利用X射线粉晶衍射和电感耦合等离子体质谱法研究江西西华山钨矿床中黑钨矿的矿物学特征及指示意义

目前针对江西大型黑钨矿石英脉型钨矿床西华山的黑钨矿矿物学特征及指示意义研究较少。本文利用X射线粉晶衍射分析和电感耦合等离子体质谱分析技术对黑钨矿晶体结构、化学成分特征及空间变化规律开展研究。获得黑钨矿晶胞参数为a0=0.477 nm,b0=0.573 nm,c0=0.498 nm,β=90°21',属于锰钨铁矿,与前人得出的黑钨矿晶胞参数略有不同,代表不同元素对铁锰的类质同象替代。主要化学成分WO3、Fe O、Mn O的含量在空间上具有一定的变化规律,反映了成矿物质的运移特征。微量元素Sc、Y、Nb、Ta在垂向含量变化大,说明矿液运移具有复杂性。稀土总量ΣREEs较高(397.16×10-6~1071.11×10-6),具有强烈的Eu负异常,具重稀土富集左倾的"躺椅式"球粒陨石标准化配分模式。将西华山、盘古山、淘锡坑、大吉山4个典型矿床的黑钨矿稀土元素特征进行对比,反映产在花岗岩内接触带的黑钨矿的稀土总量(ΣREEs)相对最高,分馏最明显;产在花岗岩内及其外接触带的黑钨矿的稀土总量(ΣREEs)相对较低,分馏程度最不明显;而产在花岗岩外接触带的黑钨矿的稀土总量(ΣREEs)有高有低,分馏程度有强有弱。因此,黑钨矿的化学成分变化特征,可以有效地指示成矿物质空间运移特征、物质来源和矿床成因。     

内蒙古大青山地区古元古代早期榴云片麻岩(大青山表壳岩)深熔作用:地质、锆石年代学和地球化学研究

大青山位于华北克拉通西部孔兹岩带中段,古元古代晚期孔兹岩系(上乌拉山岩群)十分发育。近年来,在上乌拉山岩群中分辨出一套古元古代早期变质碎屑沉积岩(大青山表壳岩,榴云片麻岩),它们遭受强烈变质变形和深熔作用改造,形成古元古代早期石榴石花岗岩。包头哈德门沟是古元古代早期榴云片麻岩典型出露区,并有古元古代早期石榴石花岗岩(哈德门沟石榴石花岗岩)形成。由榴云片麻岩经深熔榴云片麻岩再到石榴石花岗岩,浅色体增多,石榴石增多且颗粒增大,黑云母减少,石榴石包裹黑云母、石英、斜长石等矿物。石榴石岩的锆石呈浑圆状,普遍具核-幔-边或核-边结构,碎屑锆石年龄为~2.5Ga,变质锆石年龄为~2.45Ga和~1.90Ga。锆石形态、内部结构和年龄与榴云片麻岩、深熔榴云片麻岩和石榴石花岗岩中的锆石类似,但记录了古元古代晚期变质事件年龄。石榴石花岗岩与榴云片麻岩和深熔榴云片麻岩的地球化学组成特征总体上类似,高Al2O3含量和FeO T/MgO比值,CaO含量和K2O/Na2O比值存在较大变化,富集轻稀土和大离子亲石元素,亏损Nb、Ta、P和Ti。研究表明:1)浅色体和石榴石花岗岩中的石榴石是黑云母转熔的产物,并非岩浆结晶形成的;2)石榴石岩是在石榴石花岗岩岩浆形成之后进一步演化过程中石榴石不断地发生运移、分异和聚集的结果;3)尽管哈德门沟石榴石花岗岩具有一定或较大的规模,但具有深熔岩浆的性质;4)石榴石花岗岩地球化学组成变化与熔融母岩组成变化和深熔及岩浆演化过程中残余矿物相石榴石、锆石局部变化有关。     

西藏北冈底斯扎独顶A型花岗岩锆石U-Pb年代学、地球化学及其地质意义

西藏北冈底斯早白垩世花岗岩分布广泛;扎独顶岩体作为其中的一个典型代表,其分布广泛,呈岩基型式产出,在岩性上属二长花岗岩。在岩石化学上扎独顶岩体具有富Si O2(70.05%~74.97%)和K2O(4.09%~5.35%),贫Ca O(0.93%~2.19%)、Ti O2(0.22%~0.52%)和Al2O3(12.81%~14.24%)的特征;属于准铝质-弱过铝质(A/CNK=0.99~1.0)高钾钙碱性系列。岩体稀土元素总量偏高(∑REE=199.36×10-6~247.91×10-6),相对富集轻稀土元素(LREE/HREE=5.82~6.88),Eu负异常明显(δEu=0.30~0.45),球粒陨石标准化分布模式呈向右缓倾的V型。微量元素显示其富集Rb、Th、K、Zr和Hf,亏损Nb、Ta、Sr、Ba、P和Ti,(Zr+Nb+Ce+Y)平均值为427.63。全岩锆石饱和温度(828~838°C)表明岩浆形成温度高。上述岩石地球化学特征表明扎独顶岩体为A型花岗岩。扎独顶岩体LA-ICP-MS锆石U-Pb年龄为(103.8±1.0)Ma,表明其形成于早白垩世晚期;在构造判别图解上位于碰撞后的A2型花岗岩区,是在碰撞后岩石圈伸展背景下,由于软流圈物质上涌导致岩石圈地幔与壳源熔体部分熔融并经历过一定程度的混合作用而形成的。     

Lithospheric Electrical Structure across the Eastern Segment of the Altyn Tagh Fault on the Northern Margin of the Tibetan Plateau

Project INDEPTH (InterNational DEep Profiling of Tibet and the Himalaya) is an interdisciplinary program designed to develop a better understanding of deep structures and mechanics of the Tibetan Plateau. As a component of magnetotelluric (MT) work in the 4th phase of the project, MT data were collected along a profile that crosses the eastern segment of the Altyn Tagh fault on the northern margin of the plateau. Time series data processing used robust algorithms to give high quality responses. Dimensionality analysis showed that 2D approach is only valid for the northern section of the profile. Consequently, 2D inversions were only conducted for the northern section, and 3D inversions were conducted on MT data from the whole profile. From the 2D inversion model, the eastern segment of the Altyn Tagh fault only appears as a crustal structure, which suggests accommodation of strike slip motion along the Altyn Tagh fault by thrusting within the Qilian block. A large-scale off-profile conductor within the mid-lower crust of the Qilian block was revealed from the 3D inversion model, which is probably correlated with the North Qaidam thrust belt. Furthermore, the unconnected conductors from the 3D inversion model indicate that deformations in the study area are generally localized.     

The Significance of Wettability in Tight Oil Exploration and Development

<正>With the increasing of energy demand and conventional oil and gas resources depletion,unconventional oil and gas resources are getting more and more attention,and have become a major contributor to the global oil and gas production growth over the past five years(Zou et al.,2012;Jia et al.,2014).After shale gas,the tight oil in the     

A New Species of Rhodoleia (Hamamelidaceae) from the Upper Pliocene of West Yunnan, China and Comments on Phytogeography and Insect Herbivory

In Europe, fossil fruits and seeds of Rhodoleia (Hamamelidaceae) have been described from the Upper Cretaceous to the Miocene, whereas no fossil record of Rhodoleia has been reported in Asia, where the modern species occur. Herein, 21 fossil leaves identified as Rhodoleia tengchongensis sp. nov. are described from the Upper Pliocene of Tengchong County, Yunnan Province, Southwest China. The fossils exhibit elliptic lamina with entire margins, simple brochidodromous major secondary veins, mixed percurrent intercostal tertiary veins, and looped exterior tertiaries. The leaf cuticle is characterized by pentagonal or hexagonal cells, stellate multicellular trichomes, and paracytic stomata. The combination of leaf architecture and cuticular characteristics suggests that the fossil leaves should be classified into the genus Rhodoleia. The fossil distributions indicate that the genus Rhodoleia might originate from Central Europe, and that migrated to Asia prior to the Late Pliocene. Additionally, insect damage is investigated, and different types of damage, such as hole feeding, margin feeding, surface feeding, and galling, are observed on the thirteen fossil leaves. Based on the damage frequencies for the fossil and extant leaves, the specific feeding behavior of insects on Rhodoleia trees appears to have been established as early as the Late Pliocene. The high occurrence of Rhodoleia insect herbivory may attract the insect-foraging birds, thereby increasing the probability of pollination.     

甘肃花草滩煤矿区沉积相演化与内部构造的地质意义探讨

花草滩煤矿区地处北祁连褶皱带中段北侧,酒东盆地东端。古生界和中生界地层在区内发育较完整,其中石炭系太原组为含煤地层。经二、三维地震勘探、钻探等工作证实矿床总体上受单斜构造控制。石炭纪中期盆地呈逐渐上升趋势,沉积相演化经历了由海相逐渐过渡到海陆交汇相,再到陆相沉积的阶段。F5和F8断层具顺层断裂特征,破坏煤层的连续性,在一定程度上控制了瓦斯突出区的分带,可作为煤矿瓦斯含量高低的分界标志。     

基于变形分区确定某反倾岩质岸坡变形体锁固段

对处于蠕滑阶段的边坡而言,准确确定蠕滑段和锁固段是进行稳定性评价及演化趋势预测的基础和前提。以我国西南山区某水库型岸坡变形体为例,在综合分析岸坡工程地质条件的基础上,通过联合运用野外现场地质调查、地表位移监测、钻孔、平硐、深部位移监测、物探等多种勘察手段,查明了岸坡的结构特征,并分别对岸坡进行地表和深部变形分区。 在此基础上,结合当前稳定性现状,划分出岸坡蠕滑段与锁固段。结果表明:(1)岸坡在河谷下切过程中发生了弯曲倾倒变形,弯曲折断面深度为20～80m;(2)岸坡前部为蠕滑段,中部为锁固段,后部为拉裂段,具备滑移-拉裂-剪断三段式发育特征。研究结果可直接用于该岸坡变形体的稳定性评价,且对于同类型处于蠕滑阶段边坡的勘察手段及综合分析具有一定的借鉴意义。     

广东东莞黑头山花岗岩体成岩时代及成因研究

广东东莞厚街黑头山黑云母二长花岗岩体锆石SHRIMP U-Pb测定其岩浆结晶年龄为151.6 Ma(晚侏罗世),属燕山期岩浆活动产物。岩石化学成分富SiO2(70%),富K2O(4%);相对贫Al2O3(12%~14.4%),贫Sr、Ba、Eu、Ti和P;稀土配分曲线呈海鸥型,具明显的负铕异常。多方法综合判断认为黑头山花岗岩具明显的A型花岗岩特征,属弱过铝质A1型花岗岩,应是燕山期岩石圈拉张减薄构造背景下所形成的侵入岩体。     

内蒙古北山额济纳旗小红山钒钛磁铁矿床SHRIMP锆石U-Pb定年及其意义

小红山钒钛磁铁矿床是近年内蒙古北山地区新发现的一个中型钒钛磁铁矿床,含矿辉长岩体侵位于蓟县系平头山组,岩体具全岩矿化,工业矿体主要赋存于中粗粒辉长岩中。采用SHRIMP锆石U-Pb定年方法对小红山中粗粒辉长岩体进行了年代学研究,获得该岩体的锆石微区原位SHRIMP U-Pb年龄为424±6Ma,表明小红山钒钛磁铁矿成岩成矿事件发生于中志留世。该时期钒钛磁铁矿床的发现,揭示了北山地区早古生代处于陆缘裂谷环境,这对研究和认识北山地区地质构造演化及开展岩浆矿床找矿具有重要意义。