高效钻杆润滑脂研制及其在川藏铁路勘察中的应用

针对地质钻探深孔或水平孔失返性漏失时钻具磨损及钻进效率低的问题,以白油、钠基稠化剂与粘结性材料等为原料,采用一步法研制了一种高效钻杆润滑脂,并在川藏铁路昌都段定测勘察水平孔现场应用中取得显著效果,有力支撑服务了川藏铁路大位移水平孔施工。室内评价及现场应用结果表明,该润滑脂具有耐低温（-16 ℃）、易涂抹、良好的粘附性与润滑性以及高性价比特点,能长时间保护钻具,而且其润滑效果与国外同类产品相当。     

欠平衡钻井技术在梨深1井的应用

欠平衡钻井技术是准确发现和评价油气资源的方法之一,尤其适合评价和开发低压低渗油气层。介绍了梨深1井四开井段实施欠平衡钻井技术的详细情况。该井四开钻井液密度0.90～1.05 g/cm3,使钻井液液柱压力低于地层压力,地层大量气体侵入井筒,进一步增大井底欠压差。自井深3582.5 m后一直维持点火钻进,为后续井钻井施工提供了很好的借鉴。     

云南个旧锡铜矿集区石榴子石地球化学特征及成矿指示

云南高松矿床中高峰山矿段和老厂矿床中竹叶山矿段分别是个旧超大型锡铜多金属矿集区发育的典型矽卡岩型锡、铜矿段。为查明个旧矿集区锡铜成矿环境的差异,文章选取上述2个矿段矽卡岩中的石榴子石为研究对象,根据产状和矿物共生关系将石榴子石分为与高峰山花岗岩有关早期（Grt-GS1）、晚期（Grt-GS2）、与竹叶山花岗岩有关（Grt-ZS）和与玄武岩有关（Grt-ZX）共4类。电子探针（EPMA）和激光剥蚀等离子质谱（LA-ICP-MS）分析表明：Grt-GS1(Adr_10.58-20.27Grs_38.62-48.28Spe_21.06-32.37Alm_11.88-18.03)成分复杂且变化范围较大,而Grt-GS2(Adr_48.09-69.73Grs_23.84-48.87Spe_3.29-9.58)和Grt-ZS (Adr_13.97-16.06Grs_78.08-79.71Spe_2.15-2.60)成分简单且变化小;稀土元素配分曲线均呈HREE富集、LREE亏损的“左倾型”,并具明显的负Eu异常。Grt-ZX成分简单且较均一(Adr_20.12-21.99Grs_70.84-71.44Pyr_6.29-7.92),稀土元素配分曲线呈HREE亏损、LREE富集的“右倾型”,呈明显的正Eu异常,且F、Cl、U、Th、Pb、V、Cr、Co、Ni、Zn、Ti等元素含量均高于其余3类石榴子石。所有石榴子石REE³⁺与Mg²⁺的正相关性表明,REE³⁺受[X²⁺]Ⅷ-1[REE³⁺]Ⅷ+1[Y³⁺]Ⅳ-1[Y²⁺]Ⅳ+1替换机制的控制,REE³⁺主要替代Mg²⁺进入石榴子石晶格。石榴子石的U、Sn含量及稀土元素配分特征指示：高峰山石榴子石（Grt-GS1和Grt-GS2）在演化过程中氧逸度明显升高、竹叶山石榴子石（Grt-ZS和Grt-ZX）形成的氧逸度总体高于高峰山,但Grt-ZX形成时氧逸度低于Grt-ZS。稀土元素特征显示：Grt-GS1、Grt-GS2与Grt-ZS均形成于弱酸性环境,而Grt-ZX形成于近中性且富F、Cl的环境下。∑REE³⁺与Y呈良好的正相关性和REE含量变化指示4类石榴子石均形成于封闭或近封闭的体系中,在接近平衡和低水岩比的条件中受扩散交代作用缓慢生长而形成。综合研究表明,玄武岩对成矿的影响在于改变了流体性质,为成矿提供了大量微量元素（如Co、Ni、V、Cr等）和有利于成矿离子运移和富集的卤族元素（如F、Cl）,而高峰山矿段锡富集的原因可能是在演化过程中水岩反应的加强和氧逸度的升高。     

Geology and Lead–Sulphur Isotope Compositions of the Tongyu Volcanic-Hosted Massive Sulphide Copper Deposit in the Western Part of the North Qinling Orogen, China

The Tongyu copper deposit, located in the western part of the North Qinling Orogen, China, is one of several volcanic-hosted massive sulphide(VHMS) deposits with industrial value and is also a typical example of mineralization related to the subduction and metallogenesis during the Caledonian orogeny. We conducted systematic lead-sulphur isotope geochemical analyses of the Tongyu deposit to understand the possible ore-forming material sources and tectonic settings. Twenty-six sulphide samples yielded clustered δ~(34)S_(CDT) values of 1.13‰-3.36‰, average 2.22‰, and show a tower-type distribution,implying that the sulphur of the Tongyu copper deposit mainly originated from a mantle source. The Pb isotope compositions of sulphides(~(206)Pb/~(204)Pb = 17.59225-18.56354, average 18.32020; ~(207)Pb/~(204)Pb =15.51770-15.69381, average 15.66217; ~(208)Pb/~(204)Pb= 37.99969-39.06953, average 38.52722) are close to the values of the volcanic host rocks(~(206)Pb/~(204)Pb= 18.10678-18.26293, average 18.21158; ~(207)Pb/~(204)Pb =15.63196-15.68188, average 15.65345; ~(208)Pb/~(204)Pb= 38.43676-38.56360, average 38.49171), thus consistent with the Pb in ores and volcanic host rocks having been derived from a common source that was island-arc Pb related to oceanic crust subduction. The northward subduction of the Palaeo-Qinling oceanic crust triggered dehydration of the slab, which generated a large amount of high-oxygen-fugacity aqueous hydrothermal fluid. The fluid rose into the mantle wedge, activated and extracted metallogenic material and promoted partial melting of the mantle wedge. The magma and ore-forming fluid welled up and precipitated, finally forming the Tongyu VHMS copper deposit.     

浆混花岗岩专题填图方法初探——以东昆仑加鲁河地区为例

东昆仑造山带花岗岩中广泛发育暗色微粒包体,含有丰富的壳幔岩浆混合作用的证据,被认为是研究岩浆混合作用的天然场所。适逢近阶段同源花岗岩谱系填图方案在造山带岩浆混合(浆混)花岗岩图区实践时深受质疑,本研究以东昆仑加鲁河地区浆混花岗岩为例,开展浆混花岗岩区专题填图试点工作,旨在探索一套适合浆混花岗岩填图的岩石单位划分方案。从野外地质、岩相学、岩石和矿物化学等不同角度论证了加鲁河花岗闪长岩及其内部包体形成于开放体系下的壳幔岩浆混合作用。在填图工作中,将图区内的岩浆岩划分为浆混花岗岩和非浆混花岗岩2个超单元。以岩浆混合作用为理论依据,将浆混花岗岩超单元划分为基性端元、酸性端元和浆混产物3个二级单位,对于2个端元岩石单位按照其矿物组成、结构构造等方面的差异(岩浆演化导致)再次划分最基本岩石单位——侵入体,对于浆混产物单位,建议可按照岩浆混合程度差异或者内部包体变化规律灵活划分基本岩石单位——浆混体。由此建立了一套可与同源花岗岩谱系单位相兼容的浆混花岗岩谱系单位划分方案,为岩浆混合花岗岩区开展填图工作提供了初步探索方案。     

Multi‐stage Melting Processes of Ophiolitic Chromitites from Purang Peridotite,the Western Yarlung‐Zangbo Suture Zone,Tibet

The Purang ophiolite, which crops out over an area of about 600 km2 in the western Yarlung‐Zangbo suture zone, consists chiefly of mantle peridotite, pyroxenite and gabbro. The mantle peridotites are mostly harzburgite and minor lherzolite that locally host small pods of dunite. Some pyroxenite and gabbro veins of variable size occur in the peridotites, and most of them strike NW. On the basis of their mineral chemistry podiform chromitites are divided into high‐alumina (Cr# = 20‐60) (Cr# = 100*Cr/(Cr+Al)) and high‐chromium (Cr# = 60‐80) varieties (Thayer, 1970). Typically, only one type occurs in a given peridotite massif, although some ophiolites contain several massifs which can have different chromitite compositions. However, the Purang massif contains both high chrome and high alumina chromitites within a single mafic‐ultramafic body. Seven small, lenticular bodies of chromitite ore have been found in the harzburgite, with ore textures ranging from massive to disseminated to sparsely disseminated; no nodular ore has been observed. Individual ore bodies are 2‐6 m long, 0.5‐2 m wide and strike NW, parallel to the main structure of the ophiolite. Ore bodies 1 and 6 consist of Al‐rich chromitite (Cr# = 52‐55), whereas orebodies 2, 3, 4 and 5 are Cr‐rich varieties (Cr # = 63 to 89). In addition to magnesiochromite, all of the orebodies contain minor olivine, amphibole and serpentine. Mineral structures show that the peridotites experienced plastic deformation and partial melting. On the basis of magnesiochromite and olivine/clinopyroxene compositions two stages of partial melting are identified in the Purang peridotites, an early low‐partial melting event (about 8%), and a later high‐partial melting event (about 40%). We interpret the Al‐rich chromitites as the products of early MORB magmas, whereas the Cr‐rich varieties are thought to have been generated by the later SSZ melts..     

渝东北地区五峰组—龙马溪组页岩气地质特征及其勘探方向探讨

渝东北地区五峰组—龙马溪组暗色泥页岩沉积厚度介于30.92~164.47m之间,其中在朝阳镇咸池剖面及田坝一带厚度最大,往研究区东西两侧具有减薄的趋势。全区总有机碳含量平均3.32%,中部(平均3.93%)和西部(平均3.59%)相对东部(平均2.77%)具有更高的有机质丰度。有机质以I型腐泥型为主,西部个别剖面及东部栗子坪一带夹少量Ⅱ_1—Ⅱ_2型干酪根,其成熟度普遍处于高成熟—过成熟阶段,呈现自北向南升高的趋势。石英、脆性矿物含量普遍较高(尤其是中西部区块),黏土矿物较低,更易产生储气裂缝及利于后期压裂。储层特征方面,中部地区泥页岩具有更高的孔隙度和较低的渗透率,同时比表面积也相对更高,以有机质孔隙为主。中部区块田坝—朝阳—文峰一带含气性最好,结合页岩厚度、总有机碳含量分布、储层条件及构造保存条件分析,本区中部区块田坝—朝阳—文峰一带具有更好的页岩气勘探前景,是该区下一步勘探的重点区域。     

花海盆地深地震反射剖面的最佳采集参数实验和分析

深地震反射方法是探测地壳深部结构的先锋技术,能获取到莫霍面和上地幔的反射图像,成为揭示岩石圈结构、解决深部地质构造问题的有效手段。花海盆地位于河西走廊盆地群西部,处于不同大地构造单元的交汇部位,地层发育较全,但出露和发育程度差异较大,除白垩系为大面积连续分布外,其他各时代的地层均出露不全,常表现为被侵入岩分割破坏的残块状,为了确定深地震反射在花海盆地适合的采集参数,在采集前开展点试验,进行小、中、大炮炸药井炮激发参数对比优选,最终得到最优化的采集参数。在小炮实验中,36 kg药量取得的反射信息没有48 kg和60 kg的丰富,而且在MOHO反射的清晰度上48 kg和60 kg药量更为清晰,单井激发比组合井激发效果好;在中炮和大炮实验中,不同组合井对比差异不大,随着药量增大,激发能量增大,面波、折射波等干扰波能量也在增大,小炮干扰波能量最弱,反射信息最丰富的,中炮和大炮干扰波较发育,但通过后期去噪处理,也能得到中浅层反射信息。     

生烃动力学模拟实验结合GC-RMS测定在有效气源岩判识中的应用

采用动力学模拟实验对Ⅰ型干酪根的生烃过程进行了模拟,并对热解产物中的正烷烃组分进行了GC-IRMS分析。分析结果表明,当Ro<1.6%时,C8+正烷烃的碳同位素组成主要继承了母质的特征,而随热演化程度的变化不显著,因此可用于油(气)/源对比。当Ro在1.6%～2.0%之间时,C8+正烷烃迅速裂解,其δ13C显著增重。Ro>2.0%之后,C1—C4气态烃随热演化程度的增加,逐渐富集13C,其δ13C与Ro之间的关系明显受升温速率的影响,所以由模拟实验获得的δ13C1-Ro关系式不适用于高—过成熟的气源岩研究;而δ13C1-F(甲烷生成率)的关系则不受升温速率的影响,适用范围较宽,故可用于高演化阶段的有效气源岩的判识。     

西藏地堡那木岗矿区水系沉积物地球化学特征及找矿预测

利用SPSS等软件对矿区1：5万水系沉积物地球化学数据分析,选用平均值±3倍标准差（X±3S）作为上下限反复剔除原始数据的特值,使元素含量服从正态分布.最后以X+2S作为异常下限（T）,以1T、2T、4T三级浓度分带,圈定Cu、Au、Ag、Mo单元素异常和Au-Ag-Mo综合元素异常,揭示矿区内水系沉积物地球化学异常特征.将异常区与矿区地质特征、矿床（点）套合分析,表明异常受地层、断裂、围岩蚀变控制,对寻找矿（化）体、断层、围岩蚀变带有指示作用.最终,优选2处远景区,分别为3号综合异常区中心北北西方向至北东向断裂附近,1号、2号综合异常区及其东侧组成一个走向为东西向的异常带.