六横大岙附近海域环境质量现状评价

根据１９９５年４月对码头工程区附近海域的水质和沉积物的环境质量现场调查,采用环境质量指数法,评价了该海区水质和沉积物的环境质量状况。结果表明,水质中无机氮严重超标,超三类标准的超标率达１００％。无机磷超一类标准的超标率达１００％,有个别测站超二类标准。ＣＯＤ、ｐＨ、ＤＯ、油类均低于一类海水标准。潮间带水质基本符合一类水质要求。底质环境质量现状良好     

南极低温降解菌Shewanella sp. NJ49羟化酶分离纯化及最适产酶条件研究

羟化酶是细菌降解烷烃的关键酶,本文以南极低温降解菌Shewanella sp.NJ49为研究对象,通过硫酸铵沉淀、超滤浓缩及葡聚糖凝胶Sephadex G-75柱层析方法,分离纯化NJ49的羟化酶,获得了单一羟化酶组分,研究了温度、p H、表面活性剂和盐度等环境因素对NJ49羟化酶酶活活性影响。结果表明,羟化酶组分由α、β、γ三个亚基组成,分子质量分别为56,45和36 k D。NJ49最适产酶条件为:温度15℃、p H7.2、盐度55;不同类型表面活性剂对酶的活性影响效应不一,两性离子表面活性剂、阳离子表面活性剂、非离子表面活性剂对酶活没有作用,阴离子表面活性剂+非离子表面活性剂混和剂和阳离子表面活性剂+非离子表面活性剂混和剂能提高羟化酶的活性。     

大面积开荒扰动下的三江平原近45年气候变化

黑龙江省三江平原近45年来，经过大规模的开荒，农田已取代原来的沼泽和沼泽化湿地，成为现今三江平原的主要景观类型，其下垫面发生了巨大变化，采用1955－1999年三江平原地区21个气象台站的气温，降水，日照时数和气压4个要素的资料，分析近45年来三江平原的气候变化和发展趋势：用Yamamoto法和Mann-Kendall法对5年滑动平均的区域季节和年时间序列进行突变检测，定量地认述了三江平原地区的气候变化事实，对于各气候要素出现在20世纪60年代，70年代和80年代的突变事实，尤其是20世纪70年代以来的阶梯式的持续变暖事实，认为三江平原区域气候系统内部的变化可能是引起这些突变的直接原因。     

鲁北济阳坳陷沾化凹陷东部潜山的发育及油气成藏控制因素

通过对沾化凹陷东部主要断裂发育演化的特征和主要地震测线的平衡剖面、伸展率分析,对该地区潜山发育过程及其与盆地演化的关系进行了研究,并就潜山油气成藏的控制因素进行了分析.结果表明,沾化凹陷东部潜山发育可以划分为早-中三叠世、晚三叠世、早-中侏罗世的潜山发育前期,晚侏罗世-白垩纪的潜山发育期,古近纪的潜山改造、定型期和新近纪-第四纪的潜山成藏期,断裂活动是本区潜山形成演化的主控因素.沾化凹陷东部潜山油气成藏主要受控于该区中、新生代盆地的叠合关系,中生代凸起和古近纪凹陷的叠合部位是最有利的潜山油气成藏区,中生代凸起和古近纪凸起的叠合部位不利于潜山成藏,往往形成潜山披覆背斜油气藏.     

Molybdenum Mass Fractions and Isotopic Compositions of International Geological Reference Materials

The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ^98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ^98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g^?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.     

五圆柱体结构群绕流特性及互扰效应研究

基于Fluent流体计算平台,运用大涡模拟方法对亚临界雷诺数Re=3900下“X”形排列五圆柱体结构群三维绕流特性进行研究,主要分析来流攻角α与间距比L/D两个关键参数对五圆柱体结构群的尾流区三维涡结构演化与流体力系数的影响,并揭示其内在流动互扰机理。研究表明:来流攻角和间距比的变化对五圆柱体结构群流动控制及互扰效应的影响显著。在小间距比工况下,观察到柱体群间隙区域内流体高速流动的现象,导致五圆柱体之间的互扰作用十分强烈。间隙流对中间圆柱体和下游圆柱体有较强的冲击作用,对其表面的流体力分布特性有显著的影响。另外,大间距比工况下,当α=0°与L/D≥5.0工况时,柱体群尾流效应强于其间隙流效应。当α=22.5°与L/D=7.0时,位于下游与中间处的圆柱体流体绕流特性存在较大差异。而当α=45°与L/D≥6.0时,位于上游与中间处的圆柱体尾流区均会产生正负交替的漩涡结构。     

Crude-oil hydrocarbon composition characteristics and oil viscosity prediction in the northern Songliao Basin

Crude oil hydrocarbon composition characteristics and oil viscosity prediction are important bases in petroleum exploration.A total of 54 oil/heavy-oil samples and 17 oil sands were analyzed and quantified using both comprehensive 2D gas chromatography(GC×GC)and comprehensive 2D gas chromatography/time-of-flight mass spectrometry(GC×GC/TOFMS).The results show that crude oil in the West slope is mainly heavy oil and its hydrocarbon composition is characterized overall by paraffinsmono-aromaticsnaphthenesnon-hydrocarbonsdi-aromaticstri-aromaticstetra-aromatics.Aromatics are most abundant and non-hydrocarbons are least abundant,whilst content differences among paraffins,naphthenes,aromatics,and non-hydrocarbons are less than 15%.There are two types of heavy oil,secondary type and mixing type.Biodegradation is the main formation mechanism of heavy oil.Biodegradation levels cover light biodegradation,moderate biodegradation,and severe biodegradation.With increasing biodegradation,paraffin content decreases while contents of aromatics and nonhydrocarbons increase.In contrast,naphthene content increases first and then decreases with increasing biodegradation.In severe biodegradation stage,naphthenes decrease more quickly than aromatics and non-hydrocarbons.This provides a new method for studying oil/heavy-oil biodegradation mechanism and biodegradation resistance of different hydrocarbons at different biodegradation stages.In the Longhupao-Daan terrace and Qijia-Gulong depression,most crude oil is conventional oil.Its composition is dominated by paraffins with the lowest content of aromatics.In some casual oil wells from the Longhupao-Daan terrace,crude oil from Saertu oil reservoirs is moderately biodegraded whereas crude oil from Putaohua oil reservoir is lightly biodegraded.Chemical parameters using saturate hydrocarbons and aromatics are usually not suitable for determining organic type and thermal maturity of biodegraded oil,especially of moderately or severely biodegraded oil,whilst Ts/(Ts+Tm)ratio can be used to determine thermal maturity of both conventional crude oil and heavy oil.     

新疆东天山天宇、白石泉杂岩体岩石学、矿物学特征对比研究

天宇和白石泉铜镍矿区含矿镁铁-超镁铁质杂岩体是东疆铜镍成矿带的重要组成部分。天宇矿区杂岩体以角闪辉长岩、角闪单辉橄榄岩、橄榄辉石岩、二辉辉石岩为主;白石泉矿区杂岩体则以辉石闪长岩、角闪辉长岩、橄榄辉石岩、辉石辉长岩、辉石橄榄岩、橄长岩为主;天宇矿区含矿超基性岩中SiO2,Al2O3,CaO,K2O,Na2O的质量分数比白石泉岩体低,Fe2O3,MgO相对较高;两个杂岩体的主要造岩矿物均以橄榄石、辉石、斜长石为主;铜镍矿石的矿物组成都较简单,金属矿物种类基本一致;两个杂岩体基性-超基性岩的成分接近原始岩浆,均来自于地幔,均属含铜镍中等的镁铁质岩石。     

江西冷水坑矿区构造-岩浆活动的年代学约束

江西省冷水坑矿区火成岩-构造演化一直缺少系统的年代学制约.作者运用LA-ICP-MS锆石U-Pb和40Ar/39Ar测年技术,对冷水坑矿区两套火山岩地层(打鼓顶组和鹅湖岭组)、含矿花岗斑岩和主推覆断层F2进行了年代学测试,结果表明,打鼓顶组流纹质含角砾熔结凝灰岩形成于160.8±1.9Ma,鹅湖岭组合角砾熔结凝灰岩则具有间歇性和多期喷发特点,其最初活动时间为159Ma,而主体形成于146.6±2.2Ma;矿区含矿花岗斑岩与打鼓顶组、鹅湖岭组几乎同期形成,年龄介于163.6 ±2.1Ma～154.3±3.0Ma之间;研究区构造活动起始时间不晚于加里东期,推覆断层F2中保留有40Ar/39Ar年龄为398.5±2.6Ma的构造活动痕迹,中生代重新复活,导致震旦系叠覆于鹅湖岭组之上,年龄晚于146.6Ma,可能对含矿斑岩体起破坏作用.     

水平定向勘察技术在长大隧道勘察中的应用现状与展望

西南高山峡谷区是我国重大铁路交通工程规划建设的重点区域,如川藏铁路建设等,深埋、长大隧道数量多,常规垂直孔勘察方法无法满足精细化地质勘察的需求。采用水平定向勘察技术沿隧道设计轴线施工水平定向孔为隧道勘察提供了一种有效的手段。水平定向勘察技术的核心包括钻进技术、取心技术、钻孔轨迹控制技术、随钻测量/随钻测井技术、综合测井技术等。结合国内外水平定向勘察技术的发展应用现状,分析了目前存在的问题,提出了开展单次钻探长度超3000 m的水平定向多工艺钻进关键技术与装备攻关,构建安全、高效、经济合理的水平定向勘察技术体系的建议。