Geochemistry, mineralogy, and technological properties of the main Stephanian (Carboniferous) coal seams from the Puertollano Basin, Spain

This study is focused on the occurrence and distribution of mineral matter and major and trace elements in the high volatile bituminous coal from Puertollano (south-central Spain). The relationship between ash behaviour and inorganic composition, as well as the possible formation of fouling and slagging deposits in boilers during the conversion process, were investigated. The Puertollano coals do not exhibit plastic properties, despite their rank, probably because of their high ash and inertinite contents.The Puertollano coal has medium to low total S content (0.48% to 1.63% db, with a mean of 1.0% db) and is characterised by relatively high contents of Si, Pb, Sb, and Cs. Some elements such as As, Cd, Co, Cr, Cu, Ge, Li, Mn, Ni, W, and Zn are also present in relatively high contents. The enrichment in a number of heavy metals could be attributed to the common sulphide ores occurring near the Puertollano coal deposit.The following trace elements affinities are deduced: (a) sulphide affinity: As, Co, Cd, Cu, Ni, Sb, Tl, and Zn; (b) aluminum–silicate affinity: K, Ti, B, Co, Cr, Cs, Cu Ga, Hf, Li, Nb, Rb, Sn, Ta, Th, V, Zr, and LREE; (c) Carbonate affinity: Ca, Mg, Mn, and B; (d) organic affinity: B.The very high Si levels and the anomalous enrichment in Cs, Ge, Pb, Sb, and Zn shown by the Puertollano coals account for the high contents of these elements in the Puertollano fly ash when compared with the other Spanish coal fly ashes.The chemical composition of the high temperature ash (HTA) is consistent with the trend shown by the ash fusion temperatures (AFT) and also with the predictive indices related to slagging and fouling propensities. Thus, the ash fusion temperatures increase with high values of Al₂O₃ as well as with the decrease in Fe₂O₃, CaO, and MgO.     

Modified equations for the determination of odd zonal harmonics

The development of the analytical theory of the motion of an artificial satellite (Berger, 1972–1975) points out the great importance of the second, third order and coupling terms between zonal harmonics. These terms have been added to the equations established byKing-Hele andCook (1968–1973) for the determination of odd zonal harmonics. This solution is compared with theirs. It satisfies all the equations much better and especially the equations relating to near-critical inclination satellites.     

Late Miocene – Recent exhumation of the central Himalaya and recycling in the foreland basin assessed by apatite fission-track thermochronology of Siwalik sediments, Nepal

Thermochronological analysis of detrital sediments derived from the erosion of mountain belts and contained in the sedimentary basins surrounding them allows reconstructing the long-term exhumation history of the sediment source areas. The effective closure temperature of the thermochronological system analysed determines the spatial and temporal resolution of the analysis through the duration of the lag time between closure of the system during exhumation and its deposition in the sedimentary basin. Here, we report apatite fission-track (AFT) data from 31 detrital samples collected from Miocene to Pliocene stratigraphic sections of the Siwalik Group in western and central Nepal, as well as three samples from modern river sediments from the same area, that complement detrital zircon fission-track (ZFT) and U–Pb data from the same samples presented in a companion paper. Samples from the upper part of the stratigraphic sections are unreset and retain a signal of source-area exhumation; they show spatial variations in source-area exhumation rates that are not picked up by the higher-temperature systems. More deeply buried samples have been partially reset within the Siwalik basin and provide constraints on the thermal and kinematic history of the fold-and-thrust belt itself. The results suggest that peak source-area exhumation rates have been constant at ∼1.8 km Myr⁻¹ over the last ∼7 Ma in central Nepal, whereas they ranged between 1 and ∼1.5 km Myr⁻¹ in western Nepal over the same time interval; these spatial variations may be explained by either a tectonic or climatic control on exhumation rates, or possibly a combination of the two. Increasing lag times within the uppermost part of the sections suggest an increasing component of apatites that have been recycled within the Siwalik belt and are corroborated by AFT ages of modern river sediment downstream as well as the record of the distal Bengal Fan. The most deeply buried and most strongly annealed samples record onset of exhumation of the frontal Siwaliks along the Himalayan frontal thrust at ∼2 Ma and continuous shortening at rates comparable with the present-day shortening rates from at least 0.3 Ma onward.     

Nankai Trough and Zenisu Ridge: a deep-sea submersible survey

Eight submersible dives between 3000 and 4200 m water depth were made off southern Japan in the eastern Nankai subduction zone. Benthic communities associated with chemosynthetic processes were discovered along the 800 m wide active tectonic zone, at the toe of the accretionary prism. A benthic community was also discovered along a zone of active compression, at the foot of Zenisu Ridge, 30 km south of Nankai Trough. Temperature measurements within the sediments below the benthic communities confirm that upward motion of interstitial water occurs there. Studies of water samples indicate advection of methane and light hydrocarbons. Specimens of the benthic community have been shown to have included in their shells carbonate resulting from methane consumption. Thus the benthic communities are related to overpressure-driven fluid advection along tectonic zones with active surface deformation. A 300 m high active scarp at the toe of the accretionary prism is related to relative motion in a 280° direction which is close to the 305° average direction of subduction in this area. The dives establish further that compressive deformation is presently occurring at the foot of Zenisu Ridge. The previous interpretation of the Zenisu Ridge as a zone of recent north-south intraplate shortening, 40 km south of the Nankai Trench, is confirmed. We conclude that tectonic evolution might well lead to future detachment of the Zenisu Ridge and overthrusting of this large piece of oceanic crust over the continental margin. Such a process might be an efficient one to emplace ophiolites over continents.     

Argiles et zéolites dans l'altération d'un volcan bouclier en milieu tropical (Le Piton des Neiges,La Réunion)

The drilling of a gallery through the Roche-Écrite massif (Reunion Island) allowed to sample the old formations of the ‘Piton des Neiges’ volcano. The mineralogical study of the alteration products of the formations showed significant variations of the zeolites/clay minerals ratio depending on the location of the rocks in the volcano. The abundance of zeolites in the formation near the surface hydrographic network or the underground water drainage system seems to be due to the physicochemical processes favouring zeolites in more open systems in their competition with secondary clays. To cite this article: L. Bret et al., C. R. Geoscience 335 (2003).     

The formation of new quasi-stationary vortex patterns from the interaction of two identical vortices in a rotating fluid

Within the framework of the quasi-geostrophic approximation, the interactions of two identical initially circular vortex patches are studied using the contour dynamics/surgery method. The cases of barotropic vortices and of vortices in the upper layer of a two-layer fluid are considered. Diagrams showing the end states of vortex interactions and, in particular, the new regime of vortex triplet formation are constructed for a wide range of external parameters. This paper shows that, in the nonlinear evolution of two such (like-signed) vortices, the filaments and vorticity fragments surrounding the merged vortex often collapse into satellite vortices. Therefore, the conditions for the formation and the quasi-steady motions of a new type of triplet-shaped vortex structure are obtained.     

Understanding fracture distribution and its relation to knickpoint evolution in the Rio Icacos watershed (Luquillo Critical Zone Observatory,Puerto Rico) using landscape-scale hydrogeophysics

The Rio Icacos watershed in the Luquillo Mountains (Puerto Rico) is unique due to its extremely rapid weathering rates. The watershed is incised into a quartz diorite that has developed a large knickzone defining the river profile. Regolith thickness within the watershed generally decreases from 20 to 30 m at the ridges to several meters in the quartz diorite-dominated valley to tens of centimeters near the major river knickpoint, as determined from previous studies. Above the knickzone, we observe spheroidal corestones, but below this weathering is much less apparent. Measured erosion rates from previous studies are also high in the knickzone compared with upper elevations within the river profile. A suite of near-surface geophysical methods (i.e. ground penetrating radar and terrain conductivity) capable of fast data acquisition in rugged landscapes, was deployed at kilometer scales to characterize critical zone structure. Concentrations of chaotic ground penetrating radar (GPR) reflections and diffraction hyperbolas with low electrical conductivity were observed in vertical zones that outcrop at the land surface as areas of intense fracturing and spheroidally weathered corestones. The width of these fractured and weathered zones showed an increase with proximity to the knickpoint, and was attributed to dilation of these sub-vertical fractures near the knickpoint, as postulated theoretically by a stress model calculated for the topographic variability across the knickzone in the Rio Icacos, and that shows a release of compressive stress near the knickpoint. We hypothesize that erosion rates increase in the knickzone because of this inferred dilation of fractures. Specifically, opened fractures could enhance access of water and in turn promote spalling, erosion, and spheroidal weathering. This study shows that ground-based hydrogeophysical methods used at the landscape-scale (traditionally applied at smaller scales) can be used to explore critical zone architecture at the scales needed to explain the extreme variability in erosion rates across river profiles. © 2018 John Wiley & Sons, Ltd.     

Plurigaussian modeling of geological domains based on the truncation of non-stationary Gaussian random fields

The plurigaussian model is used in mining engineering, oil reservoir characterization, hydrology and environmental sciences to simulate the layout of geological domains in the subsurface, while reproducing their spatial continuity and dependence relationships. However, this model is well-established only in the stationary case, when the spatial distribution of the domains is homogeneous in space, and suffers from theoretical and practical impediments in the non-stationary case. To overcome these limitations, this paper proposes extending the model to the truncation of intrinsic random fields of order k with Gaussian generalized increments, which allows reproducing spatial trends in the distribution of the geological domains. Methodological tools and algorithms are presented to infer the model parameters and to construct realizations of the geological domains conditioned to existing data. The proposal is illustrated with the simulation of rock type domains in an ore deposit in order to demonstrate its applicability. Despite the limited number of conditioning data, the results show a remarkable agreement between the simulated domains and the lithological model interpreted by geologists, while the conventional stationary plurigaussian model turns out to be unsuccessful.