西藏果芒错蛇绿混杂岩中硅质岩的地球化学特征及其形成环境

果芒错蛇绿混杂岩位于狮泉河—永珠—嘉黎蛇绿混杂岩带中段,是该带中保存较好的一套蛇绿混杂岩,其形成环境是确定狮泉河—永珠—嘉黎蛇绿混杂岩带构造属性的重要依据。对果芒错蛇绿混杂岩中的硅质岩进行了地球化学分析,为判断蛇绿混杂岩的形成环境提供新的约束条件。硅质岩通常呈几十厘米夹层产于玄武岩中,含有大量晚三叠世—白垩纪放射虫化石。硅质岩SiO2含量为71.38%~77.67%,Al2O3含量为8.62%~11.51%,MnO/TiO2值为0.28~0.35,(Ce/Ce*)SN值为0.92~0.94,(La/Ce)SN值为1.13~1.17,反映了陆源物质的影响,而V、Ni、Cu和V/Y值高于大陆边缘硅质岩,与洋中脊和大洋盆地硅质岩相似,说明果芒错硅质岩可能形成于受陆源物质影响且与大陆边缘有一定距离的环境中。结合变质橄榄岩、镁铁质岩墙和玄武岩的地球化学特征,初步认为果芒错蛇绿混杂岩的形成环境为靠近大陆边缘的弧后盆地。     

藏北羌塘中部日湾茶卡组物源——LA-ICP-MS锆石U-Pb年龄及稀土元素特征

在龙木错—双湖—澜沧江板块缝合带中段的冈玛错—日湾茶卡地区,近东西向展布着一条富含暖水型生物化石的早石炭世地层日湾茶卡组(C1r)。对日湾茶卡组砂岩中的碎屑锆石进行LA-ICP-MS U-Pb定年,分析结果显示存在325~400Ma、400~500Ma、500~600Ma、950~1100Ma、1400~1800Ma和大于1800Ma六个年龄区间;最年轻的碎屑锆石年龄为325 Ma,时代为早石炭世维宪期;碎屑锆石中362 Ma和454Ma的年龄峰值最明显,为龙木错—双湖—澜沧江洋岛弧消减事件和加里东运动的年龄记录,表明碎屑岩的物源区主要来自于扬子大陆周缘。结合古生物化石资料可知,日湾茶卡组属于欧亚大陆扬子型石炭纪沉积地层,为岛弧环境下的一套浅水台型沉积。     

藏北羌塘中部日湾茶卡地区花岗闪长岩LA-ICP-MS锆石U-Pb年龄与地球化学特征

报道了藏北羌塘中部日湾茶卡地区花岗闪长岩体锆石U-Pb年龄和岩石地球化学特征。该花岗闪长岩位于龙木错—双湖—澜沧江板块缝合带西段。岩石样品中的锆石具有较好的晶形,可见典型的岩浆振荡环带结构,具有较高的Th/U值,为典型的岩浆成因锆石。样品锆石LA-ICP-MS技术测得的锆石年龄为211.0Ma±1.8Ma,表明其时代为晚三叠世。全岩地球化学分析表明,该花岗闪长岩具有高Si O2、Al2O3,富碱,低TFe2O3、Ti O2的特征,A/CNK值为0.97~1.04,为准铝质—弱过铝质岩石。稀土元素配分模式显示,配分曲线右倾,伴随较弱的Eu负异常;微量元素蛛网图表现出Nb、Ta、Ti、P亏损和Rb、Th、U、K、Pb富集的特征;样品点在构造环境判别图解上均落入碰撞型花岗岩区。初步分析,其岩浆来源可能为幔源岩浆底侵使古老地壳发生熔融。此碰撞型花岗闪长岩对龙木错—双湖—澜沧江洋碰撞的时限提供了一定的岩石学约束,为龙木错—双湖—澜沧江洋的演化提供了基础地质资料。     

多种地球化学异常下限确定方法的对比研究

地球化学异常下限值是区分背景区与异常区的基本参数,而异常下限的准确性直接关系到下一步找矿工作的实施。本文以青海省治多县区域1∶1万土壤化探样品中Ag、Cu、Zn、Pb、Bi、Mo、W七种元素为例,使用传统计算方法、85%累计频率法、分形方法对测试数据进行处理,对比研究认为:传统计算方法求得的异常范围小,且较为分散;85%累计频率法与传统方法所得异常下限值比较接近,具有合理性与客观性,相对于传统计算方法,分形方法对弱小异常的识别效果显著,但异常范围过大,给异常查证工作带来难度。确定异常下限值时要研究数据分布模式和地质背景,分析区域地球化学特征差异,应采用多种分析法对比确定合理的异常下限,圈定出有效的异常区。     

Variation of albedo to soil moisture for sand dunes and biological soil crusts in arid desert ecosystems

Surface albedo plays a crucial role in the energy balance of soils. The surface albedo and surface soil moisture of bare sand and biological soil crusts (BSCs) were concurrently observed on field plots of shifting sand dune and in revegetated desert ecosystems at Shapotou, northwestern China, to study relationships between surface albedo, solar elevation angle, and surface soil moisture. Results indicated that rainfall exerted a remarkable lowering effect on the variation of surface albedo by increasing surface soil moisture. Surface albedo was an exponential function of solar elevation angle, and the normalized surface albedo (solar elevation angle effect was removed) decreased exponentially with the increase of surface soil moisture. Sand surface had a higher albedo (0.266) than BSCs (0.226) when the surfaces were very dry. However, sand surface albedo became increasingly lower than that of BSCs when the surfaces were in wet conditions and when the soil moisture exceeded a critical value. The changes in soil surface albedo from sand dune to BSCs after revegetation in shallow soil profiles associated with the variation of the surface soil moisture can be seen as an indicator of the degree of sand dune stabilization when compared with the original shifting sand dune soil.     

Reservoir characteristics and main controlling factors of oil sand in Houba area,northwestern Sichuan Basin,China

Houba oil sand in frontier Longmenshan Mountain is one of the most typically important unconventional resources. The basic reservoir characteristics of oil sand and the main factors affecting reservoir quality were examined in this article based on porosity, permeability, and mercury porosimetry measurements; thin section analyses; SEM observation; and X-ray diffraction analysis. This study shows that the oil-bearing sandstone reservoir is mainly medium?coarse-grained sublitharenite and litharenite. The main pore type is intergranular pores, including residual primary intergranular pores, dissolved intergranular pores, and dissolved intragranular pores; fractures are common in this study area. The quality of sandstone reservoir is of high porosity and high permeability with a high oil saturation of 89.84 %. It is indicated that the main controlling factors of the reservoir in the study area include deposition, diagenesis, and tectonism. Deposition laid a foundation to porosity evolution, and channel sand is the most favorable depositional facies for the reservoir. Diagenetic alterations are the keys to reservoir evolution; dissolution and chlorite coatings cementation play an effective role in the generation and preservation of pores. Compaction, carbonate cementation, and quartz overgrowth cause many damages to the reservoir porosity. Fractures caused by structural breakages can improve the reservoir permeability and they also can provide fluid migration pathways to the late corrosion, which formed a lot of corroded fissures as reservoir and percolation spaces.     

应用响应曲面法优化凯氏定氮法的消解条件

经典凯氏定氮法是通过观察消解反应现象来控制温度和时间,对于数量较多的样品同时消解会耗费大量的人力及时间,因此需要采用合理的试验设计方法确定最佳消解温度和时间,以实现批量消解样品,提高分析效率。本文利用响应曲面法对凯氏定氮法中的消解条件进行了优化分析,选择料液比、消解温度和消解时间作为优化因素,研究三因素的不同水平对氮含量测定的影响。通过响应曲面分析得到最优的消解条件为:料液比(g/mL)=0.3∶5,消解温度260℃,消解时间60 min。重复实验结果表明,样品在优化的条件下能够很好地消解,重现性较好;标准物质的氮含量的实验测定值(1310×10-6)与标准值(1300×10-6)基本一致,两者的对数误差绝对值为0.003,方法的准确性高。应用响应曲面试验设计方法,对于评价凯氏定氮法中三个消解条件对氮含量的非线性影响起到了很好的优选作用,能更好地预测实验因素对分析结果的影响趋势,可以准确控制消解温度和消解时间,对于提高分析效率具有实用意义。     

黔东北地区钒矿床地球化学特征及成因研究

近年来在黔东北地区先后发现了多个中_大型沉积型钒矿床,它们均赋存在寒武系下统九门冲组(∈1jm)下部的黑色碳质泥岩中。为了从地球化学方面深入探讨该类钒矿床中含矿岩系的沉积环境以及矿床成因类别,选用电感耦合等离子体质谱(ICP_MS)法对钒矿体及其上、下地层的样品进行了主量、微量和稀土元素测试,采用层序地层学方法对典型钒矿床的含矿岩系地层进行剖析,充分利用地球化学元素对环境的敏感特性探索了含矿岩系形成的氧化还原条件和矿床成因。结果表明,含矿岩系主要为海相深(浅)水陆棚相沉积物,因沉积过程中沉积相的多次演变,形成了现在具有一定差异的岩性组合。同时,因地球化学场的不断变化,沉积物中主量、微量和稀土元素的含量呈现了特有的分布规律。文章首次从地球化学方面揭示了该区含矿岩系及钒矿层均是还原环境下的产物,钒矿床以正常海相沉积成因为主,仅与生物作用有一定关系,受热水影响并不明显。这对钒矿床的成矿预测以及实现更大找矿突破,具有一定意义。     

内蒙古卓资县大苏计斑岩型钼矿床辉钼矿Re-Os同位素年龄及流体包裹体研究

内蒙古卓资县大苏计钼矿床位于华北克拉通北缘中段的凉城断隆内,是近年来在华北克拉通北缘发现的一个大型斑岩钼矿床,矿体主要产于印支期石英斑岩和正长花岗斑岩中。成矿过程可以划分为石英_钾长石_黄铁矿±辉钼矿±磁铁矿阶段(早阶段)、石英_绢云母_辉钼矿_黄铁矿阶段(中阶段)和石英_方解石_黄铁矿±闪锌矿±方铅矿阶段(晚阶段)。矿石中5件辉钼矿的Re_Os同位素模式年龄介于(223.6±3.1)Ma~(224.2±3.4)Ma之间,其加权平均值为(223.9±1.4)Ma(MSWD=0.017),等时线年龄为(223.5±5.5)Ma(MSWD=0.026),表明大苏计钼矿床形成于印支期。大苏计钼矿床发育富液型、富气型、H2O_CO2型、含子矿物型和纯气相包裹体。成矿早阶段主要发育富液型、富气型包裹体,另有少量H2O_CO2型包裹体,其均一温度介于342~430℃之间,盐度w(Na Cleq)介于3.4%~11.0%之间;中阶段主要发育富液型、富气型、H2O_CO2型和含子矿物型包裹体,另有少量纯气相包裹体,其均一温度为234~380℃之间,盐度w(Na Cleq)介于6.2%~34.9%之间;晚阶段仅发育富液型包裹体,其均一温度介于202~280℃之间,盐度w(Na Cleq)介于1.2%~11.7%之间,指示该阶段有大气降水的加入。成矿流体从早、中阶段的H2O_Na Cl_CO2体系演化为晚阶段的H2O_Na Cl体系。早、中阶段流体均为不混溶流体,流体沸腾是成矿物质沉淀的主要机制。集宁地区钼矿床主要为斑岩型,至少存在晚三叠世和晚侏罗世2期钼成矿事件。     

Investigation of karst hydrological processes by using grey auto-incidence analysis

The karst hydrological processes are the response of karst groundwater system to precipitation. The precipitation penetrates through the vadose zone, the subsequent groundwater pressure wave propagates to a spring outlet, and then, the spring discharge changes. This paper proposes a grey auto-incidence analysis for studying the karst hydrological processes. The method can detect the periodicity of a time series, for example, precipitation and spring discharge. Then the approach is applied to Liulin Springs Basin, China. The results show that the auto-incidence degree of precipitation reaches to the maximum (i.e., 0.816) when time delay equals to 8 years. The auto-incidence degree of spring discharge reaches to the maximum (i.e., 0.865) when time delay equals to 3 years. These results show that the periodicity of precipitation is 8 years, and of spring discharge is 3 years. The difference of periodicity between the precipitation and the spring discharge reveals that the processes of precipitation recharging groundwater and groundwater transport are regulated or controlled by karst aquifer. Because of heterogeneity of karst aquifer, the quick flow and base flow occur during the groundwater propagation, which causes the periodicity of spring discharge is not coincidence with of precipitation.