On the Mechanism of Air Pollutant Removal in Two-Dimensional Idealized Street Canyons: A Large-Eddy Simulation Approach

Flow resistance, ventilation, and pollutant removal for idealized two-dimensional (2D) street canyons of different building-height to street-width (aspect) ratios $AR$ are examined using the friction factor $f$ , air exchange rate (ACH), and pollutant exchange rate (PCH), respectively, calculated by large-eddy simulation (LES). The flows are basically classified into three characteristic regimes, namely isolated roughness, wake interference, and skimming flow, as functions of the aspect ratios. The LES results are validated by various experimental and numerical datasets available in the literature. The friction factor increases with decreasing aspect ratio and reaches a peak at $AR = 0.1$ in the isolated roughness regime and decreases thereafter. As with the friction factor, the ACH increases with decreasing aspect ratio in the wake interference and skimming flow regimes, signifying the improved aged air removal for a wider street canyon. The PCH exhibits a behaviour different from its ACH counterpart in the range of aspect ratios tested. Pollutants are most effectively removed from the street canyon with $AR = 0.5$ . However, a minimum of PCH is found nearby at $AR = 0.3$ , at which the pollutant removal is sharply weakened. Besides, the ACH and PCH are partitioned into the mean and turbulent components to compare their relative contributions. In line with our earlier Reynolds-averaged Navier–Stokes calculations (Liu et al., Atmos Environ 45:4763–4769, 2011), the current LES shows that the turbulent components contribute more to both ACH and PCH, consistently demonstrating the importance of atmospheric turbulence in the ventilation and pollutant removal for urban areas.     

The effect of seafloor topography in the Southern Ocean on tabular iceberg drifting and grounding

Antarctic tabular icebergs are important active components in the ice sheet-ice shelf-ocean system. Seafloor topography is the key factor that affects the drifting and grounding of icebergs, but it has not been fully investigated. This study analyzes the impact of seafloor topography on the drifting and grounding of Antarctic tabular icebergs using Bedmap-2 datasets and iceberg route tracking data from Brigham Young University. The results highlight the following points. (1) The quantitative distributions of iceberg grounding events and the tracking points of grounded icebergs are mainly affected by iceberg draft and reach their peak values in sea water with depths between 200 m and 300 m. The peak tracking point number and linear velocity of free-drifting icebergs are found in the Antarctic Slope Front (water depth of approximately 500 m). (2) The area of possible grounding regions of small-scale icebergs calved from ice shelf fronts accounts for 28% of the sea area at water depths less than 2000 m outside the Antarctic coastline periphery (3.62 million km²). Their spatial distribution is mainly around East Antarctica and the Antarctic Peninsula. The area of possible grounding regions of large tabular icebergs with long axes larger than 18.5 km (in water depths of less than 800 m) accounts for 74% of the sea area. (3) The iceberg drifting velocity is positively correlated with ocean depth in areas where the depth is less than 2000 m (R=0.85, P<0.01). This result confirms the effect of water depth variations induced by seafloor topography fluctuations on iceberg drifting velocity.     

容量法测定水样中硫酸根

本文对EDTA滴定过量Pb间接测定SO_4~(2-)的方法作了改进。加入乙醇抑制PbSO_4沉淀的溶解,使滴定不需分离沉淀而直接进行。用六次甲基四胺调节控制pH为5.2—5.4,可避免大量共存Ca~(2+)、Mg~(2+)的干扰。改进后的方法简单、快速,准确度和精密度均好,可适用SO_4~(2-)含量高于1mg/L的天然水分析。     

Carbon dioxide emission reduction quota allocation study on Chinese provinces based on two-stage Shapley information entropy model

Chinese central government made a commitment to achieve a 40–45% reduction in carbon dioxide (CO₂) per unit of GDP by 2020 compared with 2005. This targeted reduction was allocated averagely among all the provinces rather than individually according to different situations of each province. Though some research has been done regarding this rough allocation, two shortcomings in previous studies exist: Firstly, CO₂ marginal abatement cost (MAC) has been ignored as one of the CO₂ emission reduction allocation indexes. Secondly, either subjective or objective method has been used rather than comprehensively of both subjective and objective method to calculate the weight of each index in the previous studies. In order to fill the gaps, this paper builds a two-stage Shapley information entropy model to allocate CO₂ emission reduction quota among the Chinese provinces based on the equity and efficiency principles. Afterward, three CO₂ emission reduction quota allocation scenarios have been proposed. The results show that the CO₂ MAC is an indispensable index in CO₂ emission reduction quota allocation, because its value of CO₂ Shapley information entropy is the highest among five indexes. CO₂ emission reduction quota of lower-MAC provinces should be allocated larger, while the quota of higher-MAC provinces should be allocated smaller. Therefore, two suggested policies have been proposed: First, differential CO₂ emission reduction quota allocation should be proposed. Second, synergetic development should be promoted.     

Determination of the thicknesses of oil films in micro- and nano-pores in tight oil sands: an example from the southern Songliao Basin,NE China

An experimental method of field-emission environmental scanning electron microscope (ESEM) coupled with the energy dispersive spectrum (EDS) to determine the thickness of oil films in the micro- and nano-pores of tight oil sands was proposed to overcome the limitations of current methods. First, we got the data of the detection range volumes, elemental mass percentages, and elemental atomic percentages using the EDS, and then calculated the volumes of oil films in the detection range according to the elemental mass percentages and the elemental atomic percentages of carbon. After that, we calculated the surface areas of oil films using the pore size data (lengths, widths, and depths) detected by ESEM. The thicknesses of oil films in the pores equaled the volumes divided by the surface areas. An analysis of tight oil samples from the Quan 4 Segment of in the southern Songliao Basin, NE China confirmed that the oil in the micro- and nano-pores had two main forms: oil films and oil droplets. The thicknesses of the oil films ranged from about 400 nm to 2 μm, while the thicknesses of the oil droplets ranged from about 200 to 700 nm.     

天然钛榴石的穆斯堡尔谱及晶体化学分析

本文收集了一组钛榴石样品,作了穆斯堡尔谱和化学分析。采用各对应双峰等值限制拟合。拟合结果,统计误差X~2均较小。文中还分析了钛榴石结构的阳离子占位情况,并对其五对双峰谱指派如下:Fe~(3+)在[Y]位和(Z)位,Fe~(2+)在{X}和[Y]位,而另一对双峰指派为Fe~(2+){X}→Fe~(3+)(Z)的电荷离域。从化学分析和穆斯堡尔谱数据求出二种方法Fe~(2+)/∑Fe的差值,说明钛榴石中有Ti~(3+)的存在,用此简便方法估算了Ti~(3+)的含量,得出了四面体中阳离子的占位择优为Fe~(3+)>(Al~(3+),Ti~(4+))的结论。     

Results from the Big Spring basin water quality monitoring and demonstration projects,Iowa, USA

Agricultural practices, hydrology, and water quality of the 267-km² Big Spring groundwater drainage basin in Clayton County, Iowa, have been monitored since 1981. Land use is agricultural; nitrate-nitrogen (-N) and herbicides are the resulting contaminants in groundwater and surface water. Ordovician Galena Group carbonate rocks comprise the main aquifer in the basin. Recharge to this karstic aquifer is by infiltration, augmented by sinkhole-captured runoff. Groundwater is discharged at Big Spring, where quantity and quality of the discharge are monitored. Monitoring has shown a threefold increase in groundwater nitrate-N concentrations from the 1960s to the early 1980s. The nitrate-N discharged from the basin typically is equivalent to over one-third of the nitrogen fertilizer applied, with larger losses during wetter years. Atrazine is present in groundwater all year; however, contaminant concentrations in the groundwater respond directly to recharge events, and unique chemical signatures of infiltration versus runoff recharge are detectable in the discharge from Big Spring. Education and demonstration efforts have reduced nitrogen fertilizer application rates by one-third since 1981. Relating declines in nitrate and pesticide concentrations to inputs of nitrogen fertilizer and pesticides at Big Spring is problematic. Annual recharge has varied five-fold during monitoring, overshadowing any water-quality improvements resulting from incrementally decreased inputs. Electronic Publication     

阳原盆地化稍营地区断层主要活动时期的研究

研究一个地区断层主要活动时期是了解地壳构造运动或断层发育历史的基础。本文仍沿用了传统研究法,并将同位素法和石英形貌法测年与显微构造分析法引进到研究断层主要活动时期的工作中,取得了能相互映正的结果,最后确定阳原盆地化稍营地区的断层经历过:元古代前;燕山期;6～9千万年;上新世——早更新世和最后一次较强烈活动在20—30万年以前等五次主要活动时期。     

Application of Monte-Carlo statistical experiments in design of ocean engineering——Estimating the parameters, models and probabilities

Recently, some results have been acquired with the Monte- Carlo statistical experiments in the design of ocean en gineering. The results show that Monte-Carlo statistical experiments can be widely used in estimating the parameters of wave statistical distributions, checking the probability model of the long- term wave extreme value distribution under a typhoon condition and calculating the failure probability of the ocean platforms.