Age and tectonostratigraphic significance of the Upper Carboniferous series in the basement of the Andean Frontal Cordillera: Geodynamic implications

The age and tectonosedimentary environment of the Palaeozoic sediments on the Frontal Cordillera is not well known and earlier studies have been unable to satisfactorily explain the geological history of the basement of the Andes.In the vicinity of the old Castaño Viejo mine crop out various levels of partially metamorphosed microbialite limestones, which alternate with thin marly–lutitic interstrata. These levels contain abundant palynomorph remains, which allow the series to be dated as Silurian–Devonian. These data, together with the presence of warm climate fossils, lend support to the hypothesis of a major allochtony of the Chilenia Terrane (of which the Frontal Cordillera formed part), relative to the Cuyania Terrane (which included the Precordillera), prior to their amalgamation.Upper Carboniferous palynomorphs found during this study occur in association with resedimented palynomorphs and chitinozoa, of possible Devonian age. This demonstrates the equivalence of both fossiliferous series and their location within the upper part of the Upper Carboniferous Agua Negra Fm. The Silurian–Devonian elements, deformed during a phase prior to the Gondwanic orogeny, were eroded and transported to the foreland basin during the Upper Carboniferous.The palynomorph associations found in all samples correspond to the Ancistrospora palynological zone and to the Raistrickia densa–Convolutispora muriornata Biozone, which are indicative of Upper Carboniferous times. Characteristic forms such as Ancistrospora verrucosa and C. muriornata, both indicative of an Upper Carboniferous age, were found in samples from the Castaño Viejo area.Earlier interpretations of the Frontal Cordillera attributing the sedimentation to a palaeo-latitude at some distance from Gondwana, were based on the presence of Silurian–Devonian hot water stromatolithic limestones. Our results suggest that Cuyania and Chilenia were not necessarily separated by a great distance before their amalgamation. This in turn means that a large ocean was not necessarily consumed in the process.     

Relationships Between Petrophysical and Mechanical Properties of Certain Calcarenites Used in Building

Mendicino calcarenite was once widely used in traditional constructions by Italy’s foremost stonemasons’ schools. This paper provides a complete physico-mechanical characterization in order to improve understanding of strength and durability properties and so apply that knowledge to conservation and new construction. Stone samples from three lithofacies are taken from the following quarries of Cosenza province: Scannelle in Malito; Cannataro in Carolei; Albanese in San Lucido. Samples are subjected to: X-ray diffraction, mercury intrusion porosimetry, ultrasonic pulse velocity, capillary water absorption, uniaxial compressive, flexural, point load tests with respect to the X, Y, Z axes. Malito samples exhibit creamy colour, better hydric behaviour, low open porosity, reduced water absorption capability, isotropic hydric behaviour, higher fossil abundance (both in number and size) than the lithofacies taken from Carolei and San Lucido, which exhibit whitish colour, greater strength and more homogeneous texture. The greater compactness of Carolei and San Lucido samples can be ascribed to homogeneity and low porosity and their better mechanical properties to textural features. Anisotropy plays an important role. Placing stone samples along the Z axis prevents water intrusion, and improves mechanical strength. Isotropy and compact and heterogeneous fabric in stones result in higher strength and lower water absorption.

     

Observer presence may alter the behaviour of reef fishes associated with coral colonies

Although underwater visual census (UVC) is the most frequently used technique for quantifying reef fish assemblages, remote video analysis has been gaining attention as a potential alternative. In the South Atlantic Ocean, Millepora spp. (class Hydrozoa) are the only branching coral species; however, little is known about the ecological role that they play for reef fish communities. We compared these two observation methods (remote video and UVC) to estimate reef fish abundance and species richness associated with colonies of the fire‐coral Millepora alcicornis at Tamandaré Reefs, Northeast Brazil. Additionally, the two different techniques were used to compare species behaviour in association with fire‐corals in order to examine the biases associated with each technique and provide useful information for behavioural ecologists studying fish–coral associations. There were no differences in reef fish abundance or species richness sampled by remote video or UVC. However, a significant difference in the behaviour of associated fish was recorded between the two methods. In the presence of a diver carrying out a UVC, fish were observed spending more time sheltered amongst the coral branches compared with passively swimming on coral colonies with the remote video technique. Specifically, on the remote video recordings agonistic interactions between fish and passive swimming accounted for 33.3% and 22.2% of the census time, respectively. By comparison, when observed by a diver fish spent 34.8% of their time sheltering amongst the coral branches. We demonstrate that both techniques are similarly effective for recording fish abundance and species richness associated with fire‐corals. However, differences were observed in the ability of each method to detect the behaviour of coral‐associated fishes. Our findings show that behavioural ecologists studying complex fish–coral associations need to ensure that their aims are clearly defined and that they choose the most appropriate technique for their study in order to minimize methodological biases.     

Onshore Neogene stratigraphy in the North of the Alboran Sea (Betic Internal Zones): Paleogeographic implications

The Neogene is the period in which the Betic Cordillera, the Rif, and the Alboran Sea acquired their present configuration. The Neogene sediments of the Betic Internal Zones (located directly to the North of the Alboran Sea) show the effects of important periods of deformation. Deposition was clearly controlled by tectonics. Therefore the generation, evolution, and total or partial destruction of basins and the formation of new, often superimposed, basins are common phenomena, according to the locations of the basins in the Betic Cordillera and to the different geodynamic situations.     

Keck observations of the 2002-2003 jovian ring plane crossing

We present new observations of Jupiter's ring system at a wavelength of 2.2 μm obtained with the 10-m W.M. Keck telescopes on three nights during a ring plane crossing: UT 19 December 2002, and 22 and 26 January 2003. We used conventional imaging, plus adaptive optics on the last night. Here we present detailed radial profiles of the main ring, halo and gossamer rings, and interpret the data together with information extracted from radio observations of Jupiter's synchrotron radiation. The main ring is confined to a 800-km-wide annulus between 128,200 and 129,000 km, with a ∼5000 km extension on the inside. The normal optical depth is 8×¹⁰⁻⁶, 15% of which is provided by bodies with radii a?5 cm. These bodies are as red as Metis. Half the optical depth, τ≈4×¹⁰⁻⁶, is attributed to micron-sized dust, and the remaining τ≈3×¹⁰⁻⁶ to grains tens to hundreds of μm in size. The inward extension consists of micron-sized (a?10 μm) dust, which probably migrates inward under Poynting-Robertson drag. The inner limit of this extension falls near the 3:2 Lorentz resonance (at orbital radius r=122,400 km), and coincides with the outer limit of the halo. The gossamer rings appear to be radially confined, rather than broad sheets of material. The Amalthea ring is triangularly shaped, with a steep outer dropoff over ∼5000 km, extending a few 1000 km beyond the orbit of Amalthea, and a more gradual inner dropoff over 15,000-20,000 km. The inner edge is near the location of the synchronous orbit. The optical depth in the Amalthea ring is ∼5×¹⁰⁻⁷, up to 20% of which is comprised of macroscopic material. The optical depth in the Thebe ring is a factor of 3 smaller.     

Methods for estimating the velocities of the Brazil Current in the pre-salt reservoir area off southeast Brazil (23∘ S–26∘ S)

The Brazil Current (BC) is likely the least observed and investigated subtropical western boundary current in the world. This study proposes a simple and systematic methodology to estimate quasi-synoptic cross-sectional speeds of the BC within the Santos Basin (23^° S–26^° S) based on the dynamic method using several combinations of data: Conductivity, temperature, and depth (CTD), temperature profiles, CTD and vessel-mounted Acoustic Doppler Current Profiler (VMADCP), and temperature profiles and VMADCP. All of the geostrophic estimates agree well with lowered Acoustic Doppler Current Profiler (LADCP) velocity observations and yield volume transports of -5.56 ±1.31 and 2.50 ±1.01 Sv for the BC and the Intermediate Western Boundary Current (IWBC), respectively. The LADCP data revealed that the BC flows southwestward and is ～100 km wide, 500 m deep, and has a volume transport of approximately -5.75 ±1.53 Sv and a maximum speed of 0.59 m s^?1. Underneath the BC, the IWBC flows northeastward and has a vertical extent of approximately 1,300 m, a width of ～60 km, a maximum velocity of ～0.22 m s?¹, and a volume transport of 4.11 ± 2.01 Sv. Our analysis indicates that in the absence of the observed velocities, the isopycnal (σ ₀) of 26.82 kg m^?3 (～500 dbar) is an adequate level of no motion for use in geostrophic calculations. Additionally, a simple linear relationship between the temperature and the specific volume anomaly can be used for a reliable first estimate of the BC-IWBC system in temperature-only transects.     

First Multi‐Isotopic (Pb‐Nd‐Sr‐Zn‐Cu‐Fe) Characterisation of Dust Reference Materials (ATD and BCR‐723): A Multi‐Column Chromatographic Method Optimised to Trace Mineral and Anthropogenic Dust Sources

Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.     

Efficacy of Coagulants and Ballast Compounds in Removal of Cyanobacteria (<Emphasis Type="Italic">Microcystis</Emphasis>) from Water of the Tropical Lagoon Jacarepaguá (Rio de Janeiro,Brazil)

Eutrophication is considered the most important water quality problem in freshwaters and coastal waters worldwide promoting frequent occurrence of blooms of potentially toxic cyanobacteria. Removal of cyanobacteria from the water column using a combination of coagulant and ballast is a promising technique for mitigation and an alternative to the use of algaecides. In laboratory, we tested experimentally the efficiency of two coagulants, polyaluminium chloride (PAC) and chitosan (made of shrimp shells), alone and combined with two ballasts: red soil (RS) and the own lagoon sediment, to remove natural populations of cyanobacteria, from an urban brackish coastal lagoon. PAC was a very effective coagulant when applied at low doses (≤8 mg Al L^?1) and settled the cyanobacteria, while at high doses (≥16 mg Al L^?1) large flocks aggregated in the top of test tubes. In contrast, chitosan was not able to form flocks, even in high doses (>16 mg L^?1) and did not efficiently settle down cyanobacteria when combined with ballast. The RS itself removed 33–47 % of the cyanobacteria. This removal was strongly enhanced when combined with PAC in a dose-dependent matter; 8 mg Al L^?1 was considered the best dose to be applied. The lagoon sediment alone did not promote any settling of cyanobacteria but removal was high when combined with PAC. Combined coagulant and ballast seems a very efficient, cheap, fast and safe curative measure to lessen the harmful cyanobacteria bloom nuisance in periods when particularly needed, such as around the 2016 Olympics in Jacarepaguá Lagoon.     

Holocene climate variability as derived from alkenone sea surface temperature and coupled ocean-atmosphere model experiments

Holocene climate modes are identified by the statistical analysis of reconstructed sea surface temperatures (SSTs) from the tropical and North Atlantic regions. The leading mode of Holocene SST variability in the tropical region indicates a rapid warming from the early to mid Holocene followed by a relatively weak warming during the late Holocene. The dominant mode of the North Atlantic region SST captures the transition from relatively warm (cold) conditions in the eastern North Atlantic and the western Mediterranean Sea (the northern Red Sea) to relatively cold (warm) conditions in these regions from the early to late Holocene. This pattern of Holocene SST variability resembles the signature of the Arctic Oscillation/North Atlantic Oscillation (AO/NAO). The second mode of both tropical and North Atlantic regions captures a warming towards the mid Holocene and a subsequent cooling. The dominant modes of Holocene SST variability emphasize enhanced variability around 2300 and 1000 years. The leading mode of the coupled tropical-North Atlantic Holocene SST variability shows that an increase of tropical SST is accompanied by a decrease of SST in the eastern North Atlantic. An analogy with the instrumental period as well as the analysis of a long-term integration of a coupled ocean-atmosphere general circulation model suggest that the AO/NAO is one dominant mode of climate variability at millennial time scales.     

Effects of a melted greenland ice sheet on climate, vegetation, and the cryosphere

This paper investigates the possible implications for the earth-system of a melting of the Greenland ice-sheet. Such a melting is a possible result of increased high latitude temperatures due to increasing anthropogenic greenhouse gas emissions. Using an atmosphere-ocean general circulation model (AOGCM), we investigate the effects of the removal of the ice sheet on atmospheric temperatures, circulation, and precipitation. We find that locally over Greenland, there is a warming associated directly with the altitude change in winter, and the altitude and albedo change in summer. Outside of Greenland, the largest signal is a cooling over the Barents sea in winter. We attribute this cooling to a decrease in poleward heat transport in the region due to changes to the time mean circulation and eddies, and interaction with sea-ice. The simulated climate is used to force a vegetation model and an ice-sheet model. We find that the Greenland climate in the absence of an ice sheet supports the growth of trees in southern Greenland, and grass in central Greenland. We find that the ice sheet is likely to regrow following a melting of the Greenland ice sheet, the subsequent rebound of its bedrock, and a return to present day atmospheric CO₂ concentrations. This regrowth is due to the high altitude bedrock in eastern Greenland which allows the growth of glaciers which develop into an ice sheet.