Ecotoxicological evaluation of dredged sediments from Rodrigo de Freitas Lagoon (Rio de Janeiro State,Brazil) using bioassays with earthworms and collembolans

The toxicity and metal bioavailability were studied in dredged sediments from Rodrigo de Freitas Lagoon (Rio de Janeiro, RJ, Brazil) using acute and avoidance tests with Eisenia andrei, and reproduction tests with Folsomia candida. The sediment was mixed with an artificial soil, and two natural soils (ferralsol and chernosol—representative Brazilian tropical soils) to obtain the following doses: 1, 3, 6, 12, 18, 24 and 30%. Total metal concentrations were determined in the sediment to support the interpretation of ecotoxicological data. Metal concentrations in the mixtures were in agreement with the threshold limits established by Brazilian law. However, significant avoidance responses were found on doses ≥?3% and were the most sensitive endpoint. Earthworm mortality found in artificial soil mixtures (LC50?=?3.9) suggests higher toxicity levels than those obtained in ferralsol (LC50?=?7.6%) and chernosol (11.0%) treatments. Earthworm mortality, avoidance responses and collembolan reproduction levels found in ferralsol mixtures (LC50?=?9.2; avoidance EC50?=?2.3%; reproduction EC50?=?2.8%) were higher compared to chernosol treatments (LC50?=?11.0%; avoidance EC50?=?4.3%; reproduction EC50?=?4.9%). The reduction of toxicity levels in chernosol mixtures is probably due to the abundance of expansive clay minerals in chernosols with capacity of adsorbing metals and other xenobiotic substances from soil pore water, decreasing metal bioavailability. Finally, threshold limits defined by Brazilian legislation for soil quality and land disposal of dredged sediments are not sufficient to prevent noxious effects on soil fauna and should be complemented with a preliminary ecotoxicological evaluation.     

Zoning and exsolution in alkali feldspars from Laacher See volcano (Western Germany): constraints on temperature history prior to eruption

Compositional zoning and exsolution patterns of alkali feldspars in carbonatite-bearing cognate syenites from the 6.3 km³ (D.R.E) phonolitic Laacher See Tephra (LST) deposit in western Germany (12.9 ka) are reported. These rocks represent the cooler outer portion and crystal-rich products of a cooling magma reservoir at upper crustal levels. Major and trace-element difference between cores and rims in sanidine crystals represent two generations of crystal growth separated by unmixing of a carbonate melt. Trace-element differences measured by LA–ICP–MS are in accordance with silicate–carbonate unmixing. Across the core–rim boundary, we extracted gray-scale profiles from multiple accumulations of back-scattered electron images. Gray scales directly represent K/Na ratios owing to low concentrations of Ba and Sr (<?30 ppm). Diffusion gradients are modeled to solve for temperature using known pre-eruptive U–Th zircon ages (0–20 ky) of each sample (Schmitt et al., J Petrol 51:1053–1085, 2010). Estimated temperatures range from 630 °C to 670 °C. For the exsolution boundaries, a diffusive homogenization model is constrained by the solvus temperature of ~ 712^_725 °C and gives short time scales of only 15–50 days. Based on our results, we present a model for the temperature–time history of these rocks. The model also constrains the thermal variation across the cooling crystal-rich carapace of the magma reservoir over 20 ka and suggests a thermal reactivation of cumulates, the cooling carapace, and probably the entire system only a few years prior to the explosive eruption of the remaining molten core of the phonolitic magma reservoir.     

Post-eruptive lahars at Kali Putih following the 2010 eruption of Merapi volcano,Indonesia: occurrences and impacts

Following the 2010 VEI 4 eruption of Merapi volcano, more than 250 lahars were triggered during two rainy seasons from October 2010 to March 2012. This high number of post-eruption lahars mainly occurred in the Kali (valley) Putih watershed and was mostly associated with high-magnitude rainstorms. A lahar occurring on January 8, 2011, caused significant damage to homes in several communities, bridges, sabo dams, and agricultural crops. The aims of this contribution are to document the impacts of lahars on the Kali Putih watershed and specifically (1) to analyze the lahar frequency during the period of 1969–2012 on an inter-annual and intra-annual basis and to determine the link between the volume of tephra and the frequency of lahars; (2) to detail the lahar trajectory and channel evolution following the January 8th lahar; (3) to map the spatial distribution of the thickness and geomorphic effects of the lahar deposit; and (4) to determine the impacts of the lahar on the infrastructure (sabo dams and roads) and settlements in the distal area of the volcano. The Kali Putih watershed has experienced 62 lahars, which represent 22% of all lahars triggered on 17 rivers at Merapi between 2010 and 2012. The main geomorphic impacts are: (1) excessive sedimentation in valleys, settlements and agricultural areas; (2) undercutting of the river banks by as much as 50 m, accompanied by channel widening; and (3) abrupt changes in the river channel direction in the distal area (15–20 km downstream of the volcano). About 19 sabo dams were damaged, and 3 were totally destroyed. Over 307 houses were damaged, and the National Road Yogyakarta–Semarang was regularly cut (18 times during approximately 25 days). Although the sabo dams on Kali Putih were originally constructed to protect distal areas from lahar damage, they had little effect on the 2010–2012 rain-triggered lahars. The underlying design of those dams along this river is one of the main reasons for the major destruction in this sector of the volcano’s lower slope. The catch basin capacity of the sabo dam was only 1.75?×?10⁶ m³, whereas the total volume of the 2010–2011 lahars exceeded 5?×?10⁶ m³. In order to prepare for future lahars, the government has invested in significant mitigation measures, ranging from structural approaches (e.g., building new sabo dams and developing an early warning system) to non-structural approaches (e.g., contingency and preparedness planning and hazard education).

     

Hydrologic models coupled with 2D hydrodynamic model for high-resolution urban flood simulation

Natural Hazards - Floods are the most frequent natural disaster and pose a very challenging threat to many cities worldwide. Understanding the flood dynamic is essential for developing strategies...     

Relationships Between Petrophysical and Mechanical Properties of Certain Calcarenites Used in Building

Mendicino calcarenite was once widely used in traditional constructions by Italy’s foremost stonemasons’ schools. This paper provides a complete physico-mechanical characterization in order to improve understanding of strength and durability properties and so apply that knowledge to conservation and new construction. Stone samples from three lithofacies are taken from the following quarries of Cosenza province: Scannelle in Malito; Cannataro in Carolei; Albanese in San Lucido. Samples are subjected to: X-ray diffraction, mercury intrusion porosimetry, ultrasonic pulse velocity, capillary water absorption, uniaxial compressive, flexural, point load tests with respect to the X, Y, Z axes. Malito samples exhibit creamy colour, better hydric behaviour, low open porosity, reduced water absorption capability, isotropic hydric behaviour, higher fossil abundance (both in number and size) than the lithofacies taken from Carolei and San Lucido, which exhibit whitish colour, greater strength and more homogeneous texture. The greater compactness of Carolei and San Lucido samples can be ascribed to homogeneity and low porosity and their better mechanical properties to textural features. Anisotropy plays an important role. Placing stone samples along the Z axis prevents water intrusion, and improves mechanical strength. Isotropy and compact and heterogeneous fabric in stones result in higher strength and lower water absorption.

     

The Colider and Roosevelt Volcanic rocks (sw amazonian craton): geochemistry and sm-nd isotope characteristics of a silicic large igneous province

The volcanic rocks of the Colíder and Roosevelt formations are extensively exposed in the south-central portion of the Amazonian Craton where effusive and pyroclastic rocks have been mapped. Both units, topped by chemical sediments and oceanic facies as rhyolite and andesite lavas, rhyodacite, and porphyritic dacite, with frequent intercalations of pyroclastic and epiclastic deposits. Whole-rock geochemistry for 55 samples of rhyolitic to andesitic composition suggests the involvement of fertile mantle-derived components with E-MORB to OIB compositions. The analyzed rocks display calc-alkaline to shoshonitic affinity consistent with generation related to an active continental margin. The whole-rock Sm-Nd isotope data from selected felsic volcanic rocks of the Colíder and Roosevelt formations yield negative initial ε_Nd values between –3 and –9, indicating the predominantly crustal nature of the parental magmas with early Archean to late Paleoproterozoic (ca. 2.5–2.0 Ga) depleted mantle model ages.

     

Co-variance of dissolved Fe-binding ligands with phytoplankton characteristics in the Canary Basin

Dissolved Fe and ligand concentrations and the Fe-binding strength of the organic ligands were measured in samples from the upper water column (150 m) of the oligotrophic waters of the Canary Basin (eastern North Atlantic Ocean). Concentrations of major nutrients, phytoplankton abundance and photosynthetic characteristics were also measured in the same samples.The concentrations of dissolved Fe and dissolved organic ligands were low with mean values of 0.31 ± 0.18 nM Fe and 1.79 ± 0.73 nEq of M Fe(n = 47), respectively. The conditional binding constant varied between 10^19.8–10^22.7 (n = 47). The largest variation with depth in the ligand concentrations (between 4.78 and 1.1 nEq of M Fe) was observed in the upper layer, above the Deep Chlorophyll Maximum (DCM located between 80 and 100 m), with high surface values in stations at 18 and 34.At the DCM where Fe was depleted, the ligand concentrations were still relatively high showing the same trend with depth as the amount of phytoplankton cells. Here 62% of the vertical variation in ligand concentrations can be explained by parameters describing phytoplankton cell abundance or biomass and orthosilicic acid concentration, which could reflect diatom growth. Ligand concentrations below the maximum of the DCM (n = 4) showed good linear positive relationships with the total phytoplankton biomass as well as with 2 out of 4 distinguished groups of phytoplankton (Synechococcus and pico-eukaryote I).In the maximum of the DCM and below this maximum the phytoplankton origin of the dissolved organic ligands of Fe is very probable. Data suggest a release of ligands by cell lysis and not by an active production. However, the origin in the surface layer is more difficult to explain. Although the amount of phytoplankton cells in the surface layer is reduced, it is still  25% of the cell concentration observed in the DCM. High concentrations of organic ligands could then be a remnant of past blooms or present production under nutrient depleted conditions. Input of Sahara dust can be another source of ligands.     

Spatiotemporal patterns of burned areas,fire drivers,and fire probability across the equatorial Andes

Field-based fire studies in the equatorial Andes indicate that fires are strongly associated with biophysical and anthropogenic variables. However, fire controls and fire regimes at the regional scale remain undocumented. Therefore, this paper describes spatial and temporal burned-area patterns, identifies biophysical and anthropogenic fire drivers, and quantifies fire probability across 6° of latitude and 3° of longitude in the equatorial Andes. The spatial and temporal burned-area analysis was carried out based on 18 years(2001-2018) of the MCD64 A1 MODIS burned-area product. Climate, topography, vegetation, and anthropogenic variables were integrated in a logistic regression model to identify the significance of explanatory variables and determine fire occurrence probability. A total of 5779 fire events were registered during the 18 years of this study, located primarily along the western cordillera of the Andes and spreading from North to South. Eighty-eight percent of these fires took place within two fire hotspots located in the northwestern and southwestern corners of the study area. Ninety-nine percent occurred during the second part of the year, between June and December. The largest density of fires was primarily located on herbaceous vegetation and shrublands. Results show that mean monthly temperature, precipitation and NDVI during the prefire season, the location of land cover classes such as forest and agriculture, distance to roads and urban areas, slope, and aspect were the most important determinants of spatial and temporal fire distribution. The logistic regression model achieved a good accuracy in predicting fire probability(80%). Probability was higher in the southwestern and northern corners of the study area, and lower towards the north in the western and eastern piedmonts of the Andes. This analysis contributes to the understanding of fires in mountains within the tropics. The results here presented have the potential to contribute to fire management and control in the region.     

Youth Mobility and Territorial Disparities: An Analysis of Urban and Rural Barcelona

Travel behavior of the present generation of youths is being increasingly explored due to their relevance in shaping future accessibility needs and mobility habits. The present study offers an original perspective on this topic by identifying territorial disparities that emerge in youth mobility patterns in rural and urban areas. Unlike most previous research, we propose taking a global view on mobility by analyzing all trip purposes and transportation modes. This is conducted by analyzing a comprehensive mobility survey in the Barcelona Metropolitan Region, which provides data on mobility engagement, trip purposes, modal split, travel times and territorial differences. In general, youngsters account for larger daily travel times than older adults, present a higher attachment to public transportation and walk less on a daily basis. These differences are enhanced in rural territories, where while older adults overcome accessibility issues with higher use of the private vehicle, youngsters are more likely to invest larger travel times on transit.     

Shock deformation confirms the impact origin for the Cerro do Jarau,Rio Grande do Sul,Brazil, structure

Cerro do Jarau is a conspicuous, circular morpho‐structural feature in Rio Grande do Sul State (Brazil), with a central elevated core in the otherwise flat “Pampas” terrain typical for the border regions between Brazil and Uruguay. The structure has a diameter of approximately 13.5 km. It is centered at 30^o12′S and 56^o32′W and was formed on basaltic flows of the Cretaceous Serra Geral Formation, which is part of the Paraná‐Etendeka Large Igneous Province (LIP), and in sandstones of the Botucatu and Guará formations. The structure was first spotted on aerial photographs in the 1960s. Ever since, its origin has been debated, sometimes in terms of an endogenous (igneous) origin, sometimes as the result of an exogenous (meteorite impact) event. In recent years, a number of studies have been conducted in order to investigate its nature and origin. Although the results have indicated a possible impact origin, no conclusive evidence could be produced. The interpretation of an impact origin was mostly based on the morphological characteristics of the structure; geophysical data; as well as the occurrence of different breccia types; extensive deformation/silicification of the rocks within the structure, in particular the sandstones; and also on the widespread occurrence of low‐pressure deformation features, including some planar fractures (PFs). A detailed optical microscopic analysis of samples collected during a number of field campaigns since 2007 resulted in the disclosure of a large number of quartz grains from sandstone and monomict arenite breccia from the central part of the structure with PFs and feather features (FFs), as well as a number of quartz grains exhibiting planar deformation features (PDFs). While most of these latter grains only carry a single set of PDFs, we have observed several with two sets, and one grain with three sets of PDFs. Consequently, we here propose Cerro do Jarau as the seventh confirmed impact structure in Brazil. Cerro do Jarau, together with Vargeão Dome (Santa Catalina state) and Vista Alegre (Paraná State), is one of very few impact structures on Earth formed in basaltic rocks.