under estuarine conditions

The natural human female hormones oestrone and 17β-oestradiol have been implicated in the disruption of endocrine systems in some wildlife adjacent to sewage effluents. The sorption behaviour of these two compounds under estuarine conditions was studied by spiking either 2.55 μg of oestrone or 2.65 μg of 17β-oestradiol in kinetic experiments. In equilibrium experiments, 3 ng of oestrone or 3.2 ng of 17β-oestradiol was added in each of the centrifuge tubes. Sorption onto sediment particles was relatively slow, with sorption equilibrium being reached in about 70 and 170 h for oestrone and 17β-oestradiol, respectively. The effects of a variety of environmental parameters on sorption were studied including salinity, sediment concentration (SC), the presence of a third phase, particle size and, also, surfactant concentrations. Results show that although salinity did not induce any statistically significant effect on the sorption of 17β-oestradiol, it did statistically enhance the sorption of oestrone, and a salting constant of 0.3 l mol⁻¹ was derived. The partition coefficient for both compounds decreased with increasing sediment concentration, a phenomenon that has been widely reported and attributed to the presence of colloids (which could enhance dissolved concentrations). In this paper, the true partition coefficients for sediment particles (K_p^true) and colloidal particles (K_c^true) have been calculated, and a K_p^true value of 141 and 102 ml g⁻¹ was obtained for oestrone and 17β-oestradiol, respectively. In addition, K_c^true values for oestrone (222×10² ml g⁻¹) and 17β-oestradiol (135×10² ml g⁻¹) were two orders of magnitude higher than their respective K_p^true values, suggesting that the colloidal particles are significantly stronger sorbents for natural oestrogens than sediment particles. Particles of different sizes were found to have different partition coefficients due to the strong relationships between partition coefficients for the two compounds and particulate organic carbon (POC) contents and specific surface areas (SSAs). The presence of a surfactant was shown to reduce the partition coefficients for the two compounds, although its concentrations being used were higher than those normally found in the natural environment.     

南黄海及相邻陆区松散沉积层磁性地层的研究

本文通过研究区5个钻孔松散沉积岩心磁性地层的划分对比,获知布容与松山极性带的界线,南黄海和陆区北部位于80.0—99.5m。陆区的南部此界线于270.4m深处。松山和高斯极性带的界线,海区未揭露到,其沉积起始时间都小于1.7Ma。而陆区的南、北部分别位于117m和328.2m。高斯和吉尔伯特极性带的界线,陆区北部为140m,而南部区为460.15m。沉积起始时间为3.4Ma。吉尔伯特底界仅北部陆区所揭示,为190.5m。松散沉积层与下伏白垩纪(?)石灰岩接触面位于400.35m,沉积起始时间约17.0Ma。     

常压法合成Methomyl的研究

提出一种合成Methomyl的改良法。该方法的特点是反应可在常压下进行。对常压反应的优宜条件作了系统研究,并讨论了反应机理。