Metal fluxes to the sediments of the Moulay Bousselham lagoon,Morocco

The metal content in surface sediments (0–2 cm, 26 samples), in a sediment core (120, 1 cm slices), taken from Moulay Bousselham (Morocco) was investigated. Concentrations of Al, Fe, Mn, Pb, Zn, Cu, Ni, Cr, Cd, As, and Hg were evaluated in surface and cored sediments of Moulay Bousselham lagoon. Significantly high concentrations in μg g⁻¹ dw of Pb (31.7–6.2), Zn (758.9–167), Cu (310.7–22), Ni (96–10.5), Cr (113–18.9), Cd (0.84–0.02), As (1–0.1), and Hg (0.61–0.02) were found in sediment samples from Moulay Bousselham lagoon. Calculated enrichment factors [EF_Me = (Me/Al)_sample/(Me/Al)_background], using Al as a normalizer, and correlation matrices showed that metal pollution in Merja Zerga of Moulay Bousselham lagoon was the product of anthropogenic sources, while the metal content in Merja Kehla was of natural origins. The results suggest that a major change in the sedimentary regime of the lagoon, associated with internal trapping and re-distribution of heavy metal, has been occurring in the past few decades. The cause would appear to be the construction of a Nador Canal at the lagoon. Probable effects concentrations (PEC) were often exceeded for heavy metals in the lagoon sediments, especially for Zn, Cu, Ni, and Cr, and four stations, stations MZ-11, MZ-12, MZ-13, MZ-14, MZ-16, and MZ-17, had multiple metals at presumptively toxic levels. These comparisons suggest that sediment metal levels in the river are clearly high and probably pose an environmental risk at some stations. The levels of most of the metals were not greatly enriched, a consideration that is of the utmost importance when contamination issues are at stake. Metal concentrations found in Moulay Bousselham lagoon were comparable to aquatic systems classified as contaminated from other regions of the world.     

Statistical distributions of daily rainfall regime in Europe for the period 1951–2000

Amount and time distributions, X and Y, of daily rain amounts in Europe along the second half of 20th century have been studied from 267 rain gauge records. Different geographical features, such as latitude, vicinity to Mediterranean Sea or the Atlantic Ocean or altitude above sea level, cause the averages of daily rain and annual number of rainy days to vary within a wide range. The largest daily percentiles of amount and time distributions are reached at latitudes south of 50°N and in southwestern Norway. The amount of distribution, X, is well-modelled by the exponential function, with parameters derived from probability graphs. Time distributions, Y, are well-fitted by Pearson type III (Gamma) and Weibull models, their parameters being estimated by L-moments. Normalised rainfall curves (NRC) have been modelled by the analytical function $ X = Y \cdot \exp \left\{ { - b{{\left( {1 - Y} \right)}^c}} \right\} $ , with b and c parameters depicting spatial variability. Alternatively, the beta distribution also describes quite well the empirical NRCs, with parameters estimated by statistical moments. The coordinates of the average daily amount (X _r , Y _r ) and the values of X ^* and Y ^* , which are defined as the fraction of rain amount for a half of rainy days and the fraction of number of rainy days accounting for a half of total rain amount, respectively, depict very similar spatial distribution throughout Europe. In fact, X _r and X ^* keep a linear relationship, as well as Y _r and Y ^* , the four coordinates depending on the coefficient of variation of daily rain amounts. A similar linear relationship is found for the pair (X ^* , Y ^* ). Finally, the Average Linkage algorithm applied to the coordinates X _r , Y _r , X ^* and Y ^* characterising every one of the 267 NRCs permits to group the rain gauges into several spatial clusters, each of them related to a different normalised daily pluviometric regime.     

Future changes in Central Europe heat waves expected to mostly follow summer mean warming

Daily output from the PRUDENCE ensemble of regional climate simulations for the end of the twentieth and twenty-first centuries over Europe is used to show that the increasing intensity of the most damaging summer heat waves over Central Europe is mostly due to higher base summer temperatures. In this context, base temperature is defined as the mean of the seasonal cycle component for those calendar days when regional heat waves occur and is close, albeit not identical, to the mean temperature for July–August. Although 36–47% of future Central Europe July and August days at the end of the twenty-first century are projected to be extreme according to the present day climatology, specific changes in deseasonalized heat wave anomalies are projected to be relatively small. Instead, changes in summer base temperatures appear much larger, clearly identifiable and of the same order of magnitude as changes in the whole magnitude of heat waves. Our results bear important consequences for the predictability of central European heat wave intensity under global warming conditions.     

Practical aspects of demand and capacity evaluation of RC members in the context of EC8‐3

The structural safety assessment procedures proposed in Part 3 of Eurocode 8 (EC8‐3) for the case of reinforced concrete structures are addressed. The practical evaluation of the member chord rotation demand according to EC8‐3 is examined in detail along with several alternative formulations. The need for these formulations is demonstrated by presenting example situations where the EC8‐3 proposal is difficult to apply. The effectiveness of the proposed approaches is assessed through an example application and recommendations for their practical use are defined. Given the importance of the shear span in this context, a sensitivity analysis of the EC8‐3 capacity models with respect to this parameter is carried out and discussed in a later section. This analysis aims to assess the validity of the simplifications proposed by a previous research study for the quantification of the EC8‐3 capacity values. Copyright © 2009 John Wiley & Sons, Ltd.     

Phase separation,fluid mixing,and origin of the greisens and potassic episyenite associated with the Água Boa pluton,Pitinga tin province,Amazonian Craton,Brazil

Based on petrographical data, three types of greisen have been characterized at the western border of Água Boa pluton: siderophyllite–topaz–quartz greisen (greisen 1), fluorite–phengite–quartz greisen (greisen 2) and quartz–chlorite–phengite greisen (greisen 3). Episyenites were also identified.Two fluids of independent origin interacted with the same protolith – a hornblende-biotite alkali feldspar granite – and produced both the greisens and potassic episyenite: (1) an acid, low-salinity (4–12 wt.% NaCl eq.), F-rich, relatively hot (400–350 °C) reduced aqueous-carbonic fluid (CH₄–H₂O–NaCl–FeCl₂ ± KCl), which by immiscibility gave rise to fluid IA (aqueous) and IC (carbonic); and (2) a lower salinity (2–4 wt.% NaCl eq.) and temperature (200–150 °C) aqueous fluid (H₂O–NaCl), which was responsible for all dilution processes. Fluid 1 seems to have had a magmatic-hydrothermal origin, while fluid 2 is probably surface-derived (meteoric water?). An alkaline, F-poorer and diluted equivalent of fluid IA was interpreted to have caused the episyenitization of the granite host rock as well as the formation of phengite-rich greisen 3. The continuos interaction of this fluid with the potassic episyenite produced a moderate- to high-salinity (20–24 wt.% NaCl eq.), low-temperature (200–100 °C) fluid (H₂O–NaCl–CaCl₂ ± KCl), leading to the formation of chlorite-rich zone of greisen 3 and late silicification of potassic episyenite.In the greisen 1, decreasing F-activity and increasing oxygen fugacity, as the system cooled down, favored the formation of a topaz-rich inner zone, which grades into a siderophyllite-rich zone outwardly. Greisen 2 was formed under more oxidizing conditions by fluids poorer in F than those trapped in the siderophyllite-rich zone.The oxidation of aqueous-carbonic fluid took place at three distinct stages: (i) below the FMQ buffer; (ii) between the FMQ and NNO buffers; and (iii) above the NNO buffer.The dissolution cavities generated during the episyenitization process increased the permeability of the altered rocks, resulting in an increase of the fluid/rock ratios at the potassic episyenite and greisen 3 sites.All these fluids were trapped under pressure conditions of <1.0 kbar, representing shallow crustal levels and are consistent with those that have been estimated for the Pitinga tin–granites.The oxygen fugacity, F-activity gradients and salinity variations that occurred during the cooling of the hydrothermal system, in addition to differences in permeability, were important factors in the formation of distinct greisens. They not only controlled the fluid compositional changes, but also caused the cassiterite and sulfide precipitation at the greisen sites.     

Organic matter in sediments of canyons and open slopes of the Portuguese,Catalan, Southern Adriatic and Cretan Sea margins

We describe the quantitative and compositional (phytopigment, protein, carbohydrate and lipid) patterns of sedimentary organic matter along bathymetric gradients in seven submarine canyons and adjacent open slopes located at four European regions: one along the NE Atlantic and three along the Mediterranean continental margins. The investigated areas are distributed along a putative longitudinal gradient of decreasing primary production from the Portuguese (northeastern Atlantic Ocean), to the Catalan (western Mediterranean Sea), Southern Adriatic (central Mediterranean Sea) and Southern Cretan (eastern Mediterranean Sea) margins. Sediment concentrations of organic matter differed significantly between the Portuguese margin and the Mediterranean regions and also from one study area to the other within the Mediterranean Sea. Differences in quantity and composition of sediment organic matter between canyons and open slopes were limited and significant only in the eutrophic Portuguese margin, where the differences were as large as those observed between regions (i.e. at the mesoscale). These results suggest that the overall trophic status of deep margin sediments is controlled mostly by the primary productivity of the overlying waters rather than by the local topography. Moreover, we also report that the quantity and nutritional quality of sediment organic matter in canyons and adjacent open slopes do not show any consistent depth-related pattern. Only the Nazaré and Cascais canyons in the Portuguese margin, at depths deeper than 500 m, displayed a significant accumulation of labile organic matter. The results of our study underline the need of further investigations of deep margins through sampling strategies accounting for adequate temporal and spatial scales of variability.     

Magnetotelluric measurements at Eusebio,an equatorial station

Magnetotelluric measurements in the period range 100–86400 s were conducted at a coastal station under the equatorial electrojet (Eusebio, 3.87°S, 321.58°E). The magnetotelluric data were hand-scaled and analysed to obtain a scalar apparent resistivity profile at Eusebio. The depth of the intermediate conducting layer was found to be in the range 45–75 km and the final conducting layer seems to begin at a depth of about 350 km. Possible effects of the source field equatorial electrojet are discussed and our results are compared with those of an African station under the equatorial electrojet.