云南会泽铅锌矿床分散元素的富集机制——兼论浅色闪锌矿富集Cd的原因

文章对云南会泽铅锌矿床的黄铁矿、方铅矿和闪锌矿中的分散元素进行了电子探针分析(EMPA),探讨了分散元素的富集机制.结果表明,分散元素含量已达到综合利用指标,且富集规律为:分散元素以类质同象的形式赋存,黄铁矿中分散元素含量较低,而方铅矿中分散元素的含量稍高于闪锌矿.闪锌矿中:Cd富集顺序为红色＞杂色＞黑色,在高温阶段Cd置换Fe,低温阶段Cd置换Zn;Ga通过置换Zn进入闪锌矿,Ge可能主要替代Fe而进入闪锌矿晶格.方铅矿中:Cd和Ga元素置换Fe或Pb先进入方铅矿晶格内,Ge则富集较晚,具体表现为:当Ga含量较低时,元素进入方铅矿品格顺序为Fe,Zn→Cd→Ga,Ge,当Ga含量较高时,元素进入方铅矿品格的顺序依次为Cd,Ga→Ge.     

西藏雅鲁藏布江缝合带西段普兰纯橄岩中橄榄石的出溶特征及指示意义

西藏雅鲁藏布江缝合带西段普兰纯橄岩中橄榄石存在透辉石和磁铁矿共生出溶现象。这类纯橄岩非常新鲜,主要由橄榄石、尖晶石和透辉石等矿物组成。橄榄石的Fo值是90.1~90.7,铬尖晶石的Cr~#为19.8~20.8,远小于蛇绿岩地幔橄榄岩中常见纯橄岩中铬尖晶石的铬值(Cr~#60)。基于前人研究结果,提出这种现象是由于亏损方辉橄榄岩与含钛、铝、钙熔体发生交代作用,从而形成橄榄石的固溶体存在Ti~(4+)、Al~(3+)、Ca~(2+)、Fe~(3+),而Cr~(3+)进入铬尖晶石结晶。后期由于岩体在抬升过程中降温,橄榄石中出溶形成单斜辉石和磁铁矿,而铬尖晶石结晶被保留。依据铬尖晶石-橄榄石的矿物化学成分,识别出低铬纯橄岩具有最低的部分熔融程度为~8%,Cr~#最高的纯橄岩壳其部分熔融程度达到~50%,表明不同岩相间其形成背景存在明显差异。因此,笔者认为普兰蛇绿岩具有多阶段的过程。首先是在洋中脊环境下经历富Ca、Al和Na等熔体交代和部分熔融作用,后受到俯冲带玻安质熔体改造。     

云南建水腊里河超基性岩地质特征及其构造意义

川滇黔等地在二叠世晚期发生峨眉山玄武岩短期内大规模溢流喷发。滇西地区发育的镁铁—超镁铁质岩均被认为是峨眉山大火成岩省的产物,但在滇东地区却一直缺少该类岩石组合的报道。本文在滇东建水地区首次发现了腊里河超基性岩体,通过LA-ICP-MS锆石UPb定年分析表明该超基性岩先期形成年龄为(246±5.2)Ma,为晚二叠-早三叠世的产物,后期中侏罗世晚期(169.6±2.0)Ma(MSWD=3.5)发生岩浆活化。该超基性岩Mg#值平均为78.73,稀土元素表现出略微右倾的平坦型特征,Rb、Sr、Ba、Pb等大离子亲石元素相对富集,高场强元素Zr、Hf相对亏损,Ta异常富集。其地化特征表现出富集型地幔源区特征,与峨眉山玄武岩成因关系密切。晚二叠世建水地区由于地幔柱活动形成地表溢流玄武岩,在深部岩浆房由玄武质岩浆结晶分异作用形成超基性侵入岩,到中侏罗世晚期,伴随着华南地区发生多期次构造运动,先前存在于岩浆房中的超镁铁质岩经过后期热液改造活化,沿着断层裂隙侵入地表。     

黄海南部小黄鱼洄游分布及种群结构特征

Monthly fishery survey data of the small yellow croaker Larimichthys polyactis in the southern Yellow Sea from2003 and 2013 were employed to evaluate the variation in the resource distribution and biological characteristics(especially body length and sex ratio) in the population on a decadal scale.The results indicated that the small yellow croaker migrated from the Shawai fishing ground to the Dasha fishing ground in spring and was mainly distributed in the central and western parts of the Dasha fishing ground in April and May.Larimichthys polyactis in the Dasha fishing ground migrated eastward to offshore wintering grounds in autumn and reached the central Dasha fishing ground in October and November.The small yellow croaker entered the western waters of the Shawai fishing ground in winter.A large number of age 0+ fish occurred in the Shawai and Jiangwai fishing grounds in October of 2003 and 2013.The body lengths of the spawning stock and wintering stock in 2013 were larger than those in 2003,and the monthly sex ratios(female to male) were significantly less than 1 in both years.The monthly distribution of this fish in the southern Yellow Sea was consistent with a previous finding that "the stock migrated between the wintering grounds in the west of Jeju Island and the Lüsi spawning grounds" but tended to move more northward,with the spawning grounds extending outward.In the past decade,body length variation experienced a decline after an increase,rather than a steady decrease.The sex ratio in the single-stick stow net showed a tendency to increase over the decade,but was either less than or more than 1 depending on the fishing gear;therefore,further studies should be conducted to determine the sex structure.     

消油剂处理120#燃料油对海水青鳉(Oryzias melastigma)胚胎抗氧化酶活性影响的研究

以海水青鳉(Oryzias melastigma)胚胎为研究对象,比较了120#燃料油分散液(water-accommodated fractions,WAFs)与乳化液(biologically enhanced water-accommodated fractions,BE-WAFs)的急性毒性效应,并研究了不同浓度(40、100、250 mg/L)下WAFs、BE-WAFs对胚胎内超氧化物歧化酶(SOD)、过氧化氢酶(CAT)、谷胱甘肽硫转移酶(GST)活性的影响。结果表明:在受到石油烃的氧化胁迫后,海水青鳉胚胎内3种抗氧化酶活性变化明显。随着石油烃浓度的升高和暴露时间的延长,3种酶表现出程度不同的诱导效应和抑制效应。其中受石油烃污染影响最为明显的为SOD酶;而GST酶则对消油剂单独暴露表现较为敏感。实验证明,海水青鳉体内SOD酶活性对石油烃污染反应最为敏感,适合作为监测石油烃污染程度的生物标志物。     

海底管道检测中侧扫声纳声波掠射角的优化设计

针对利用侧扫声纳检测海底管道时因其检测声影图像模糊而导致管道悬空高度检测误差过大的问题,提出了侧扫声纳声波掠射角优化设计的思路及方法。阐述了利用侧扫声纳对海底管道进行检测的工作原理,并利用海底管道和海底底质反向散射强度的计算公式探讨了声波在海底的反向散射强度、侧扫声纳声影图像的质量以及声波掠射角的取值这三者之间的关系对海底管道悬空高度h计算精度的影响,从理论上确定声波掠射角最佳取值范围的存在。通过工程实例的现场检测与比对试验,获得了在本试验所处海域环境中利用侧扫声纳检测海底管道时声波掠射角的最佳取值范围,对于类似的海底管道检测工程具有一定的指导意义。     

Petrology and PGE Abundances of High‐Cr and High‐Al Podiform Chromitites and Peridotites from the Bulqiza Ultramafic Massif,Eastern Mirdita Ophiolite,Albania

The Bulqiza ultramafic massif, which is part of the eastern Mirdita ophiolite of northern Albania, is world renowned for its high-Cr chromitite deposits. High-Cr chromitites hosted in the mantle section are the crystallized products of boninitic melts in a supra-subduction zone (SSZ). However, economically important high-Al chromitites are also present in massive dunite of the mantle-crust transition zone (MTZ). Chromian-spinel in the high-Al chromitites and dunites of the MTZ have much lower Cr# values (100Cr/(Cr+Al)) (47.7–55.1 and 46.5–51.7, respectively) than those in the high-Cr chromitites (78.2–80.4), harzburgites (72.6–77.9) and mantle dunites (79.4–84.3). The chemical differences in these two types of chromitites are reflected in the behaviors of their platinum-group elements (PGE). The high-Cr chromitites are rich in IPGE relative to PPGE with 0.10–0.45 PPGE/IPGE ratios, whereas the high-Al chromitites have relatively higher PPGE/IPGE ratios between 1.20 and 7.80. The calculated melts in equilibrium with the high-Cr chromitites are boninitic-like, and those associated with the high-Al chromitites are MORB-like but with hydrous, oxidized and TiO2-poor features. We propose that the coexistence of both types of chromitites in the Bulqiza ultramafic massif may indicates a change in magma composition from MORB-like to boninitic-like in a proto-forearc setting during subduction initiation.     

Petrological and Os Isotopic Characteristics of Zedong Peridotites in the Eastern Yarlung–Zangbo Suture in Tibet

The Zedong ophiolites in the eastern Yarlung–Zangbo suture zone of Tibet represent a mantle slice of more than 45 km~2. This massif consists mainly of mantle peridotites, with lesser gabbros, diabases and volcanic rocks. The mantle peridotites are mostly harzburgite, lherzolite; a few dike-like bodies of dunite are also present. Mineral structures show that the peridotites experienced plastic deformation and partial melting. Olivine(Fo89.7–91.2), orthopyroxene(En_(88–92)), clinopyroxene(En_(45–49) Wo_(47–51) Fs_(2–4)) and spinel [Mg~#=100×Mg/(Mg+Fe)]=49.1–70.7; Cr~#=(100×Cr/(Cr+Al)=18.8–76.5] are the major minerals. The degree of partial melting of mantle peridotites is 10%–40%, indicating that the Zedong mantle peridotites may experience a multi–stage process. The peridotites are characterized by depleted major element compositions and low REE content(0.08–0.62 ppm). Their "spoon–shaped" primitive–mantle normalized REE patterns with(La/Sm)_N being 0.50–6.00 indicate that the Zedong ultramafic rocks belong to depleted residual mantle rocks. The PGE content of Zedong peridotites(18.19–50.74 ppb) is similar with primary mantle with Pd/Ir being 0.54–0.60 and Pt/Pd being 1.09–1.66. The Zedong peridotites have variable, unradiogenic Os isotopic compositions with ~(187)Os/~(188)Os=0.1228 to 0.1282. A corollary to this interpretation is that the convecting upper mantle is heterogeneous in Os isotopes. All data of the Zedong peridotites suggest that they formed originally at a mid-ocean ridge(MOR) and were later modified in supra–subduction zone(SSZ) environment.