硫化物固—液界面电化学效应实验探讨

硫化物作为一类重要的常见矿物，目前国内外对其表面矿物学特征研究有限。具体到硫化物固－液界面处的行为机理，前人的研究程度就更低了。笔者自行设计了一个Fe1-xS-Cr^6 原电池，通过实测电动势（E），t-E关系曲线，溶液可见光吸收谱及其λ－A关系曲线，阐明硫化物与Cr^6＋溶液间的界面行为机理。认为其界面行为过程为；硫化物溶解→离子反应（氧化还原）→吸附Cr^3 。该原电池与一般原电池结构不同，其主要差别在于将反应电极和测量电极分开，从而解决电极反应过程中的浓度极化问题，提高了电化学实验的精度。该研究成果有助于揭示矿物－液体相互作用机理，完善和丰富表面矿物学研究内容，深化化界面成矿理论，并对环境治理，矿物材料应用等开发领域具有重要的参考价值。     

环洞庭湖区城镇体系发展研究

通过对环洞庭湖区城镇体系发展的历史背景以及现状特征分析，指出其发展过程存在着城市空间格局发展不平衡，产业结构重复严重等问题，在此基础上，提出了相应的对策与发展措施，确保环湖区内城镇体系的持续，快速发展，并最终实现带动区域经济发展的目的。     

Geochemical evidence for the characteristic of the 1908 Tunguska explosion body in Siberia, Russia

Twenty-two peat samples collected at different depths of a core including the layer affected by the 1908 explosion in Tunguska area of Central Siberia, Russia, and three basalt samples collected near the site, are analyzed by ICP-MS. The concentrations of Pd, Ni, Co, ΣREE, Ti and Sr in the event layers are 4–35 times higher than the background values in the normal layers. The variation of Pd is closely related to Ni, Co and ΣREE in the event layers, but not to these elements in the normal layers. It indicates that these excess elements came from the same source, i.e. the Tunguska explosion body. In addition, the patterns of Cl-chondrite-normalized REE in the event layers ((La/Yb)_N ≈2–3) are much flatter than those in the normal layers ((La/Yb)_N ≈7–143), and differ from those in the three basalt samples. The concentrations of REE in the three basalt samples are tens times higher than those in the event layers. It may be inferred that these excess elements could not be produced by the contamination of the terrestrial material, but probably by the Tunguska explosion body. Additionally, the ratios of Ti/Ni and Sr/Co in the event layers are close to those in comet. It implies that the solid part of the explosion body was compositionally similar to carbonaceous chondrites (Cl) and more probably a small comet. In terms of the Pd excess fluxes in the explosion area, it can be estimated that the celestial body that exploded over Tunguska in 1908 weighed more than 10⁷ tons, corresponding to a radius of > 126 m.     

抚州市泥质粉砂岩全风化工程性质研究

泥质粉砂岩全风化工程性质在有关规范中均未进行定量评价，这给工程技术人员带来困难与不便。本文根据抚州市工程实测资料，评价了软质岩石全风化工程性质，提出确定承载力的方法及承载力的取值。     

信丰大塘盆地恐龙蛋化石层位特征及其生物地层划分

通过1：5万信丰县、大塘圩幅的区调工作，对大塘盆地晚白垩世恐龙蛋化石进行了研究，新建立了Macroolithus-Nanshiungoolithus-Elongatoolithus组合带（A.-Z）、Elongatoolithus顶峰带（Ac.-Z）和Macroolithus顶峰带（Ac.-Z）等3个生物地层单位，并进行区域对比讨论。     

硫化物矿物溶解度与溶液pH值的关系

硫化物作为自然界常见的一大类矿物 ,由于溶解度很小 ,硫化物对水pH值的影响以及水对它的溶解度影响往往被人们所忽视。通过计算常见硫化物矿物的自由能ΔG0f、溶度积Ksp和溶解度S、绘制logS—pH曲线 ,得出硫化物矿物在不同 pH值条件下的溶解规律 ,水溶液的pH值受硫化物矿物的控制 ;反过来 ,水溶液的pH值也影响着矿物溶解度的大小。此外 ,对硫化物矿物饱和溶液的缓冲范围、缓冲容量和硫化物与溶液pH值相互作用的机理进行了探讨     

闽西南地区成岩成矿作用与构造环境

闽西南地区是特提斯构造域向环太平洋大陆边缘构造域转换的典型地区，区内多期构造演化形成了复杂多变的构造单元格局和多种成岩成矿环境。多期多阶段火山侵入岩浆作用为矿集区矿床的形成提供了良好的热液活动条件和深部热源基础。笔者总结了研究区矿床时空演化规律、矿床成矿系列与成矿构造环境的关系，指出复杂多变的构造环境造成了本区矿床具多时代、多层位、多矿种、多成因类型的特点。     

长庆油区提高延长统油层稳产水平的先导性试验——陶粒压裂井的效果

长庆油区为解决低渗油田稳产问题，选择了一批井进行了高强度支撑剂压裂试验。本文对16口压裂井投产后的稳产效果进行了研究，得出该工艺适合的油层特点。     

Seismo-tectonic divisions of strong earth-quakes with MS37.0 and their tectonic geomorphology along Xianshuihe-Xiaojiang fault zone

Seismo-tectonic areas of historical strong earthquakes with MS37 along Xianshuihe-Xiaojiang fault zone are di-vided, and their individual fault-pattern and tectonic geomorphology are analyzed. Those strong-earthquake areas are located in some special parts of the fault zone, where the major branch-faults of the fault zone form left step-ping, parallel, and fork-like patterns. In the strong-earthquake areas structurally complicated basins are developed, such as pull-apart basins in fork-like area, in double stepping area, and in stepping and fork-like areas.     

Transition of Quaternary glacial cyclicity in deep-sea records at Nansha, the South China Sea

High-resolution oxygen isotope records over the last 2249 ka (MIS 1–86) have been obtained from cores of the upper section (105.08 m) at ODP Site 1143 (water depth of 2772 m) drilled in the Nansha area, southern South China Sea. The sampling resolution is at about 2 ka intervals, resulting in one of the best oxygen isotope records over the global ocean. The oxygen isotope curves, displaying details in the Pleistocene glacial cycles, have revealed a nearly 300 ka long stage of transition from a predominant 40 ka to 100 ka periodicity. Therefore, the “Mid-Pleistocene Revolution” should be considered as a process of transition rather than an abrupt change. Within the 100 ka glacial cycles, the changes in tropical sea surface water were found to lead those in high-latitude ice sheet. Our comparisons show that the ice sheet expansion and the glacial stage extension in the Northern Hemisphere with the 100 ka cycles must have been driven not by ice sheet itself, but by processes outside the high latitudes of the Northern Hemisphere.