Copper(II) humate mobility in kaolinite soil

An investigation of the influence of humate on the mobility of copper(II) ions in a kaolinite soil using leaching tests and electrokinetic experiments is reported. The data are interpreted in terms of humate–copper–clay interactions and humate electrical charge. Humate is mostly immobile below pH8 but is more mobile in alkaline conditions (sorption to kaolinite reduces its mobility in neutral conditions). Copper humate complexes are mobile in both acidic and alkaline conditions, but not in neutral conditions where they are sorbed. The dissolved copper humate complexes that form in acidic conditions are positively charged. The net effect of humate is to increase cupric ion mobility in kaolinite soil, especially in alkaline conditions.     

Reconstruction of palaeosalinity using carbon isotopes and benthic associations: a comparison

Carbon and oxygen isotopes were determined on 40 recrystallized shells of Late Jurassic bivalves from the Lusitanian Basin of Portugal. In contrast with the oxygen isotopes, which exhibited considerable diagenetic distortion, the carbon isotopes are thought to preserve a record of the salinity of the Jurassic marginal marine seas in which these bivalves lived. The reconstructed palaeosalinities range from 35%o (euhaline) to 5% (oligohaline). Comparing these values with the palaeosalinity reconstructed from a palaeoecological analysis of 17 stratigraphic levels within the basin, the independently derived values agree in most cases. Strongly differing values are explained as being due to biotic factors and to diagenetic distortion of the isotopic signal; they are less likely to be due to smallscale time-averaging or insufficient microstratigraphic sampling. On the whole, the carbon isotope analyses are thought to produce reasonable palaeosalinity values, although data from infaunal, originally aragonitic bivalves appear to be less reliable than those from epifaunal bivalves with a predominantly or exclusively calcitic shell. As diagenetic alteration of the carbon isotope signal is, however, unpredictable and biotic effects on the isotopic composition are insufficiently known, palaeosalinity reconstructions based on stable isotope data should be supported by palaeoecological data.     

Improved Petrological Modal Analyses from X-ray Powder Diffraction Data by use of the Rietveld Method I. Selected Igneous, Volcanic, and Metamorphic Rocks

Mineral modes have been determined for specimens of eight rocktypes from CuK X-ray powder diffraction data using the Rietveldmethod. The samples include two granites, a granodiorite, adamellite,gabbro, basalt, trachyte, and two granulite-facies metamorphicrocks. Up to eight individual mineral components have been measuredin each sample (no glassy phases were observed), with a detectionlimit of {small tilde}1 wt.%, depending on the mineral assemblage.Marked variations in grain size (i.e., granite vs. trachyte)provide no difficulties for the X-ray method. The X-ray resultscompare very favourably with (1) optical modes determined forthe medium–coarse-grained samples by point counting, (2)normative calculations obtained using locally enhanced catanormand mesonorm software, and (3) corresponding Rietveld modesdetermined, for two samples, from neutron powder data. Wheredifferences occur, these are discussed in relation to the limitationsof each of the methods. The improved accuracy of the X-ray method is due primarily tothe incorporation of the full diffraction profile in the Rietveldanalysis calculations, and the elimination of preferred orientationby collecting the data from samples packed in glass capillaries(i.e., Debye–Scherrer mode). The good agreement of theX-ray and neutron modes shows that the usual problems encounteredwith microabsorption, extinction, and sampling are of littleconcern in these rocks. The results highlight one of the majoradvantages provided by Rietveld modal analysis over the moretraditional ‘reference intensity’ X-ray methods,namely, that the crystal chemistry (and thus the calibrationconstants) of the individual phases can be adjusted dynamicallyduring each individual analysis. This not only provides moreaccurate phase abundances, but also gives important supplementaryinformation about the mineralogy of the major components.     

桥梁气象专题研究与服务

根据实际开展的桥梁气象专题研究，分析桥梁气象研究与服务如何面对国内大型桥梁建设发展趋势所带来的机遇和挑战，提出开展桥梁气象研究与服务的必要性，并从桥位气候背景、桥位气象参数取值、桥梁气象研究方法以及桥梁施工及营运期气象服务与保障等方面介绍桥梁气象专题研究及服务应开展的主要内容，同时，给出一个已投入实际使用的桥梁施工期气象环境监测与预警系统的建设思路。     

冬春季切变类冰雹发生条件的对比分析

本文以 1996年 12月 31日和 1981年 5月 1日为例 ,对冬、春季节发生在江苏的较大范围的切变类冰雹天气过程作了对比分析。结果指出 ,无论冬季或春季当高原东部有深槽东移 ,冷暖空气在江淮地区交汇 ,地面抬升系统为暖切 ,并有大气层结不稳定 (Δθse( 50 0 - 850 ) <0℃ =中心和较强的风向和风速垂直切变、85 0hPa西南急流轴、85 0hPa最大水汽通量轴线、5 0 0和 85 0hPa正涡度中心等相配置时 ,就可能导致江苏地区较大范围强对流天气的发生。     

A Case study of a snowstorm at the Great Wall Station,Antarctica

A case of a snowstorm at the Great Wall Station was studied using data of NCEP (National Centers for Environmental Prediction) analysis, in situ observations and surface weather charts. The storm occurred on August 29th,2006, and brought high winds and poor horizontal visibility to the region.It was found that the storm occurred under the synoptic situation of a high in the south and a low in the north. A low-level easterly jet from the Antarctic continent significantly decreased the air temperature and humidity.Warm air advection at high level brought sufficient vapor from lower latitudes for the snowstorm to develop.The dynamic factors relating to strong snowfall and even the developmentof a snowstorm were deep cyclonic vorticity at middle and low levels,the configuration of divergence at high level and convergence at low level, and strong verticaluplift. There was an inversion layer in the low-level atmosphere during the later phase of the storm.This vertical structure of cold air at low levels and warm air at high levels may have been important to the longevity of the snowstorm.     

Photometrische Kalibrierung von Schmidtspiegelaufnahmen durch ein bildteilendes Hilfsprisma

Plates of the Tautenburg Schmidt can be calibrated with the aid of a beam-splitting prisma only if Schraffierkassette plates are used. The effects of image structure, scintillation and intermittence on in-focus images are different for the main component and the prismatic companion. Therefore, such plates cannot be used to set up a photometric scale.     

An internal-external optimized convolutional neural network for arbitrary orientated object detection from optical remote sensing images

Due to the bird's eye view of remote sensing sensors, the orientational information of an object is a key factor that has to be considered in object detection. ...     

A new semi-quantitative Surface-Enhanced Raman Spectroscopy (SERS) method for detection of maleimide (2,5-pyrroledione) with potential application to astrobiology

Nitrogen-containing heterocyclic compounds are fundamental biochemical components of all life on Earth and, presumably, life elsewhere in our solar system. Dete...