离子色谱法检测土壤样品水溶态中的七种阴离子

采用离子色谱法测定土壤样品水溶态中的F^-、Cl^-、NO2^-、SO4^2-、Br^-、NO3^-、PO4^3-。通过优化提取条件,得出最优条件下7种阴离子的加标回收率为94.4%～102.5%,精密度为3.1%～4.6%。对实际样品进行测试,结果表明,该方法适用于土壤样品水溶态中7种阴离子的定性、定量分析。     

稀土元素对鲁西铜石、铜井、龙宝山杂岩体的同源性制约

20世纪80年代,在山东省平邑县发现归来庄大型金矿床,实现了鲁西黄金找矿的重大突破。此后,鲁西相继发现卓家庄、磨坊沟和龙宝山金矿。近年,又在沂南金矿的深部发现新的矿体,鲁西良好的金矿成矿前景引起了地质学界的广泛关注。目前,鲁西发现的金矿床主要分布在铜石、铜井和龙宝山等燕山期杂岩体的附近。这些岩体在成因上有什么关系值得研究。通过对上述岩体稀土元素的地球化学分析,每种岩体不同期次侵入的岩浆岩的稀土元素分布形式和3种岩体综合稀土元素分布形式均呈向右陡倾的弧形线,且配分曲线形态基本相似,都没有明显的Ce、Eu异常,指示了岩体之间存在同源性,均来自深部同一岩浆房。该认识对于指导鲁西黄金找矿具有一定的意义。     

Mineralogy and Mineral Chemistry of the Cretaceous Duolong Gold‐Rich Porphyry Copper Deposit in the Bangongco Arc,Northern Tibet

The Early Cretaceous Duolong gold‐rich porphyry copper deposit is a newly discovered deposit with proven 5.38 Mt Cu resources of 0.72% Cu and 41 t gold of 0.23 g t^?1 in northern Tibet. Granodiorite porphyry and quartz diorite porphyrite are the main ore‐bearing porphyries. A wide range of hydrothermal alteration associated with these porphyries is divided into potassic, argillic and propylitic zones from the ore‐bearing porphyry center outward and upward. In the hydrothermal alteration zones, secondary albite (91.5–99.7% Ab) occurs along the rim of plagioclase phenocryst and fissures. Secondary K‐feldspar (75.1–96.9% Or) replaces plagioclase phenocryst and matrix or occurs in veinlets. Biotite occurs mainly as matrix and veinlet in addition to phenocryst in the potassic zone. The biotite are Mg‐rich and formed under a highly oxidized condition at temperatures ranging from 400°C to 430°C. All the biotites are absent in F, and have high Cl content (0.19–0.26%), with log (X_Cl/X_OH) values of ?2.74 to ?2.88 and IV (Cl) values of ?3.48 to ?3.35, suggesting a significant role of chloride complexes (CuCl₂^‐ and AuCl₂^‐) in transporting and precipitating copper and gold. Chlorites are present in all alteration zones and correspond mainly to pycnochlorite. They have similar Fe/(Fe+Mg), Mn/(Mn+Mg) ratios, and a formation temperature range of 280–360°C. However, the formation temperature of chlorite in the quartz‐gypsum‐carbonate‐chlorite vein is between 190°C and 220°C, indicating that it may have resulted from a later stage of hydrothermal activity. Fe³⁺/Fe²⁺ ratios of chlorites have negative correlation with Al^IV, suggesting oxygen fugacity of fluids increases with decreasing temperature. Apatite mineral inclusions in the biotite phenocrysts show high SO₃ content (0.44–0.82%) and high Cl content (1–1.37%), indicating the host magma had a high oxidation state and was enriched in S and Cl. The highest Cl content of apatite in the propylitic zone may have resulted from pressure decrease, and the lowest Cl content of apatite in the argillic zone may have been caused by a low Cl content in the fluids. The low concentration of SO₃ content in the hydrothermal apatite compared to the magmatic one may have resulted from the decrease of oxygen fugacity and S content in the hydrothermal fluid, which are caused by the abundant precipitation of magnetite.     

西昆仑康西瓦断裂西段斜长片麻岩LA-ICP-MS锆石U-Pb定年及其构造意义

在康西瓦断裂西段发育着一套含石榴子石二云斜长片麻岩。根据锆石的阴极发光图像和Th、U、REE等特征,锆石可分为岩浆成因和变质热液成因2类。利用LA-ICP-MS法进行锆石U-Pb定年,测得含石榴子石斜长片麻岩的源岩形成年龄为254.5Ma±4.2Ma(MSWD=0.16),变质年龄为242.7Ma±2.3Ma(MSWD=0.11)。结合区域地质资料,含石榴子石二云斜长片麻岩的变质作用与古特提斯碰撞造山有关,表明西昆仑造山带在中三叠世早期(243Ma)仍处于古特提斯碰撞造山期。     

湘南宜章地区辉绿岩、花岗斑岩、安山岩的形成时代和成因——锆石U-Pb年龄和Hf同位素组成

湘南宜章县长城岭地区广泛出露以辉绿岩、花岗斑岩为主的燕山早期岩体,而宜章平和地区主要分布安山岩体,其年龄和成因有待进一步研究。分别用SHRIMP和LA-ICP-MS法测试了它们的年龄和Hf同位素组成,长城岭辉绿岩的SHRIMP锆石U-Pb年龄为153.7Ma±3.1Ma、227.0Ma±4.2Ma;长城岭花岗斑岩的LA-ICP-MS锆石U-Pb测年结果为153Ma±14Ma和231.58Ma±0.67Ma;平和安山岩的SHRIMP锆石U-Pb测年结果为159Ma±14Ma和229.3Ma±7.6Ma,LA-ICP-MS锆石U-Pb测年结果为161Ma±1Ma,显示为燕山早期岩浆侵位和印支期基性岩浆底侵。锆石Lu-Hf同位素原位分析结果表明,εHf(t)值在正值和负值范围内变化,指示岩浆为壳幔混合来源。结合长城岭花岗岩体中继承锆石的年龄信息,认为花岗质岩石可能来源于中元古代基底的重熔。岩体岩浆很可能是由元古宙火成岩石部分熔融形成的,并伴有年轻或新生幔源物质的加入,岩浆上升侵位的过程中发生了混合作用。     

基于InSAR技术的江苏水闸垂直位移监测方法可行性探讨

利用Sentinel-1雷达卫星影像,探讨InSAR技术作为水闸垂直位移变形监测辅助手段的可行性。结果表明,InSAR技术与水准测量相比,两种方法得到的水闸垂直位移变化趋势基本一致;InSAR测量结果具有可信性,后续可进一步推广应用。     

空间U统计量法在遥感蚀变信息提取中的应用研究

鉴于传统蚀变异常信息提取方法的局限性,试图在二维光谱特征空间(即散点图)中研究遥感蚀变信息的提取方法.在二维散点图中,两个波段灰度值的联合分布体现了各向异性的特点,聚类常呈类似椭圆形分布.对散点图中点的频数使用空间U统计量法逐个获得地物聚类的椭圆参数,将每个椭圆内的点映射到遥感图像上,经过目视解译,最终获得蚀变异常信息...     

POS数据的上下视差误差源检测及误差补偿回归模型

分析POS数据存在系统误差的主要原因,推导基于POS的立体像对相对定向模型,建立POS系统误差回归补偿模型。三个不同比例尺测区试验数据的结果表明：POS系统提供的外方位元素中角元素误差是引起模型上下视差的主要误差源;利用回归补偿模型对POS数据进行改正后模型上下视差明显减小;在无需区域网平差的情况下,直接通过相对定向消除POS系统误差,定位精度有较大提高,从而证明该补偿模型的正确性与可行性。     

基于相对定向和三角形约束的近景影像匹配

针对近景影像自动相对定向过程中初匹配点对中误匹配率较大的情况,将基于三角形约束方法引入近景影像匹配.首先利用Harris算子提取特征点集,经初匹配后运用基于RANSAC方法和P-H算法的相对定向构建核线几何得到内点集,删除误匹配点生成同名Delaunay三角网;在同名三角形的约束下通过缩小Harris特征点阈值得到新内...     

导航电子地图生产过程中的质量控制方法

从分析导航电子地图数据特点和质量特性入手,给出导航电子地图生产过程中从检测标准、质控设置、检验手段到质量改进的质量控制过程。