Gold Solubility in SiO2—HCl—H2O System at 200℃：a Preliminary Assessment of the Implications of Silicification with Regard to Gold Mineralization

The complexation between gold and silica was experimentally, confirmed and calibrated at 200 °C: $$\begin{gathered} Au^ + + H_3 SiO_4^ - \rightleftharpoons AuH_3 SiO_4^0 \hfill \\ \log K_{(200^\circ C)} = 19.26 \pm 0.4 \hfill \\ \end{gathered} $$ Thermodynamic calculations show that AuH₃SiO ₄ ⁰ would be far more abundant than AuCl ₂ ^? under physicochemical conditions of geological interest, suggesting that silica is much more important than chloride as ligands for gold transport. In systems containing both sulfur and silica, AuH₃SiO ₄ ⁰ would be increasingly more important than Au (HS) ₂ ^? as the proportion of SiO₂ in the system increases. The dissolution of gold in aqueous SiO₂ solutions can be described by the reaction: $$\begin{gathered} Au + 1/4O_2 + H_4 SiO_4^0 \rightleftharpoons AuH_3 SiO_4^0 + 1/2H_2 O \hfill \\ log K_{(200^\circ C)} = 6.23 \hfill \\ \end{gathered} $$ which indicates that SiO₂ precipitation is an effective mechanism governing gold deposition, and thus explains the close association of silicification and gold mineralization.     

云南省禄劝县开发方向的初步研究

云南省禄劝县隶属昆明市辖区,是一个国家级扶贫开发重点县之一.境内河流众多,水资源丰富,但地表切割强烈,山高谷深,坝地仅占总面积的1.6%,复杂的地貌条件严重制约了县域经济的发展.从禄劝县资源优势出发,变劣势为优势,提出发展生态种植业,生态养殖业和生态林果业的持续农业发展方向,使禄劝县发展成昆明市的菜篮子基地,为农民脱贫致富,增加收入提出了一条切实可行的路子.     

Two-dimensional pH distributions and dynamics in bioturbated marine sediments

The seafloor is the site of intense biogeochemical and mineral dissolution-precipitation reactions which generate strong gradients in pH near the sediment-overlying water interface. These gradients are usually measured in one-dimension vertically with depth. Two-dimensional pH distributions in marine sediments were examined at high resolution (65 × 65 μm pixel) and analytical precision over areas of ∼150 to 225 cm² using a newly developed pH planar fluorosensor. Dramatic three-dimensional gradients, complex heterogeneity, and dynamic changes of pH occur in the surficial zone of deposits inhabited by macrofauna. pH can vary by ±2 units horizontally as well as vertically over millimeter scales. pH minima zones often form in association with redoxclines within a few millimeters of inner burrow walls, and become more pronounced with time if burrows remain stable and irrigated for extended periods. Microenvironmental pH minima also form locally around decaying biomass and relict burrow tracks, and dissipate with time (∼5 d). H⁺ concentrations and fluxes in sandy mud show complex acid-base reaction distributions with net H⁺ fluxes around burrows up to ∼12 nmol cm⁻² d⁻¹ and maximum net reaction rates varying between −90 (consumption) to 120 (production) μM d⁻¹ (∼90 nmol cm⁻¹ d⁻¹ burrow length). Acid producing zones that surround irrigated burrows are largely balanced by acid titration zones along inner burrow walls and outer radial boundaries. The geometry and scaling of pH microenvironments are functions of diagenetic reaction rates and three-dimensional transport patterns determined by sediment properties, such as diffusive tortuosity, and by benthic community characteristics such as the abundance, mobility, and size of infauna. Previously, undocumented biogeochemical phenomena such as low pH regions associated with in-filled relict biogenic structures and burrowing tracks are readily demonstrated by two-dimensional and time-dependent images of pH and sedimentary structure.     

钻孔灌注桩缺陷桩处理实践

在颍河特大桥桩基施工中灌注35号墩-1桩基时，混凝土输送泵出现故障造成浇注中断，桩基检测时发现缺陷，采用旋喷压浆技术进行处理，经检测合格。对采用旋喷压浆处理桩基缺陷的全过程进行了介绍，并对施工中出现的技术问题进行分析。     

邢台矿区山字型构造的发现及其地质意义

邢台山字型构造位于河北省邯邢煤田内，其前弧向ES突出，脊柱呈ES-WN走向。分别分析了山字型构造脊柱及其东、西翼反射弧构造形迹特征，对研究区找矿具有重要意义。     

淮北煤田孙庄勘探区煤层气赋存规律及影响因素分析

通过对淮北煤田孙庄勘探区地质构造、沉积特征、煤层煤质及煤层气赋存特征的分析，研究认为有利于本区煤层气赋存的主要因素是较大的埋藏深度、较高的壳质组＋镜质组、较高的变质程度、较大的煤层厚度、低透气性的盖层、较缓的地层倾角和封闭性较好的构造条件，推测煤田深部可能具有一定工业价值的煤层气资源。     

氢化物发生-原子荧光光谱法测定地球化学样品中痕量碲

采用焙烧富集分离地球化学样品中痕量Te,并用氢化物发生原子荧光光谱法测定。通过实验确定出方法的最佳实验条件,在此条件下获得的检出限为0.005μg/g,线性范围0.025~10μg/g,精密度(RSD,n=8)为5.03%~9.24%。方法已用于国家一级地球化学标准物质中痕量Te的测定,结果与标准值基本相符。     

过硫酸铵氧化容量法测定矿石中锰方法的改进

采用过硫酸铵氧化容量法测定锰时,可在低酸度(0.18mol/LH2SO4、0.29mol/LH3PO4)和大体积(300mL)溶液中氧化Mn2 至Mn7 。所测得的结果十分稳定,回收率为100%。采用管理样分析验证方法,其结果与铋酸钠容量法结果一致。对于w(Mn)=11.36%的试样进行10次分析测定,RSD=0.33%。方法可测定w(Mn)≥0.01%的常见矿种样品。     

基于地表定量参数的沙漠化遥感监测方法

利用野外沙漠化调查的定位数据和ETM+ 遥感数据，在实验分析的基础上，探讨了沙漠化程度与地表参数之间的定量关系，即沙漠化与植被指数（NDVI）、地表辐射温度（LST）之间的关系，提出了综合反映沙漠化土地生物物理特征的遥感监测指数——沙漠化遥感监测差值指数（DDI），为沙漠化遥感监测提供有效的定量化方法。     

贵州关岭生物群中植物化石的发现及其意义

关岭生物群是近年来在我国贵州关岭地区瓦窑组中发现的一个十分重要的生物群 ,其中的植物化石经研究计有 Equisetites cf.arenaceus(Jaeger) Bronn.、Ctenozamitessarrani Zeiller。依据植物化石 C.sarrani常见于晚三叠世和 E.cf.arenaceus系似木贼属中较古老的类型 ,指出含植物化石的地层时代为晚三叠世卡尼期。瓦窑组系海相沉积 ,其中的植物化石无疑为异地埋藏 ,但从化石通常保存尚好来看 ,估计搬运的距离不会很远 ,它们可能是从距海岸不远的陆地被河流带到较平静的海湾或海槽而沉积下来的。此外 ,从该组植物茎干化石具清楚的年轮分析 ,推测卡尼期时 ,贵州关岭一带为非热带雨林地区 ,一年中气候不是四季如一 ,而是有明显的季节变化