应用GPS数据与重力数据确定大地水准面

作为GPS/重力边值问题理论及方法的应用,在对GPS/重力方法确定(似)大地水准面的原理进行简要介绍与分析的基础上,利用收集到的N区的600个GPS/重力数据和48个高精度GPS水准数据,计算出该区域的(似)大地水准面。通过拟合法和系统差直接改正法进行的精度分析表明,应用GPS/重力数据结合水准方法确定的该地区(似)大地水准面的精度达到厘米级精度。     

辽东中生代晚期和古近纪玄武岩及深源捕虏晶--对岩石圈地幔性质的制约

辽东地区玄武岩的K-Ar定年结果表明,曲家屯玄武岩形成于晚白垩世,K-Ar年龄为81．58±2．46Ma;乱石山子玄武岩形成于古近纪,K-Ar年龄为58．36±1．64Ma。本区玄武岩含有丰富的橄榄石、单斜辉石和角闪石捕虏晶。乱石山子玄武岩中橄榄石捕虏晶的Mg^#值（79．5-88．5之间,平均值为84）较曲家屯玄武岩中橄榄石捕虏晶Mg^#值（77．0～79．8之间,平均值为78．4）偏高;单斜辉石捕虏晶为透辉石,其从核部到边部的Mg^#等变化趋势与橄榄石类似;斜方辉石捕虏晶为占铜辉石,其Mg^#值介于85．2-87．6之间,平均值为86．4。捕虏晶发育的环状裂隙、扭折带、矿物成分环带以及捕虏晶与主岩Mg^#值之间的不平衡均暗示它们为玄武质岩浆上升捕获的早期岩浆晶出矿物的堆晶体。玄武岩的岩石地球化学分析结果表明：（1）它们属于碱性系列,为碱性玄武岩,曲家屯玄武岩较乱石山子玄武岩贫硅、镁,富钙、铝,它们均具有原始岩浆的特征;（2）二者具有相似的稀土元素配分模式,但曲家屯玄武岩轻稀土元素总量更高,且轻重稀土元素分离程度高;（3）二者具有相似的Sr-Nd同位素组成,Isr和εNd（t）值分别介于0．7039～0．7045和＋1．60～＋3．69,反映了亏损的岩石圈地幔特征。     

钾长石分解反应热力学与过程评价

综述了添加各种助剂分解钾长石的研究进展。对不同体系中钾长石分解反应的G ibbs自由能和能耗计算,综合考虑一次性资源、能源消耗量和烧结过程的环境相容性、产品方案等因素,结果表明:只有以石灰石、碳酸钠为配料的工艺路线具有实际工业应用价值;而唯有以碳酸钠为配料时,钾长石原料烧结过程才具有一次性资源消耗量最少、能耗最低、温室气体CO2排放量最小、且可生产高附加值产品、实现完全清洁生产等优点。因此,选择以碳酸钠为配料分解钾长石的技术路线,具有良好的工业化应用前景。     

Diamond in Oceanic Peridotites and Chromitites: Evidence for Deep Recycled Mantle in the Global Ophiolite Record

Diamonds have been discovered in mantle peridotites and chromitites of six ophiolitic massifs along the 1300 km‐long Yarlung‐Zangbo suture (Bai et al., 1993; Yang et al., 2014; Xu et al., 2015), and in the Dongqiao and Dingqing mantle peridotites of the Bangong‐Nujiang suture in the eastern Tethyan zone (Robinson et al., 2004; Xiong et al., 2018). Recently, in‐situ diamond, coesite and other UHP mineral have also been reported in the Nidar ophiolite of the western Yarlung‐Zangbo suture (Das et al., 2015, 2017). The above‐mentioned diamond‐bearing ophiolites represent remnants of the eastern Mesozoic Tethyan oceanic lithosphere. New publications show that diamonds also occur in chromitites in the Pozanti‐Karsanti ophiolite of Turkey, and in the Mirdita ophiolite of Albania in the western Tethyan zone (Lian et al., 2017; Xiong et al., 2017; Wu et al., 2018). Similar diamonds and associated minerals have also reported from Paleozoic ophiolitic chromitites of Central Asian Orogenic Belt of China and the Ray‐Iz ophiolite in the Polar Urals, Russia (Yang et al., 2015a, b; Tian et al., 2015; Huang et al, 2015). Importantly, in‐situ diamonds have been recovered in chromitites of both the Luobusa ophiolite in Tbet and the Ray‐Iz ophiolite in Russia (Yang et al., 2014, 2015a). The extensive occurrences of such ultra‐high pressure (UHP) minerals in many ophiolites suggest formation by similar geological events in different oceans and orogenic belts of different ages. Compared to diamonds from kimberlites and UHP metamorphic belts, micro‐diamonds from ophiolites present a new occurrence of diamond that requires significantly different physical and chemical conditions of formation in Earth's mantle. The forms of chromite and qingsongites (BN) indicate that ophiolitic chromitite may form at depths of >150‐380 km or even deeper in the mantle (Yang et al., 2007; Dobrthinetskaya et al., 2009). The very light C isotope composition (δ13C ‐18 to ‐28‰) of these ophiolitic diamonds and their Mn‐bearing mineral inclusions, as well as coesite and clinopyroxene lamallae in chromite grains all indicate recycling of ancient continental or oceanic crustal materials into the deep mantle (>300 km) or down to the mantle transition zone via subduction (Yang et al., 2014, 2015a; Robinson et al., 2015; Moe et al., 2018). These new observations and new data strongly suggest that micro‐diamonds and their host podiform chromitite may have formed near the transition zone in the deep mantle, and that they were then transported upward into shallow mantle depths by convection processes. The in‐situ occurrence of micro‐diamonds has been well‐demonstrated by different groups of international researchers, along with other UHP minerals in podiform chromitites and ophiolitic peridotites clearly indicate their deep mantle origin and effectively address questions of possible contamination during sample processing and analytical work. The widespread occurrence of ophiolite‐hosted diamonds and associated UHP mineral groups suggests that they may be a common feature of in‐situ oceanic mantle. The fundamental scientific question to address here is how and where these micro‐diamonds and UHP minerals first crystallized, how they were incorporated into ophiolitic chromitites and peridotites and how they were preserved during transport to the surface. Thus, diamonds and UHP minerals in ophiolites have raised new scientific problems and opened a new window for geologists to study recycling from crust to deep mantle and back to the surface.     

从流体包裹体特征探讨泥堡金矿成因

泥堡金矿床据脉石矿物和萤石的包裹体研究,包裹少而小,类型较为简单。综合包裹体各项参数和气液成分分析认为,成矿流体属NaCl-H_2O体系的富K~ 的、弱酸性溶液,具有较高密度、较低盐度和中-低温度的特点。结合硫和氢氧同位素测定结果,成矿流体是燕山运动阶段的地表水沿断裂深循环,特别是在富K、富Au的凝灰岩中往复循环作用形成的。当各种条件具备时即可卸载成矿,成矿的最佳位置就是沿P_(2-3)β_1与P_2m~(dc)之间沉积间断面发生的层间滑动构造带。     

云南大坪金矿区煌斑岩的地球化学特征及成因探讨

大坪金矿区闪长岩体中发育多条煌斑岩脉,并且多伴随石英脉出现。在岩石化学组成上,SiO2含量为44.86%~54.10%、K2O/Na2O在0.56~2.09之间,属钾玄质系列;岩石富集大离子亲石元素(Sr、U、Rb和Ba)和轻稀土元素(LREE)、相对亏损高场强元素(Ta、Nb和Ti),且Ta、Nb和Ti具"TNT"负异常;δEu值为0.72~1.36,负Eu异常不明显;87Sr/86Sr值范围为0.706 6~0.707 4,均值0.707 1,高于原始地幔现代值0.704 5;143Nd/144Nd值范围为0.512 4~0.512 5,均值0.512 4,低于原始地幔现代值0.512 638;εNd值范围为-2.5~-4.2,均值-3.98。Nb/Ta比值为48.96~82.58(平均62.99),远高于原始地幔值的17.5±2.0;Zr/Hf比值为20.45~47.53(平均39.57),略高于原始地幔值的36.27±2.0;Nb/Ta和Zr/Hf都远大于陆壳值11和33。表明煌斑岩源区可能来自早期俯冲洋壳或造山带根部拆沉组分脱水形成富集流体在地幔源区发生交代作用形成的富集地幔,岩浆在上升侵位过程中受到地壳物质的混染较弱,形成于碰撞后的板内构造环境。     

藏南冈底斯岩基日多地区花岗岩体形成时代和地球化学特征

冈底斯岩基广泛发育三叠纪-中新世的岩浆岩,是研究与新特提斯洋北向俯冲和印度-欧亚大陆碰撞相关的构造岩浆作用特征的天然实验室。日多地区花岗岩体位于藏南墨竹工卡县东侧日多乡附近,其主体为花岗岩,被花岗闪长玢岩脉侵入。锆石U-Pb地质年代学表明:主体花岗岩形成于62.7±0.5Ma,侵入其中的花岗闪长玢岩脉形成于59.5±1.5Ma,并捕获了大量的侏罗纪岩浆岩锆石(155.4±1.8Ma)。日多地区花岗岩体的全岩地球化学特征为:(1)高Si O_2、Na_2O、Al_2O_3,低Fe O~T、MgO、Ti O_2;(2)富集轻稀土(LREE),亏损重稀土(HREE)及高场强元素Nb、Ta、Ti、P元素;(3)具有Eu负异常,总体显示高钾钙碱性、过铝质花岗岩和岛弧型岩浆岩特征。锆石Hf同位素特征暗示其岩浆源区为基性下地壳物质。花岗闪长玢岩脉裹挟大量侏罗纪岩浆型锆石,表明冈底斯岩基拉萨以东地区可能经历了较广泛的晚侏罗世岩浆作用。     

煤与瓦斯突出预报的理想灰贴近函数聚类关联分析

从预报煤与瓦斯突出所获取的数据信息知，其信息多数为灰色特征。为突出其灰色特性，本文采用理想灰贴近函数聚类关联分析预测预报煤与瓦斯突出的危险程度，并将此方法同模糊聚类预测预报法和模糊聚类关联分析预报法及模糊聚类相似分析预报法进行了对比分析。由对比分析可知，采用4种数学方法预测预报煤与瓦斯是否突出，给出的结论是一致的，只是预测预报是否发生的可能程度略有差别。其中关联分析比相似分析计算过程较简单，且相似分析在确定编号时，有时受截值λ取值影响。尽管如此，但不影响预测预报结果。所以，不论是采用模糊聚类，还是灰色聚类数学方法预报煤与瓦斯突出均是可行的，可在实践中应用。     

地下水超采对农业灌溉的影响及对策研究

在北方一些灌区,由于地下水的过量开采,出现了水位持续下降、地下水矿化度增加、土壤盐渍化等一系列环境问题.一些灌区对地下水的可采资源量估计过高,造成目前超采仍有进一步发展的趋势.因此必须采取有效措施控制地下水超采,实现灌区农业的可持续发展、保护环境.讨论灌区地下水超采的判别方法、超采对灌区的影响、以及应采取的对策.     

黄河上游地区气候变化及其对黄河水资源的影响

通过对1961年以来黄河上游地区气候变化的分析,发现黄河源区进入80年代中后期以后,年平均气温上升趋势非常明显,特别是1998年的年平均气温竟达到-2.1℃,是40年来年平均气温最高的一年;进入90年代,春季和夏季温度急剧回升.黄河上游地区年平均降水量及秋季降水量无明显的变化趋势,且其年际间的波动趋于缓和;冬季(12～2月)和春季(3～5月)降水量的变化趋势呈现出逐年增多的趋势;夏季(6～8月)降水量变化趋势却表现出显著的减少趋势.同时,分析了38年黄河上游径流量及其与流域降水、气温的关系,着重分析了干旱气候对黄河水资源的影响.结果表明,黄河上游地区水资源呈减少趋势,其减少趋势进入90年代后尤为明显.这一变化趋势与黄河上游地区夏季降水量变化趋势有着一致性,说明汛期降水量的减少是黄河上游流量减少的最直接的气候因子.