广西大气能见度气候特征分析

对1980至2012年广西85个县市能见度资料进行统计分析得出：广西主要城市及其周边地区能见度较低,边远山区及边境地区较高,呈现东部低、西部高的特点;广西近32a能见度年均值在14.4至18.2km之间,总体呈下降趋势.一年之中,能见度夏季高、冬季低,汛期能见度明显好于非汛期;能见度与气象要素的相关分析表明,能见度与温度、风速成正比,与压强、降水、湿度成反比.     

基于遗传小波神经网络的海底声学底质识别分类

分割海底声纳探测图像,提取单元特征向量进行主成份分析,选取均值、标准差、对比度、相关系数、能量及同质性作为训练特征向量,构建小波神经网络。利用遗传算法优化小波神经网络的初始权值及小波参数,对砂、礁石、泥3种底质类型分别进行训练,并得到3种底质的测试精度都在90%以上,优于单独利用小波神经网络进行训练时的测试精度,克服了小波神经网络训练时易陷入局部极小的固有缺陷,表明基于遗传算法的小波神经网络可有效用于海底底质声纳图像的识别和分类。     

Ecological indicators showing the succession of macrofauna communities in Sonneratia apetala artificial mangrove wetlands on Qi’ao Island at Zhuhai, South China

The Sonneratia apetala artificial mangroves in the intertidal zone of Da Wei Bay at Qi’ao Island of Zhu-hai, South China were chosen as the macrofauna succession plots while bare tidal flats of the same size were established as control plots in surrounding interference-free areas. Conventional change indicators of community structure, such as biomass and biodiversity, and indicators, such as exergy and specific exergy, which reflect the information change of overall communities, were used to analyze the succession of macro-fauna communities inS. apetala artificial mangroves. The similarities and differences in variation tendency of the different ecological indicators and their reflected ecological principles were compared. The results showed that from D-1 to D-1275 after plantingS. apetala, the biomass of the macrofauna communities first increased, which was then followed by an increase in the network relationship between the macrofauna communities （analysis of the Pielou evenness index and Shannon-Wiener diversity index）. The system in-formation （specific exergy） increased the slowest. Between D-1460 and D-2370 after plantingS. apetala, there was a decrease in biomass, network structure, and system information in the succession plots. After the decrease in the system information （the specific exergy）, there was a decline in the network relationships （Pielou evenness index and Shannon-Wiener diversity index）. Biomass was the last indicator to decrease. The similarities and differences among the different ecological indicators varied during the succession pro-cess, which reflected the relativity and differences among the indicators. This study suggested that, although the species diversity index can be an effective indicator of two types of changes （network structure and system information）, it was quite clear that species diversity measurement was not suitable for expressing the changes in biomass during the succession process. While exergy and specific exergy can provide useful information     

广西北仑河口红树林保护区表层海水溶解态重金属时空分布及其影响因素

根据2013年5月(春季)和8月(夏季)对广西北仑河口红树林保护区的现场调查监测数据,研究了表层海水中溶解态重金属Cu、Zn、Pb、Cd、Cr、As、Hg的时空分布特征,探讨了其影响因素,并对其污染水平进行了评价。结果表明,表层海水各溶解态重金属的浓度、空间波动程度在春、夏季均存在一定的差异;Hg的污染明显超过国家一类海水水质标准,且夏季污染水平高于春季。Cu-Zn、Cu-Cd、Zn-Pb、Zn-Cd之间存在显著正相关,春、夏季As以及夏季Cr分别与盐度之间呈显著正相关,其他重金属与盐度之间无显著相关性。各重金属的时空分布主要受到陆源输入、沿岸江河冲淡水和海水盐度变化等因素的影响。     

花岗岩类土质边坡工程特性及加固方法研究

华南、华东南地区具有厚度可达上百米的花岗岩风化残积层。高等级公路、铁路的规模建设在该地区形成了大量的花岗岩类土质高边坡。深入认识该类边坡的工程特性并提出有效的针对性边坡加固方法,对该地区公路、铁路的安全建设和正常运营具有重要意义。为了更有效指导该类边坡的稳定性分析及边坡设计,本文深入调查分析了广东和广西境内4条高等级公路沿线的44处花岗岩类土质边坡特征及其稳定性,认为控制该类边坡稳定性的因素主要有:土体的均匀性、岩脉(墙)及花岗岩球状硬核的分布情况、坡体中保留的结构面是否对坡体稳定性起控制作用。继而依据这些因素把花岗岩类土质边坡划分为岩脉(墙)隔挡型边坡、网状结构型边坡、外倾结构型边坡、浮石型边坡4种类型。深入分析了每种类型边坡的坡体结构特征、稳定特性,针对性地提出了边坡稳定性分析中应重点考虑的因素。认为花岗岩类土质边坡的土质及坡体结构特征,造成了该类边坡开挖临时自稳性较好,但具有较强的开挖卸荷效应和较弱的抗冲刷能力。最后针对每种类型的花岗岩类土质边坡,提出了相应的设计方案建议。基于花岗岩类土质边坡良好的临时自稳性,认为可进行陡开挖强支护设计,同时强调逐级开挖逐级支护、加强坡面防冲刷、边坡护脚及压顶、边坡截排水等设计建议。     

青海格尔木哈希牙地区中基性岩墙群地球化学特征与LA-ICP-MS锆石U-Pb年龄

位于东昆仑造山带上的东昆北哈希牙地区发育中基性岩墙群。其岩性主要为辉绿岩、闪斜煌斑岩和闪长玢岩,地球化学数据显示其具有高钾钙碱性玄武岩系列特征。轻、重稀土元素存在较高程度分馏,LREE/HREE值为4.72~8.66,平均值为6.57。δEu值介于0.81~0.98之间,平均值为0.91,显示出微弱的负Eu异常,表明斜长石的分离结晶作用不明显,富集Rb、Ba、Pb、K等大离子亲石元素,贫高场强元素Ta、Nb、Zr、Hf等地球化学特征,主体显示板内玄武岩特征,但有来自俯冲带的部分信息。采用LA-ICP-MS技术对锆石进行了U-Th-Pb同位素测定,结果显示锆石年龄较为分散,其中8颗岩浆锆石给出的206Pb/238U年龄加权平均值为411.5±7.5Ma,代表了格尔木哈希牙地区辉绿岩墙的结晶年龄,反映东昆北地块于晚志留世—早泥盆世已由地体碰撞的挤压状态转为碰撞后伸展状态,标志着该地区加里东期构造旋回的结束。     

Microbiological degradation of phenol using two co-aggregating bacterial strains

Phenol biodegradation in an aerobic batch reactor was investigated using mixed two co-aggregating strains (Flavobacterium sp. and Acetobacter sp.). Response surface methodology by the Box–Behnken model was used to evaluate the optimal cell growth and phenol degradation conditions. The optimum temperature, pH value and inoculum size were found to be 33 °C, 6.06 and 13 %, respectively. In the conditions, phenol degradation rate and biomass were predicted to be 96.97 % and 410.78 mg/L within the range examined, respectively. Less toxic acetaldehyde, ethanol and acetic ether were identified as main intermediate products from the degraded samples using GC–MS. Substrate inhibition was calculated from experimental biomass growth and phenol degradation parameters using the Haldane equation. Kinetic parameters derived from nonlinear regression with correlation factors (R ²) were 0.9682 for phenol degradation and 0.9594 for biomass growth, respectively. The phenol concentration to avoid substrate inhibition was 278.17 mg/L.     

微波等离子体炬质谱技术快速鉴别天然石材与人造石材

天然石材主要有大理石、花岗岩等;人造石材多以不饱和聚酯树脂为基料,添加适量的无机物粉料和添加剂固化制成。由于石材种类繁多,并且各种石材的岩体所含矿物成分也有差异,当前很少应用化学成分分析方法准确、快速鉴别天然和人造石材,仅有的红外光谱法由于对待测物纯度的要求较高而具局限性。本文基于微波等离子体炬源(MPT)同时具有热解吸与强电离能力,能在短时间内离子化待测物的特点,采用微波等离子体炬质谱(MPT-MS)技术,无需样品复杂预处理直接对天然与人造石材进行分析,获得正离子检测模式下在m/z 50~1000之间的石材的指纹谱图,并运用化学计量学的主成分分析(PCA)方法处理所获取的数据,实现了不同建筑石材的区分。结果表明,MPT-MS能够获得石材丰富的指纹谱图,结合PCA方法能够快速鉴别天然石材与人造石材,天然石材中解吸出的物质主要为CO₂和H₂O的团簇分子;而人造石材中解吸出的主要成分为有机物(人为添加的黏合剂等)。本研究采用的MPT-MS技术无需采用喷雾、激光、基质和加热等方法辅助,并且无需对石材进行任何复杂的处理即可进行质谱分析,从而获取石材表面及内部物质的质谱信息,为快速直接鉴定石材样品提供了一种新的质谱分析方法。     

江西香炉山矽卡岩型钨矿床流体包裹体研究

从江西西北部至安徽南部发育一条显著的斑岩-矽卡岩型钨成矿带,香炉山是其中一典型的矽卡岩钨矿床。矿床具有明显的矿化分带特征,由近接触带矽卡岩和云英岩矿体和远接触带脉状石英-硫化物-白钨矿和透镜状矿体组成。通过对不同蚀变带上矿石矿物和脉石矿物的流体包裹体显微测温分析表明:矽卡岩中的流体包裹体的均一温度范围在209～383℃,脉状石英-白钨矿和石英-硫化物-白钨矿中流体包裹体的均一温度范围分别为163～278℃和204～284℃,晚期方解石脉的温度最低为143～235℃;矽卡岩中的流体包裹体的盐度范围在0.35%～5.26%NaCleqv,脉状石英-白钨矿和石英-硫化物-白钨矿中流体包裹体的盐度范围分别为0.35%～5.86%NaCleqv和0.70%～9.21%NaCleqv,晚期方解石脉的盐度为0.35%～2.07%NaCleqv。激光拉曼探针测试表明,矽卡岩、石英-白钨矿脉和石英-硫化物-白钨矿脉中流体包裹体组分主要为H2O,还含有一定量CH4和少量的N2。从早期到晚期成矿阶段表现为一个降温的过程,指明了钨成矿温度较宽泛;钨在流体中可能以钨酸的形式运移,与围岩反应时,温度降低和碱性升高,促使白钨矿沉淀成矿。早期到晚期成矿流体温度和物质组成发生变化是成矿发生分带的重要原因。