Mechanisms of shear failure in artificial fractures of sandstone and their implication for models of hydromechanical coupling

Summary Direct shear tests, in which the behaviour of the rock surfaces during shear could be continuously observed, were used to study the shear failure of a profiled and clean discontinuity artificially prepared from natural sandstone. Displacement transducers were used to measure the normal and shear displacements. A series of strain gauges glued on the sides of the upper block provided information on the change of the stress field occurring close to the discontinuities whilst shear displacement increased, and these changes were then compared with the behaviour of the profiled surface. The results of the laboratory tests, the sequence of photographs taken for most of them, and the results conducted with a sample of similar shape made from the same rock material and tested in a rotary shear machine, allowed several stages and mechanisms of failure to be defined: static friction and mobilization of initial shear stiffness; mobilization of sliding; mobilization of brittle fracture; post-peak failure of the teeth; descent of the teeth; gliding and ploughing; commencement of second cycle of shearing. In many respects these stages are similar to those occurring between sliding surfaces of metal and suggest that the analyses developed in tribology may be relevant to the development of constitutive models for predicting the hydromechanical coupled behaviour of a discontinuity with shear displacement. Such models will have to consider these different stages of shear, because the original discontinuity changes its geometry with displacement and is filled with gouge which changes its grain size with displacement.     

Organic matter of the Mulhouse Basin, France: a synthesis

The lower Oligocene evaporite sequence of the Mulhouse Basin (France) contains organic matter-rich marl deposits. These marls display an overall cyclic variation of sedimentation rate, organic carbon content, hydrogen index and selected molecular parameters over a 30 m thick stratigraphic interval. The integration of all sedimentological and geochemical parameters has allowed the reconstruction and characterization of the paleoenvironment of deposition. The marls were deposited in a perennial lake that was at times connected to the sea. Two organic facies end members could be assigned to a lake stage with a marine connection and a lake stage that received dominantly continental water input. The overall stratigraphic variation in the organic matter content is interpreted to reflect the adaptation of the Oligocene flora to the changing paleoclimate and environmental conditions.     

Earth''s earliest continental lithosphere, hydrothermal flux and crustal recycling

The Kaapvaal craton in southern Africa and the Pilbara craton of northwestern Australia are the largest regions on Earth to have retained relatively pristine mid-Archaean rocks (3.0–4.0 Ga).The Kaapvaal craton covers about 1.2×10⁶ km², and varies in lithospheric thickness between 170 and 350 km. At surface, the craton can be subdivided into a number of Archaean sub-domains; some of the subdomains are also well defined at depth, and local variations in tomography of the lithosphere correspond closely with subdomain boundaries at surface.The Archaean history of the Kaapvaal craton spans about 1 Gyr and can be conveniently subdivided into two periods, each of about the same length as the Phanerozoic. The first period, from circa 3.7-3.1 Ga, records the initial separation of the cratonic lithosphere from the asthenosphere, terminating with a major pulse of accretion tectonics between 3.2 and 3.1 Ga, which includes the formation of “paired metamorphic belts”. This period of continental growth can be compared to plate tectonic processes occurring in modern-day oceanic basins. However, the difference is that in the mid-Archaean, these oceanic processes appear to have occurred in shallower water depths than the modern ocean basins. The second period, from circa 3.1-2.6 Ga, records intra-continental and continental-edge processes: continental growth during this period occurred predominantly through a combination of tectonic accretion of crustal fragments and subduction-related igneous processes, in much the same way as has been documented along the margins of the Pacific and Tethys oceans since the Mesozoic.The intra-oceanic processes resulted in small, but deep-rooted continental nucleii; the first separation of this early continental lithosphere could only have occurred when the mean elevation of mid-oceanicridges sank below sea-level. Substantial recycling of continental lithosphere into the mantle must have occurred during this period of Earth history. During the second period, at least two large continental nucleii amalgamated during collisional processes which, together with internal chemical differentiation processes, created the first stable continental landmass. This landmass, which is known to have been substantially bigger than its present outline, may have been part of the Earth's first supercontinent.The oldest known subdomains of the craton include the oceanic-like rocks of the Barberton greenstone belt. The comagmatic mafic-ultramafic rocks (3.48–3.49 Ga) of this belt represent a remnant of very early oceanic-like lithosphere (known as the Jamestown Ophiolite Complex), which was obducted, approximately 45 Ma after its formation, onto a volcanic arc-like terrain by processes similar to those which have emplaced modern ophiolites at convergent margins of Phanerozoic continents. The early metamorphic history, metamorphic mineralogy, oxygen isotope profiles and degree of hydration of the 3.49 Ga Jamestown Ophiolite Complex are similar to present day subseafloor hydrothermal systems. The ratio of ΔMg to ΔSi for hydrothermally altered igneous rocks, both present day and Archaean, are remarkably uniform at −5(±0.9) and the same as that of hydrothermal fluids venting on the present-day East Pacific Rise. This observation suggests that the process of Mg exchange for Si in hydrothermal systems was commonplace throughout Earth's history.The chemistry of vent fluids and hydrothermally altered igneous rocks was combined with an inventory of ³He in the mantle to model Earth's total hydrothermal flux. An Archaean flux (at 3.5 Ga) of about 10 times present day was accompanied by a correspondingly greater abundance of Mg(OH), SiO₂, carbonate and Fe---Mn metasomatic rock types as well as massive sulphides. Assuming a constant column of seawater since the Archaean, the average residence time of seawater in the oceanic crust was 1.65−8.90×10⁵ years in the Archaean. Assuming that ³He and heat are transported from the mantle in silicate melts in uniform proportions, the model stipulates that accretion of oceanic crust decreased from about 3.43−6.5×10¹⁷ g/yr to a present-day rate of 0.52−0.8×10¹⁷ g/yr, with a drop in heat flow from 1.4−2.6×10²⁰ cal/yr to 2.1−3.2×10¹⁹ cal/year.The total amounts of SiO₂ and Fe mobilised in marine hydrothermal systems since 3.5 Ga is less than their masses in the present exosphere reservoirs (crust, hydrosphere, atmosphere). The total amounts of Mg, K, CO₂, Ca and Mn are greater than their respective masses in exosphere reservoirs; therefore, they must have been recycled into mantle. The total mass of recycled hydrothermal components is small compared to the mass of the mantle. The flux of volatiles in hydrothermal systems is large compared to their volume in the atmosphere suggesting that the CO₂ and O₂ budgets of the atmosphere have been influenced by hydrothermal processes, especially in the Archaean.     

Modelling of longterm surface moisture and monitoring vegetation response by satellite in semi-arid Botswana

A daily surface soil moisture model described and tested previously with data from the Phoenix, AR (USA) area, has been applied now to climate data collected in semi-arid Botswana over a multi-year period. The physically based model was calibrated with observed surface moisture data from one growing season and validated with data from another. Good overall agreement (r² = .89) was found between the observed and modelled data. The seasonal variability of precipitation in this region is reflected in the simulated daily surface moisture. The response of the natural savanna vegetation as observed from monthly composites of satellite-derived Normalized Difference Vegetation Index (NDVI) is also monitored for the same period. It is seen that the NDVI peaks at different times during the rainy season from one year to the next, according not only to the total seasonal precipitation, but its temporal distribution as well. It is also seen that there is a delay in intraseasonal vegetation response. While the NDVI is poorly correlated with the current month's average soil moisture, a distinct relationship with the previous month's average soil moisture was found.     

Dynamic displacements and stresses in the vicinity of a cylindrical cavity embedded in a half-space

The two-dimensional response of a viscoelastic half-space containing a buried, unlined, infinitely long cylindrical cavity of circular cross-section subjected to harmonic plane SH, P, SV and Rayleigh waves is obtained by an indirect boundary integral method based on the two-dimensional Green's functions for a viscoelastic half-space. An extensive critical review of the existing numerical results obtained by other techniques is presented together with some new numerical results describing the motion on the ground surface and the motion and stresses on the wall of the cavity for P, SV, SH and Rayleigh waves.     

Seismic response of a cylindrical shell embedded in a layered viscoelastic half-space. I: Formulation

A method to obtain the three-dimensional harmonic response of a infinitely long cylindrical shell of circular cross-section embedded in a layered viscoelastic half-space and subjected to harmonic plane waves impinging at an oblique angle with respect to the axis of the shell is presented. The procedure combines an indirect integral representation for the field in the exterior half-space with a model of the pipeline or tunnel based on Donnell shell theory. The integral representation for the soil is based on the use of moving Green's functions for the layered viscoelastic half-space. The accuracy of the formulation is tested by comparison of results obtained by using different discretizations. Extensive comparisons with previous two- and three-dimensional results for the case of a shell embedded in a uniform half-space and some new numerical results for a shell embedded in a multilayered half-space are presented in a companion paper.     

Seismic response of a cylindrical shell embedded in a layered viscoelastic half-space. II: Validation and numerical results

A procedure to calculate the three-dimensional harmonic response of a infinitely long cylindrical shell of circular cross-section embedded in a layered viscoelastic half-space and subjected to harmonic plane waves impinging at an oblique angle with respect to the axis of the shell is validated by extensive comparisons with previous two- and three-dimensional results for the particular case of a shell embedded in a uniform half-space. New numerical results describing the motion and stresses within a shell embedded in a multilayered half-space and subjected to obliquely incident P-, SV- and SH-waves with different horizontal angles of incidence are presented and discussed.     

The Amazon river breeze and the local boundary layer: I. Observations

Observations of the diurnal evolution of the planetary boundary layer over the Amazon rain forest, made at sites close to the confluence of the Solimões and Negro rivers (approximately at 3°S, 60°W) near Manaus, Amazonas, Brazil, show the existence of a diurnal rotation of the wind near the surface and the frequent presence of low-level nocturnal wind maxima. These circulations are shown to be plausibly explained as elements of a river and land breeze circulation induced by the thermal contrast between the rivers and the adjacent forest.     

Identification and occurrence of novel C36–C54 3,4-dialkylthiophenes with an unusual carbon skeleton in immature sediments

A series of novel long-chain 3,4-dialkylthiophenes (C₃₆–C₅₄) was identified in a number of sediments ranging from Pleistocene to Cretaceous. The identifications were based on mass spectral characterisation, desulphurisation and mass spectral data of synthesised model compounds. These organic sulphur compounds are probably formed by sulphur incorporation into mid-chain dimethylalkadienes with two methylenic double bonds. These putative precursor lipids are unprecedented and may be considered rather unusual. The distribution of 3,4-dialkylthiophenes in sediments varies considerably with the depositional palaeoenvironment, indicating that these compounds have a potential as molecular markers reflecting changes in palaeoenvironment.