Sea,freshwater or saltpans? Foraging ecology of terns to assess mercury inputs in a wetland landscape: The Ebro Delta

The Ebro catchment, the largest river basin in Spain, includes various heavily industrialized areas. Among these is the Flix site, where a chemical plant has been operating since the beginning of the 20th century. This extended operational period, together with the construction of a dam next to the factory around 1960, resulted in the accumulation of large amounts of heavily polluted sediments in the adjacent riverbed, many of which are contaminated by mercury. Pollutants from Flix are carried downstream by the Ebro River to its delta. In order to assess the transfer of mercury to the complex river estuary ecosystem, we studied the ecology of the tern community living there as these birds segregate into a range of habitats. For this purpose, first we used stable isotope analysis (SIA) (δ³⁴S, δ¹³C, δ¹⁵N) of eggs to determine the trophic ecology and habitat partitioning of several tern species (Common, Sandwich, Little, Gull-Billed and Whiskered Tern) breeding sympatrically, in order to link their foraging ecology with habitat types. Next we measured mercury concentrations in eggs to monitor the input of this metal into the diverse habitats. With the exception of the Little Tern, the other terns used a restricted habitat range in the Ebro Delta, as shown by C and S isotopes; the Gull-Billed and Whiskered Tern foraged in freshwater habitats, while the Common and Sandwich Tern used marine habitats. This restricted feeding behavior of the Gull-Billed and Common Tern contrasts with previous reports in other breeding sites. The Little Tern, which showed a wide range of isotopic values, was found to be an opportunistic forager but fed mainly in saltpans, a feeding habitat not reported previously for this species in this area. We found that mercury concentrations are related to foraging habitat and diet, and are unexpectedly higher in species feeding on demersal prey in marine habitats and also higher in birds feeding in saltpans than in those feeding in freshwater habitats. The mercury concentrations found in the Little and Common Tern eggs sampled in “Punta de la Banya” may be sufficiently high to endanger breeding success.     

Characteristics and regional classification of the copepod community in Ariake Bay with note on comparison with 3 decades ago

Ariake Bay, Kyushu Island, has recently exhibited environmental degradation in the form of red tides and anoxic bottom water. To determine the characteristics and regional classification of the copepod community, zooplankton surveys were made throughout the bay in three cruises each in October 2004, January 2005 and March 2009 by vertical tows of a 0.1-mm-mesh plankton net. Oithona davisae was the most abundant in January and March, and Microsetella norvegica in October. Cluster analysis revealed that the copepod community from each cruise was generally separated into the inner to eastern-middle region and the western-middle to mouth region. A SIMPER analysis revealed that dissimilarity between the groups and similarity within each group were mainly due to the dominant species, but the similarities within the outer-region group in January and March were mostly contributed by Paracalanus parvus s.l. A non-metric multidimensional scaling with bubble plots of environmental variables and a BIOENV analysis showed that transparency was more different between the two groups than temperature and salinity. As compared with two similarly sized, eutrophic bays (Tokyo and Osaka Bays), Ariake Bay differs from Tokyo Bay in the dominance of M. norvegica and from Osaka Bay in the high abundance of O. davisae even in the colder season. The dominant species and the regional classification of the copepod community in the bay were similar to those in the studies in the 1970s, suggesting that the copepod community has not notably changed during the last 3 decades.     

Delivery and deposition of organic matter in surface sediments of Lagoa do Caçó (Brazil)

Elemental and isotopic compositions of organic matter in surficial sediments from five transects across Lagoa do Caçó (Brazil) were analyzed to identify the depth-related processes that affect the production and deposition of sedimentary organic matter in this shallow tropical lake. Each of four transverse transects began at a margin dominated by aquatic macrophytes (Eleocharis), crossed the central deep part of the lake, and terminated in the opposite, macrophyte-dominated margin. In each transect, TOC concentrations, C/N ratios, and δ¹³C values decreased between 0 and 4 m, whereas δ¹⁵N values increased. The variables remained stable in sediment from 4 m water depth to the center of the lake at 10 m. The depth-related patterns reflect differences in both the delivery and the deposition of organic matter in the lake. Organic matter is produced in abundance in the marginal area by emersed and submerged macrophyte vegetation that diminishes with depth and disappears at 4 meters. After the disappearance of macrophytes, organic matter is produced at low rates principally by open-lake phytoplankton. Drawdown of dissolved oxygen is high in the lake margins, but it is low in the oligotrophic open waters of the lake. Preservation of organic matter is consequently better in sediments of the lake margins than in deep waters. The depth-related pattern of organic matter delivery and deposition in the sediments of Lagoa do Caçó, in which water levels are sensitive to groundwater fluctuations, shows that the elemental and isotopic compositions of sediment organic matter can provide a record of changes in the paleohydrology of this and other similar shallow lake systems.     

Petrogenetic links between lepidolite-subtype aplite-pegmatite,aplite veins and associated granites at Segura (central Portugal)

In the Segura area, Variscan S-type granites, aplite veins and lepidolite-subtype granitic aplite-pegmatite veins intruded the Cambrian schist-metagraywacke complex. The granites are syn D3. Aplite veins also intruded the granites. Two-mica granite and muscovite granite have similar ages of 311.0 ± 0.5 Ma and 312.9 ± 2.0 Ma but are not genetically related, as indicated by their geochemical characteristics and (⁸⁷Sr/⁸⁶Sr)₃₁₁ values. They correspond to distinct pulses of magma derived by partial melting of heterogeneous metapelitic rocks. Major and trace elements suggest fractionation trends for: (a) muscovite granite and aplite veins; (b) two-mica granite and lepidolite-subtype aplite-pegmatite veins, but with a gap in most of these trends. Least square analysis for major elements, and modeling of trace elements, indicate that the aplite veins were derived from the muscovite granite magma by fractional crystallization of quartz, plagioclase, K-feldspar and ilmenite. This is supported by the similar (⁸⁷Sr/⁸⁶Sr)₃₁₁ and δ¹⁸O values and the behavior of P₂O₅ in K-feldspar and albite. The decrease in (⁸⁷Sr/⁸⁶Sr)₃₁₁ and strong increase (1.6‰) in δ¹⁸O from two-mica granite to lepidolite-subtype aplite-pegmatite veins, and the behaviors of Ca, Mn and F of hydroxylapatite indicate that these veins are not related to the two-mica granite.     

Probabilistic earthquake risk assessment using CAPRA: application to the city of Barcelona, Spain

The risk evaluation model CAPRA (Comprehensive Approach to Probabilistic Risk Assessment) is a techno-scientific methodology and information platform, composed of tools for evaluating and communicating risk at various territorial levels. The model allows evaluating losses on exposed elements using probabilistic metrics, such as the loss exceedance curve, the expected annual loss and the probable maximum loss, useful for multi-hazard risk analyses. In this article, the process of probabilistic seismic risk analysis is described, explaining the main features of the CAPRA modules of hazard, vulnerability and risk estimation applied to the city of Barcelona, Spain. In addition, according to the physical risk results and the information on the socioeconomic indicators of the city, this article presents the holistic evaluation of seismic risk, which is a valuable result to facilitate the integrated risk management by the different stakeholders involved in risk reduction decision making.     

Isotope geochemistry of Paleoproterozoic metacarbonates from Itatuba,Borborema Province,Northeastern Brazil: Evidence of marble melting within a collisional suture

Strongly-deformed marbles may be easily confused with linear and elongated carbonatite intrusions. Both rocks may present similar texture and foliation to the host rock, or even cross cutting field relationships, which could be interpreted either as igneous or high-grade metamorphosed marble. Diagnostic criteria are even more complex when there is evidence of melting of the metasedimentary carbonate rock, such as has been described in the Himalayas and in the Eastern Ghats, India.In the Alto Moxotó Terrane, a high-grade gneissic domain of the Borborema Province, Northeastern Brazil, there are metacarbonates associated with banded gneisses and different metaplutonic rocks. Field evidence indicates the absence of other metasedimentary rocks associated with these marbles, thus suggesting that these carbonates were separated from other siliciclastic metasedimentary rocks. The presence of marble also suggests that it may represent the initial stage of a crustal carbon recycling into the mantle. These marbles present many field similarities to carbonatites (e.g., fluid-flow structure) and, together with metagranites and metamafic intrusions, may represent a major collisional tectonic suture.A detailed study of the carbon, oxygen and strontium isotopic composition of these marbles is presented. This study aims to identify the origin of the different isotopic components. It is argued that these rocks were subjected to temperature and pressure conditions that were sufficiently high to have melted them. The isotopic data presented here support this interpretation and indicate the mixing of two components: (i) one characterized by radiogenic Sr isotopes and mantle-like carbon isotopes, which is associated with the gneissic and mafic rocks, and (ii) another characterized by low ⁸⁷Sr/⁸⁶Sr ratios and highly positive δ¹³C values. Available geochemical data for the upper Paleoproterozoic indicate that the ⁸⁷Sr/⁸⁶Sr ratio of ocean water, varying between 0.7050 (2.25 ± 0.25 Ga) and 0.7047 (1.91 Ga), falls within the lower range of the samples from Itatuba and thus reinforces the interpretation that these marbles are sedimentary-derived and were partially contaminated by interaction with the host gneissic and mafic rocks.     

Assessing Decomposition Rates of Rhizophora mangle and Laguncularia racemosa Leaves in a Tropical Mangrove

Studies exploring leaf decomposition in mangroves in the Brazilian northeast are scarce. Therefore, in a mangrove of the Cachoeira River estuary at Ilhéus, Bahia, the decomposition of senescent leaves of Rhizophora mangle L. and Laguncularia racemosa Gaertn was studied. The litter-bag method and the Olson exponential model were applied to estimate the decomposition rates. The decay pattern of leaf material of both species was similar to those reported in the literature, with rapid initial weight loss, followed by a deceleration and period of slow weight loss. L. racemosa had the highest decay constants at all the study sites which suggest that their leaves are more easily degraded than those of R. mangle. The constantly submerged site presented the highest decay constants of 0.022 g g^?1 day^?1 for R. mangle and 0.031 g g^?1 day^?1 for L. racemosa. Most (95 %) of the leaf material of the two species was lost in 135 and 98 days, respectively. Benthic macrofauna organisms were recorded in the litter bags from the fifth day after the start of the experiment. Such organisms play a key role in the first phase of decomposition in this mangrove system. The decay constants of the leaf litter were generally higher than those reported in other tropical and subtropical regions. This suggests that differences in the process of decomposition are in response to environmental conditions at each location.     

Web-GIS tool for the management of rural land markets

Land abandonment and stagnation of rural markets in the last few years have become one of the main concerns of rural administrations. The use of Web and GIS (Geographic Information System) technologies can help to mitigate the effects of these problems. This paper pro-poses a novel Web-GIS tool with spatial capabilities for the dynamization of rural land markets by encouraging the transfer of land from owners to farmers through the leasing of plots. The system, based on open source software, offers information about the properties, their environment and their owners. It uses standards for handling the geographic information and for communicating with external data sources. This system was used as the basis for the development of SITEGAL, the tool for the management of the Land Bank of Galicia (www.bantegal.com/sitegal). SITEGAL has been operational since 2007 obtaining benefits for both administration and users (farmers and land owners), and promoting the e-Government.     

A Top-Cut Model for Deposits with Heavy-Tailed Grade Distribution

In some ore deposits, the grade distribution is heavy-tailed and high values make the inference of first- and second-order statistics nonrobust. In the case of gold data, high values are usually cut and the block estimation is performed using truncated grades. With this method, a part of the deposit is omitted, resulting in a potential bias on resources figures. Ad-hoc corrections can be applied on the final figures to take into account the tail of the grade distribution, but no theoretical guidelines are available. A geostatistical model has been developed to handle high values based on the assumption that for high grade zones, the only tangible information is the geometry. The grade variable z can be split into three parts: the truncated grade ( $\operatorname{Min} (z, z_{\mathrm{e}})$ where z _e is the top-cut grade), a weighted indicator above top-cut grade (1{z≥z _e}), and a residual. Within this framework, the residual is poorly structured, and in most cases is a pure nugget-effect. Moreover, it has no spatial correlation with the truncated grade and the indicator above top-cut grade. This decomposition makes the variographic study more robust because variables (indicator and truncated grade) do not keep high grade values. The underlying hypotheses can be tested on experimental indicator variograms and the top-cut grade can be justified. Finally, the estimation is based on a truncated grade and indicator cokriging. The model is applied to blast holes from a gold deposit and on a simulated example. Both cases illustrate the benefits of keeping the high values in the estimation process via an appropriate mathematical model.