小秦岭某金矿区农田土壤重金属元素污染的潜在生态危害评价

土壤重金属元素污染的潜在生态危害程度及空间分布是土壤污染防治的前提和基础。为揭示土壤中重金属元素的潜在生态危害程度,在前期土壤污染调查评价的基础上,采用Hakanson的潜在生态危害指数,以研究区西邻无工矿影响的农田土壤重金属元素含量均值作为参比值,对矿区农田土壤进行了重金属元素污染的潜在生态环境危害评价。结果表明,Hg是农田土壤中潜在生态危害最严重的元素,其次是Cd和Pb。Hg、Pb、Cd对土壤污染危害的贡献率之和达97.41%,仅Hg的贡献率就达84.37%。多个重金属元素潜在生态危害很强、极强的土壤样品占样品总数的49.62%,影响面积达74.54%。从西北向东南,土壤重金属元素潜在生态危害程度激增,这种空间分布与目前金矿选冶的布局一致。土壤重金属元素潜在生态环境危害的后果已被前期研究成果所证实。     

The paleoclimatic records and the relevance with the formation of hydrocarbon source rocks:A case study of Huanghekou depression,Bohaiwan basin

Bohaiwan basin, covering an area of 200 000 km², is one of the most important oil-bearing basins in Eastern China. Rifting processes formed the basin, and two evolution phases can be recognized. The rifting phase developed in Paleogene, and post-rifting phase occurred in Neogene. More than 200 oil fields have been found in the onshore and offshore area in Bohaiwan basin in recent years. The distribution of the oil fields is closely related to the rich hydrocarbon depressions, and the Huanghekou depression is one of these rich hydrocarbon depressions. A number of large and medium-sized oil and gas fields have been found in this area, such as BZ25-1, BZ34 etc., and the hydrocarbon was mainly from the Huanghekou depression. The formation of rich hydrocarbon source rocks depended on the tectonic setting of rapid subsidence, favorable paleoclimatic conditions and paleolimnology environments. The effects of paleoclimatic condition on hydrocarbon source rocks are the focus of this paper. __________ Translated from Geological Bulletin of China, 2007, 26(7): 830–840 [译自: 地质通报]     

造山带沉积盆地构造原型恢复

沉积盆地是造山带中最为重要的构造单元之一,其中分布有丰富的矿产资源.这些盆地的构造原型恢复可为造山带的构造演化、板块构造重建和区域找矿提供重要依据.盆地充填物的组成(包括矿床)、时代、物源区及充填序列是进行造山带古沉积盆地构造原型恢复的基础.通过沉积相、砂岩/砾岩碎屑组成、碎屑时代、构造环境、碎屑重矿物、细碎屑岩的地球化学组成、古水流、生物组合等方面对盆地充填物形成的沉积环境、沉积物源区、形成时代和盆地基底属性进行综合研究,借助对现代沉积盆地的研究结果和沉积盆地的构造分类原则,恢复造山带内古沉积盆地的构造原型.     

陕西潼关金矿区太峪河底泥重金属元素的含量及污染评价

通过对潼关金矿区太峪河和太峪水库底泥中重金属元素总量的调查,探讨了金矿开发活动中重金属元素对河流底泥的污染程度。研究结果表明,除As外,河流底泥中重金属元素的含量与尾矿渣中重金属元素的含量变化一致,表明其主要来源于尾矿渣,但又明显高于尾矿渣。在同一地点河流底泥中重金属元素的含量平均高出河水中的1048.61～666030.08倍,呈显著富集。以邻近地区不受工矿活动影响的河流底泥重金属元素的含量均值作为评价参比值,太峪河底泥受到了Hg、Pb、Cd、Cu、Zn元素的极度污染,单项污染超标倍数及综合污染指数法评价结果表明,Hg、Pb、Cd平均污染超标倍数达366.90、217.42和149.97,是底泥中最主要的污染元素。河流底泥重金属元素的综合污染指数高达278.97,表明河流的复合污染亦呈极度状态。太峪河底泥受重金属元素极度污染的现实提示,矿区的环境防治工作已刻不容缓。     

四川盆地泸州古隆起嘉陵江组储层特征研究

对研究区嘉陵江组沉积背景认识的基础上,通过岩心观察、岩石薄片确定了不同类型的储集岩和储集空间,得出本地区储层岩石类型和储渗空间类型均多样化的特点。从成因角度识别出来了溶蚀孔隙型储层、膏溶孔洞型储层、裂缝型储层等三类储层。研究不同类型储层的孔、渗特征及关系表明,溶蚀孔隙型储层物性要优于膏溶孔洞型储层,而溶蚀孔隙型储层中的颗粒云岩溶蚀孔隙型储层物性最好、颗粒灰岩溶蚀孔隙型物性其次、粉晶云岩溶蚀孔隙型储层物性最差,其原因是不同储层受沉积环境和成岩作用控制和影响。     

钢筋混凝土圆环内支撑在软土深基坑支护中的设计与应用

通过对星河世纪城B2地块工程基坑成功支护设计实例介绍,全面阐述了钢筋混凝土圆环内支撑体系独特的布置形式、内力计算模式、方法和结果,以及在施工过程中的质量保证,为软土地基中类似基坑工程提供借鉴。     

(ϖμ/ϖT) P of the lower mantle

We estimate (/T) _P of the lower mantle at seismic frequencies using two distinct approaches by combining ambient laboratory measurements on lower mantle minerals with seismic data. In the first approach, an upper bound is estimated for |(/T) _P | by comparing the shear modulus () profile of PREM with laboratory room-temperature data of extrapolated to high pressures. The second approach employs a seismic tomography constraint ( lnV _S / lnV _P ) _P =1.8–2, which directly relates (/T) _P with (K _S /T) _P . An average (K _S /T) _P can be obtained by comparing the well-established room-temperature compression data for lower mantle minerals with theK _S profile of PREM along several possible adiabats. Both (K _S /T) and (/T) depend on silicon content [or (Mg+Fe)/Sil of the model. For various compositions, the two approaches predict rather distinct (/T) _P vs. (K _S /T) _P curves, which intersect at a composition similar to pyrolite with (/T) _P =–0.02 to –0.035 and (K _S /T) _P =–0.015 to –0.020 GPa/K. The pure perovskite model, on the other hand, yields grossly inconsistent results using the two approaches. We conclude that both vertical and lateral variations in seismic velocities are consistent with variation due to pressure, temperature, and phase transformations of a uniform composition. Additional physical properties of a pyrolite lower mantle are further predicted. Lateral temperature variations are predicted to be about 100–250 K, and the ratio of ( lnp/ lnV _S ) _P around 0.13 and 0.26. All of these parameters increase slightly with depth if the ratio of ( lnV _S / lnV _P ) _P remains constant throughout the lower mantle. These predicted values are in excellent agreement with geodynamic analyses, in which the ratios ( ln / lnV _S ) _P and ( / lnV _S ) _P are free parameters arbitrarily adjusted to fit the tomography and geoid data.     

The Epi－continental arc of Southeast China and relevant earthquakes

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Electron microscopy study of domain structure due to phase transitions in natural perovskite

Transmission electron microscopy on natural calcium metatitanate perovskite (dysanalyte) reveals the following twin laws in the orthorhombic (space group Pbnm) phase: reflection twins on the {110} and {112} planes, and 90° rotation twins about the [001] axis (referred to as [001]_90° twin). Single crystals that were heattreated and quenched from above 1585 K exhibit a dramatic change in domain structure compared with the starting material and specimens quenched from T < 1470=" k.=" mutually=" perpendicular=" {110}=" and=">_90° twins are observed throughout the crystal, forming a cross-hatched domain texture. 1/2[001] antiphase domains, which are very rarely observed in the starting material, also become dominant in the crystal. This change in domain structure is interpreted as due to a structural phase transition in perovskite at a temperature below 1585 K. From the point symmetry elements that describe the twin laws and the translational elements that relate the antiphase domains, the most likely phase near 1585 K is tetragonal with space group P4/mbm. These results are consistent with high-temperature powder X-ray diffraction study. On the other hand, density of the {112} twins is increased significantly in the crystal quenched from 1673 K. Twin domains are either bound by mutually perpendicular {110} and (001) walls, or by {112} walls with {110} twin domains within the polygonal {112} domains. Both twin density variation and domain morphology suggest that the crystal may be cubic at this temperature. Microstructure of a single crystal deformed at 1273 K and 3.5 GPa (within the orthorhombic stability field) is morphologically quite distinct from that of the heat-treated specimens. Dislocations dominate the microstructure and often interact with twin domain boundaries.A National Science Foundation Science and Technology Center     

生物炭对磷石膏中磷的固化作用

磷石膏中的磷在雨水淋滤作用下浸出,将污染堆场附近水体。本研究采用生物炭固化磷石膏中的磷,以减少其对周遭水体的污染。主要通过模拟固化实验和对照浸出实验,分析生物炭用量、反应时间和温度、初始pH值对固化效果的影响,通过XRD、SEM-EDS分析固化后的生成物。实验结果显示,在生物炭用量为25 mg时,单位固化量达到最大值13.20 mg/g;在反应温度T=293 K、初始pH=7条件下,反应平衡时间72 h时浸出液的磷平衡浓度C_e= 1.40 mg/L;温度提升有助于提高生物炭的固化效果,当T=308 K时,浸出液的磷平衡浓度C_e=0.167 mg/L;碱性条件有利于固化反应持续进行,在pH=11条件下,浸出液的磷平衡浓度C_e=0.153 mg/L。实验结果表明生物炭对磷石膏中的磷具有明显的固化效果。磷石膏中的二水硫酸钙溶解后,Ca²⁺与表面带负电的生物炭结合,在生物炭显微结构的凹陷处,化学吸附溶液中的磷酸根生成了絮状、团簇状的羟基磷灰石(HAP)沉淀,从而使浸出磷得到有效控制。