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31.
An investigation has been made of available data on the saturation state of seawater with respect to calcium carbonate and its possible significance for scale formation on Ocean Thermal Energy Conversion (OTEC) heat exchangers. Pertinent oceanographic data is lacking at or near potential OTEC sites for the calculation of the degree of saturation of seawater with respect to calcium carbonate. Consequently, only “extrapolated” saturation values can be used. These indicate that near surface seawater is probably supersaturated, with respect to the calcium carbonate phases calcite and aragonite, at all potential OTEC sites. The deep seawater that would be brought to the surface at the potential Atlantic Ocean sites is also likely to be supersaturated with respect to calcium carbonate. The deep seawater at the potential Pacific Ocean sites may be slightly undersaturated.The fact that OTEC heat exchangers will be operating in seawater, which is supersaturated with respect to calcium carbonate, means that if nucleation of calcite or aragonite occurs on the heat exchanger surfaces, significant growth rates of calcium carbonate scale may be expected. The potential for calcium carbonate nucleation is highest at cathodic metal surface locations, which are produced as the result of aluminum corrosion in seawater. Consequently, corrosion and scale formation may be closely related. What the possible effects of biofouling may be on this process are not known. 相似文献
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Annual Cycle of Zooplankton Biomass, Abundance and Species Composition in the Neritic Area of the Balearic Sea, Western Mediterranean 总被引:7,自引:0,他引:7
Abstract. Seasonal changes in zooplankton biomass, abundance and species composition were studied at a neritic station in the Balearic Sea between April 1993 and May 1994. Sampling was carried out every 10 days in a zone influenced by the main current circulating through the Mallorca channel. Three main peaks of zooplankton biomass and abundance were observed: (1) at the beginning of summer when the thermocline developed, (2) in autumn when the thermocline broke down, and (3) in early spring. The smaller zooplankton fraction (100–250 μm) comprised on average 32 % of the total biomass and 73 % of total abundance. Copepods were the predominant group (64 % of the total abundance) with Clausocalanus, Oithona and Paracalanus being the most abundant genera. Paracalanus parvus, Clausocalanus furcatus, Acartia clausi, Oithona plumifera, Temora stylifera, Centropages typicus and Oncaea mediterranea were found to be the most important species in the area. Other abundant groups were cladocerans (15 %) and meroplankton larvae (12 %), both of which were particularly numerous during the stratified period. The copepod community was characterized by the above‐cited perennial species, which were abundant during the cycle studied. However, the influence of the hydrological conditions of the Balearic Sea, such as the Atlantic water influx and the physical structure of the water column (stratification and mixing), promoted the observed variability in zooplankton as well as the appearance of characteristic species during the annual cycle. 相似文献
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I. Brandariz P. Castro M. Montes F. Penedo M.E. Sastre de Vicente 《Marine Chemistry》2006,102(3-4):291-299
Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl2 or CaCl2), with binary mixtures of MgCl2 and CaCl2, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl2, while it is increased by the other electrolytes used in this work. 相似文献
36.
Anna Badosa Dani Boix Sandra Brucet Rocío Lpez-Flores Xavier D. Quintana 《Estuarine, Coastal and Shelf Science》2006,66(3-4):513-522
The role of the hydrological regime in the nutrients and zooplankton composition and dynamics has been analysed in five lagoons of La Pletera salt marshes (NE Iberian Peninsula) during a complete hydrological cycle (2002–2003). Two of the lagoons have their origin in the old river mouths while the other three were recently created in the framework of a Life Restoration project. This fact has also allowed us to study the effect of the lagoon age on nutrient and zooplankton composition and dynamics. The salt marsh hydrology is determined by a prolonged period of confinement without water inputs, irregularly interrupted by sudden water inputs due to flooding events (sea storms or intense rainfalls). While the dynamics of oxidized nitrogen compounds in the lagoons depends on the water inputs variability within each hydrological cycle, the internal load of phosphorus, total nitrogen and organic matter is related more to the cumulative mechanisms during the confinement periods. Accumulation processes may be easily related to lagoon age, since old lagoons have higher content of nutrients and organic matter, suggesting that these lagoons progressively accumulate nutrients during the successive confinement events. This is the usual case for most Mediterranean salt marshes without an artificially manipulated water regime. The zooplankton community in La Pletera integrates the effects of both the hydrological regime and the lagoon age since the former determines the temporal pattern of the main zooplankton species and the latter explains differences in composition and structure between old and new lagoons. 相似文献
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The transport pathways of fine sediments (fraction <2 μm) along the Brazilian continental shelf from Ceará to the Amazon River
mouth were studied by means of clay mineral analyses. On the continental shelf southeast of the Amazon mouth, fluctuations
in clay mineral compositions reflect simple mixing between the suspended load of the North Brazil Current and sediment from
several smaller rivers. Previously, clay mineral variations west of the Amazon mouth have been explained by variable settling
velocities of different grain-size classes within the <2 μm fraction or by selective coagulation of individual clay mineral
groups. By contrast, our experiments with river bank samples show that selective coagulation does not occur in Amazon River
sediments. A more appropriate explanation for observed variations in clay mineral composition off the Amazon mouth seems to
be, similarly to that for the shelf between Ceará and the Amazon mouth, a mixing of Amazon sediments with suspended material
of the North Brazil Current. This interpretation is supported by data on clay mineral composition east and south of the Amazon
mouth, showing more affinity to sediments of the North Brazil Current than to the suspended load of the Amazon River. Additionally,
relatively low sedimentation rates and low concentrations of fine-grained sediments on the shelf suggest that high riverine
input by the Amazon River does not overprint the sediments of the North Brazil Current in this region. The strong North Brazil
Current shunts the Amazon suspended load in a north-westerly direction along the north-eastern coast of South America. Hence,
stronger sedimentation of Amazon sediments would occur only west of the river mouth. 相似文献