基于贝叶斯网络的地下水环境系统决策管理研究

应用贝叶斯网络解决地下水环境管理中具有不确定性的多目标决策问题,通过对决策变量氮肥施用量以及灌溉模式的调控,减少水中的硝酸盐含量,达到既能有效改善水环境又不至使农民经济利益受到损害的目标。通过分析具体的地下水环境管理系统中变量间的相互关系,构建描述变量间不确定性关系的贝叶斯网络模型,其中包括表示其依赖关系的有向无环图和表示其具体概率依赖程度的条件概率表。并在多个水环境管理目标均达到最优的前提下进行概率推理,得到决策变量氮肥施用量以及灌溉模式取不同值时目标变量的概率分布情况。最终确定出能使所有目标均达到最优的合理的水环境管理决策:(1)使用喷灌,将氮肥施用量控制在0.01~0.03 kg/m2;(2)使用漫灌,将氮肥施用量控制在0.01~0.02 kg/m2。     

Provenance of Lower Cretaceous Wölong Volcaniclastics in the Tibetan Tethyan Himalaya: Implications for the final breakup of Eastern Gondwana

Lower Cretaceous volcanic lithic arenites, widely distributed in the Tethyan Himalaya, provide insights into the continental breakup of Eastern Gondwana. In southern Tibet they are represented by the Wölong Volcaniclastics. The volcanic rocks that contributed clastic material to the lower parts of this unit were predominantly alkali basalts, whereas rhyolitic/dacitic volcanism becomes the predominant source of the upper strata. Geochemical analyses of basaltic grains and of detrital Cr-spinels from the Wölong Volcaniclastics demonstrate the alkaline character of the volcanism and suggest “within-plate” tectonic setting for the volcanism. Zircon U–Pb ages confirm that this volcanism continued from ～ 140 Ma to ～ 119 Ma. Hf-isotope data on these Early Cretaceous zircons indicate that their parental magmas were mantle-derived, but in the later stage of magmatic activity mantle-derived magmas were mixed with partial melts derived from the continental crust.The Lower Cretaceous volcaniclastics occur along a broad belt paralleling the northern margin of Greater India. The onset of volcaniclastic deposition in the Himalayas appears to become progressively younger toward the west, but it ended synchronously during the Late Albian (～ 102 Ma). The low volume of volcanic rocks and their intra-plate tectonic setting suggest that they are the result of decompressional melting along extensional deep-seated fractures cross-cutting the continental crust, and reflect changes in regional intra-plate tectonic stresses when Greater India began to separate from the Australia–Antarctica supercontinent.     

Glacial paleoceanography off the mouth of the Mekong River, southern South China Sea, during the last 500 ka

We have analyzed core MD01-2392, ∼ 360 km east of the Mekong River mouth in the South China Sea (SCS). Over the past 500 ka, planktonic foraminiferal oxygen-isotopic values are consistently lighter than northern SCS and open-ocean records by up to 0.5‰, indicating the influence of run-off from the Mekong River during both glacial and interglacial periods. Carbonate content is higher during interglacials; sedimentation rates were higher during glacials. Increased sedimentation rates since 30 ka imply increased run-off during the last glacial maximum and Holocene Period. Contrary to general experience, in which it is classed as a warm species for temperature estimates, the thermocline-dwelling species Pulleniatina obliquiloculata increased its numbers during glacial periods. This implies an estuarine circulation and even brackish-water caps during glacial periods, reinforcing the sense of strong run-off. In an overall decline of warm water, the thermocline shoaled stepwise, with rapid rises across the glacial terminations. We infer that the southern SCS was opened to an influx of Indian Ocean waters through southern passages at those times of rising sea levels.     

气相色谱-质谱法同时测定河流沉积物中多环芳烃和有机氯农药

建立了用加速溶剂萃取,气相色谱-质谱法同时测定河流沉积物中16种多环芳烃和19种有机氯农药的分析方法,优化了萃取溶剂、萃取温度和时间、凝胶渗透色谱收集时间、固相萃取洗脱溶剂和洗脱体积等条件。16种多环芳烃的方法检出限在0.15~0.59 ng/g,加标回收率为82%~102%,相对标准偏差(RSD,n=5)为1.1%~4.5%。19种有机氯农药的方法检出限在0.14~2.23 ng/g,加标回收率为71%~108%,相对标准偏差(RSD,n=5)为1.0%~4.5%。实际样品的测定结果表明,该方法分离效果较好,能够满足沉积物样品中多环芳烃和有机氯农药的分析要求。     

Zircon U–Pb ages and tectonic implications of Paleozoic plutons in northern West Junggar,North Xinjiang,China

North Xinjiang, Northwest China, is made up of several Paleozoic orogens. From north to south these are the Chinese Altai, Junggar, and Tian Shan. It is characterized by widespread development of Late Carboniferous–Permian granitoids, which are commonly accepted as the products of post-collisional magmatism. Except for the Chinese Altai, East Junggar, and Tian Shan, little is known about the Devonian and older granitoids in the West Junggar, leading to an incomplete understanding of its Paleozoic tectonic history. New SHRIMP and LA-ICP-MS zircon U–Pb ages were determined for seventeen plutons in northern West Junggar and these ages confirm the presence of Late Silurian–Early Devonian plutons in the West Junggar. New age data, combined with those available from the literature, help us distinguish three groups of plutons in northern West Junggar. The first is represented by Late Silurian–Early Devonian (ca. 422 to 405 Ma) plutons in the EW-striking Xiemisitai and Saier Mountains, including A-type granite with aegirine–augite and arfvedsonite, and associated diorite, K-feldspar granite, and subvolcanic rocks. The second is composed of the Early Carboniferous (ca. 346 to 321 Ma) granodiorite, diorite, and monzonitic and K-feldspar granites, which mainly occur in the EW-extending Tarbgatay and Saur (also spelled as Sawuer in Chinese) Mountains. The third is mainly characterized by the latest Late Carboniferous–Middle Permian (ca. 304 to 263 Ma) granitoids in the Wuerkashier, Tarbgatay, and Saur Mountains.As a whole, the three epochs of plutons in northern West Junggar have different implications for tectonic evolution. The volcano-sedimentary strata in the Xiemisitai and Saier Mountains may not be Middle and Late Devonian as suggested previously because they are crosscut by the Late Silurian–Early Devonian plutons. Therefore, they are probably the eastern extension of the Early Paleozoic Boshchekul–Chingiz volcanic arc of East Kazakhstan in China. It is uncertain at present if these plutons might have been generated in either a subduction or post-collisional setting. The early Carboniferous plutons in the Tarbgatay and Saur Mountains may be part of the Late Paleozoic Zharma–Saur volcanic arc of the Kazakhstan block. They occur along the active margin of the Kazakhstan block, and their generation may be related to southward subduction of the Irtysh–Zaysan Ocean between Kazakhstan in the south and Altai in the north. The latest Late Carboniferous–Middle Permian plutons occur in the Zharma–Saur volcanic arc, Hebukesaier Depression, and the West Junggar accretionary complexes and significantly postdate the closure of the Irtysh–Zaysan Ocean in the Late Carboniferous because they are concurrent with the stitching plutons crosscutting the Irtysh–Zaysan suture zone. Hence the latest Late Carboniferous–Middle Permian plutons were generated in a post-collisional setting. The oldest stitching plutons in the Irtysh–Zaysan suture zone are coeval with those in northern West Junggar, together they place an upper age bound for the final amalgamation of the Altai and Kazakhstan blocks to be earlier than 307 Ma (before the Kaslmovian stage, Late Carboniferous). This is nearly coincident with widespread post-collisional granitoid plutons in North Xinjiang.     

超微量钐同位素的热表面电离质谱分析

采用双带测量方式,法拉第杯和离子计数器同时接收与跳峰接收相结合,建立了超微量钐同位素的热表面电离质谱的测量方法。优化了制样程序和质谱测量程序,研究了蒸发带电流对离子流强度的影响,考察了从纳克至微克不同样品用量的测量效果及其中Nd、Eu干扰核素的情况。对4 ng~2μg的天然丰度钐样品进行了同位素比值分析,相对标准偏差均小于1.1%。     

兰坪金顶铅锌矿床泥底辟流体成矿特征初探

兰坪金顶铅锌矿床的成矿过程与油气的生成有许多相似之处,泥底辟构造在金顶铅锌矿床的成矿过程中起着极为重要的作用。首先,随着泥底辟的上侵,塑性泥流夹带大量气体到构造圈闭中释放压力,扩大成矿空间;其次,流体的去气作用在构造圈闭中进行一系列的强改造活动,进而促使铅锌矿体的形成。文章通过对金顶铅锌矿床形成有关的泥底辟流体的来源、流体形成原因、流体在张性-挤压走滑盆地阶段的演化及金顶铅锌矿床成矿的泥底辟流体特征的分析,认为兰坪金顶铅锌矿床的形成与泥底辟构造密切相关,该矿床具泥底辟流体的成矿特征。     

延边闹枝铜金矿床的矿物流体包裹体特征与成矿作用研究

闹枝铜金矿床是延边内生金铜矿集区内的典型矿床之一,矿体主要为含金黄铜矿黄铁矿石英脉型。笔者运用显微测温、激光拉曼探针,对其矿物内的流体包裹体进行了系统研究。实验结果表明:①流体包裹体的类型主要为气液两相包裹体,其次为纯气相、富气相包裹体及纯液相包裹体,还有少量含子晶的多相包裹体;②流体包裹体的均一温度为150～410℃,与黄铁绢英岩、石英-黄铁矿、石英-多金属硫化物及石英方解石脉4个矿化蚀变阶段相对应的流体包裹体的均一温度分别为350～410℃、290～350℃、210～290℃、150～210℃;③流体包裹体的盐度w(NaCleq)为1.74%～20.97%,Ⅰ、Ⅱ、Ⅲ、Ⅳ矿化阶段成矿流体的盐度w(NaCleq)分别为2.396%～5.548%、2.24%～8.68%、1.74%～20.97%和6.3%;④流体包裹体的气体成分主要为H2O和CO2。结合前人的研究成果,笔者进一步确定该矿床的成矿流体具有深源岩浆热流体性质,在流体上升过程中曾发生过弱的沸腾作用,并在硫化物石英脉、多金属硫化物石英脉、方铅矿脉以及石英方解石脉形成过程中,伴有少量地下水或大气水的加入。     

Investigation of the sulfur speciation during chalcopyrite leaching by moderate thermophile Sulfobacillus thermosulfidooxidans

The surface sulfur speciation of chalcopyrite leached by moderately thermophilic Sulfobacillus thermosulfidooxidans was investigated by employing scanning electron microscopy (SEM), X-ray diffraction (XRD) and sulfur K-edge X-ray absorption near edge structure spectroscopy (XANES), accompanying with the leaching behavior elucidation. Leaching experiment showed that there was an optimum range of the redox potential for chalcopyrite dissolution. Leaching products were found accumulating during the leaching process, which might be jarosite according to the XRD analysis. The sulfur K-edge spectra indicated that chalcocite might be the intermediate sulfur compound under a critical redox potential, which might explain the existence of optimum range of the redox potential and provide an evidence for the two-step leaching model of chalcopyrite at low Eh. In addition, the results of sulfur K-edge spectra showed jarosite would accumulate on mineral surface, which might be the main component of the passivation layer.     

烃气测量法在黑龙江乌拉嘎金矿区找矿预测评价中的应用

乌拉嘎金矿是一个大型金矿床,随着生产对探明储量的不断消耗,保有资源已近枯竭,在矿床深部及周边寻找新的隐伏矿体已刻不容缓。然而,由于该矿床形成后,其上覆盖了一层第三系的凝灰岩,以至于在地表使用常规的地球化学方法找矿效果很差。基于烃类气体具有挥发性强、运移距离远、能穿透深厚的盖层、反映深度大,并可在地表形成异常场等特点,我们将烃气测量技术应用于该地区的找矿预测。本文在分析该区烃类气体的背景特征的基础上,通过分析该区烃类组分在空间上与已知矿体之间的对应关系,异常的分带序列,测区异常的展布特征和时空结构,并结合地质和构造特征,对区内的成矿潜力进行了评价,圈定了相关找矿有利靶区。