便携式Li-K分析仪的研制及其在锂辉石中锂的分析应用

我国锂钾主要矿产资源大多分布在西部偏远地区,其勘查找矿或综合利用迫切需要现场快速分析技术的支持。本文介绍了自行开发的便携式Li-K分析仪的主要性能及其在锂辉石中锂的分析应用。Li-K分析仪是一种基于大气压的液体阴极辉光放电光谱仪,以待测液体为放电阴极,实现了样品中Li、K等元素的原子化和激发。该仪器以光纤传导CCD光谱仪作为检测器,其波长范围为345~1015 nm,分辨率3 nm;以Li 670.78 nm和K 769.90 nm分析谱线,在仪器最佳工作条件下测定Li、K的精密度(RSD,n=14)均低于2%,检出限为0.03μg/m L,检测范围0.1~10μg/m L。研究表明,不同酸度和酸的类型对谱线强度影响较大,且存在显著的样品基体效应,标准曲线法分析锂辉石中Li的结果偏差高达267%;而标准加入法可克服基体效应的影响,获得与ICP-OES一致性较好的分析结果,为现场开展固体样品中Li的测定奠定了基础。     

Phase transition of the Pacific decadal oscillation and decadal variation of the East Asian summer monsoon in the 20th century

This paper focuses on the relationship between the phase transition of the Pacific decadal oscillation (PDO) and decadal variation of the East Asian summer monsoon (EASM) in the twentieth century. The first transition occurred in the 1940s, with an enhanced SST in the North Pacific and reduced SST in the tropical eastern Pacific and South Indian Ocean. In agreement with these SST changes, a higher SLP was found in most parts of the Pacific, while a lower SLP was found in the North Pacific and most parts of the Indian Ocean. In this case, the EASM was largely enhanced with a southerly anomaly in the lower troposphere along the east coast of China. Correspondingly, there was less rainfall in the Yangtze River valley and more rainfall in northern and southern China. An opposite change was found when the PDO reversed its phase in the late 1970s. In the tropical Indian Ocean and western Pacific, however, the SST was enhanced in both the 1940s and 1970s. As a result, the western Pacific subtropical high (WPSH) tended to extend westward with a larger magnitude in the 1970s. The major features were reasonably reproduced by an atmospheric general circulation model (IAP AGCM4.0) prescribed with observed SST and sea ice. On the other hand, the westward extension of the WPSH was exaggerated in the 1970s, while it was underestimated in the 1940s. Besides, the spatial pattern of the simulated summer rainfall in eastern China tended to shift southward compared with the observation.     

Mesoscale numerical simulation study of warm fog dissipation by salt particles seeding

Based on the dynamic framework of WRF and Morrison 2-moment explicit cloud scheme, a salt-seeding scheme was developed and used to simulate the dissipation of a warm fog event during 6–7 November 2009 in the Beijing and Tianjin area. The seeding effect and its physical mechanism were studied. The results indicate that when seeding fog with salt particles sized 80 μm and at a quantity of 6 gm~(-2) at the fog top, the seeding effect near the ground surface layer is negative in the beginning period, and then a positive seeding effect begins to appear at 18 min, with the best effect appearing at 21 min after seeding operation. The positive effect can last about 35 min. The microphysical mechanism of the warm fog dissipation is because of the evaporation due to the water vapor condensation on the salt particles and coalescence with salt particles.The process of fog water coalescence with salt particles contributed mostly to this warm fog dissipation. Furthermore, two series of sensitivity experiments were performed to study the seeding effect under different seeding amounts and salt particles sizes. The results show that seeding fog with salt particles sized of 80 μm can have the best seeding effect, and the seeding effect is negative when the salt particle size is less than 10 μm. For salt particles sized 80 μm, the best seeding effect, with corresponding visibility of 380 m, can be achieved when the seeding amount is 30 g m~(-2).     

An algorithm to retrieve precipitation with synthetic aperture radar

This paper presents a new type of rainfall retrieval algorithm, called the model-oriented statistical and Volterra integration. It is a combination of the model-oriented statistical (MOS) and Volterra integral equation (VIE) approaches. The steps involved in this new algorithm can be briefly illustrated as follows. Firstly, information such as the start point and width of the rain is obtained through pre-analysis of the data received by synthetic aperture radar (SAR). Secondly, the VIE retrieval algorithm is employed over a short distance to obtain information on the shape of the rain. Finally, the rain rate can be calculated by using the MOS retrieval algorithm. Simulation results show that the proposed algorithm is effective and simple, and can lead to time savings of nearly 50% compared with MOS. An example of application of SAR data is also discussed, involving the retrieval of precipitation information over the South China Sea.     

高性能计算技术在气象领域的应用

高性能计算通过应用超级计算机与并行处理技术解决复杂的计算问题,是信息技术发展比较迅猛的领域之一。气象应用始终是高性能计算的重要领域,高性能计算技术有效地解决了高分辨率、高精度气象数值预报模式发展限制,在气象预报预测业务中发挥着核心支撑作用。数十年以来,由于数值天气模式研究和业务运行对计算资源的强烈需求,国内外气象领域高性能计算机及应用迅速发展起来。气象领域对高性能计算能力及系统的可靠性需求日益提升。高性能计算技术将与气象预报应用日益融合,相互影响促进,不断创新发展。为满足气象预报预测业务和科研工作需求,中国气象部门将进一步提升高性能计算能力,并致力于优化集约高性能计算系统布局,高效管理计算资源,发挥最大效益。     

辽宁地区不同降水云系雨滴谱参数及其特征量研究

利用位于辽宁省沈阳市和辽阳市的Parsivel（Particle Size and Velocity）激光雨滴谱仪观测到的雨滴谱资料按照积雨云降水系统、积层混合云降水系统和层状云降水系统分析雨滴谱特征量和谱参数的平均特征及随时间的演变特征。结果表明:Gamma分布拟合谱参数N₀和λ按照层状云、积层混合云和积雨云的顺序减小,谱参数μ按照层状云、积层混合云和积雨云的顺序增大;直径小于1 mm的降水粒子对数浓度的贡献最大,直径大于1 mm的降水粒子对雷达反射率的贡献最大;M-P分布的谱参数N₀与雨强I具有幂函数关系,并且随着雨强I的增大而增大,谱参数λ与雨强I具有指数函数关系,随着雨强I的增大而减小。     

Estimation of Aerosol Radiation Effects under Background and Smoke-haze Atmospheric Conditions over Siberia from Empirical Data

The results of numerical simulation of downward solar radiation fluxes for background and smoke-contaminated atmospheric conditions are discussed. Vertical profiles of aerosol characteristics are obtained from the empirical model based on the data of aircraft sounding of profiles of angular scattering coefficients and content of absorbing particles in the lower troposphere. The background model was created using the results of measurements obtained under cloudless and mostly cloudless atmospheric conditions in 1999–2011. Optical parameters of smoke aerosol are determined from the data of aircraft measurements in the period of long-term wildfires in Siberia in the summer 2012. It is demonstrated that deficiency in diurnal values of total solar radiation at the surface level caused by the formation of the optically dense smoke layer as compared to background conditions, is more than 13 MJ/m².