Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

地形因素对航空面阵CCD影像的影响分析与评价

地形因素,包括地面起伏和地球曲率,是造成航空数字遥感影像变形的主要原因之一.本文以中国科学院遥感所自行研发的多模态航空CCD相机系统为对象,结合其成像模式和几何形态,分析了地形因素给影像带来的变形,推导出航空面阵CCD影像变形的一般公式,并通过概算进行了定量评价,得出了对于航空面阵CCD影像,要想得到高精度的几何处理,必须改正地球曲率影响的结论.     

石油测井光电编码器深度测量系统

介绍了石油测井深度光电编码器测量系统的测量原理、系统组成以及电路分析,同时在对系统误差分析的基础上给出了具体校正方法。     

Vertical distribution and water solubility of phosphorus and heavy metals in sediments of the St. Lucie Estuary, South Florida, USA

Accumulation and distribution of heavy metals and phosphorus in sediments impact water quality. There has been an increasing concern regarding fish health in the St. Lucie Estuary, which is related to increased inputs of nutrients and metals in recent decades. To investigate vertical changes of contaminants (P, Cd, Cr, Co, Cu, Ni, Pb, Zn, and Mn) in sediments of the St. Lucie Estuary in South Florida, 117 layer samples from six of the 210 to 420 cm depth cores were analyzed for their total and water-soluble P and heavy metals, clay, total Fe, Al, K, Ca, Mg, Na, and pH. Principal component analysis (PCA) was used in two sets of analytical data (total and water-soluble contaminant concentrations) to document changes of contaminants in each core of sediments. The PCA of total contaminants and minerals resulted in two factors (principal components). The first and second factors accounted for 61.7 and 17.2 % of the total variation in all variables, and contrast indicators associated with contaminants of P, Cd, Co, Cr, Ni, Pb, Zn, and Mn and accumulation of Fe and Al oxides, respectively. The first factor could be used for overall assessment of P and heavy metal contamination, and was higher in the upper 45–90 cm than the lower depths of each core. The concentrations of P and heavy metals in the surface layers of sediments significantly increased, as compared with those in the sediments deeper than 45–90 cm. The PCA of water-soluble contaminants developed two factors. The second factor (Cu–P) was higher in the upper than the lower depths of the sediment, whereas the highest score of the first factor (Cd–Co–Cr–Ni–Pb–Zn–Mn) occurred below 100 cm. The water-soluble Cu and P concentrations were mainly dependent on their total concentrations in the sediments, whereas the water-soluble Cd, Co, Cr, Ni, Pb, Zn, and Mn concentrations were mainly controlled by pH.     

Biostratigraphy,sedimentology and sequence stratigraphy of the Tournaisian–Viséan transitional strata in South China (Guangxi)

The biostratigraphy and sedimentological evolution of the Tournaisian–Viséan (T–V) transitional strata in South China (Guangxi) have been investigated. The sediments were deposited on a carbonate platform and in slope and basinal environments. In the T–V transitional strata, six foraminiferal associations have been distinguished which allow correlation between the shallow and deep water deposits. A careful examination of the evolutionary stages of the foraminifer Eoparastaffella provides a more accurate criterion for the definition of the T–V boundary, but does not significantly modify the historical one. The distinction of two morphotypes is based on the elevation of the last whorl and the peripheral outline. Tournaisian specimens of Eoparastaffella have a well rounded periphery (morphotype 1) contrasting with the subangular periphery of younger Viséan specimens (morphotype 2). A coefficient can be deduced from simple biometric measurements for more precisely defining the T–V boundary. The sequence stratigraphy of the T–V strata in South China has been reconstructed by combining biostratigraphical and sedimentological data. It allowed the correlation of the T–V transitional strata between the platform area and the slope and basinal locations. Late Tournaisian strata were deposited during a highstand systems tract. Near the end of the Tournaisian, a major drop in relative sea-level led to the development of an unconformity in the platform area. Lowstand deposits formed during latest Tournaisian time in the basin where a detailed biostratigraphic framework has been devised. Sediments deposited during the ensuing transgressive systems tract overlie the late Tournaisian highstand sediments in the platform area and the latest Tournaisian lowstand deposits in the basin. A major drop in relative sea-level near the end of the Tournaisian has been recognized worldwide. Therefore, the possibility of using the sequence stratigraphy of the T–V strata in South China for worldwide correlations should be investigated. © 1997 John Wiley & Sons, Ltd.     

河南省飞机人工增雨试验方案设计

借鉴国内外已有的探测和分析研究成果，结合国内人工增雨飞机的性能，着重介绍在催化作业和探测时，开展等半径盘旋上升（或下降）垂直观测，和在特定高度上进行水平观测的方案设计及其资料收集、处理、存档的流程。为开展人工增雨作业、观测提供科学依据。     

高分辨率机载SAR影像判读实验

近年来机载SAR系统在国内得到快速发展。由于SAR系统具有不同于光学传感器的成像机理,因而可以提供全新的数据获取手段和不同的地物信息。利用高分辨率机载SAR影像进行解译时必须熟悉其成像机理和图像信息特点,充分了解SAR图像解译标志的特点和各类地物的解译规律。本文以高分辨率机载SAR数据为基础,对比光学影像,从SAR成像特点和地物散射特性出发,对SAR影像进行了目视解译,分析了SAR影像在地形地物要素识别中的应用潜力。     

青藏高原西北缘盆山过渡带陡坡地貌的形成时代与成因

平均海拔大于4500 m的青藏高原,是通过高原边缘的陡坡地貌与海拔低于1500 m的周缘盆地或平原相连接的,这些围绕高原的陡坡地貌是何时、如何形成的呢？本文通过对西昆仑山中段北缘主逆冲断层上盘陡坡地貌区9件磷灰石样品的裂变径迹年龄与长度分析表明：在海拔3900～4635 m的陡坡地貌中的裂变径迹样品年龄为6.2±1.4 Ma～0.9±0.3 Ma,呈现“上新下老”的反序分布特征; 而通过热历史模拟显示约5 Ma,约3～2 Ma,约2～1 Ma 和约1 Ma该地区出现多阶段的隆升与剥露。结合前人研究成果和野外地质的观察认为,现今青藏高原西北缘陡坡地貌的形成是中新世晚期以来高原边界叠瓦状断裂系经历了约8 Ma、约5 Ma、约3～2 Ma、约2～1 Ma和约1 Ma多阶段后展式逆冲运动的结果,这为青藏高原周缘陡坡地貌的形成和青藏高原的隆升时代与型式提供了关键的热年代学约束。     

Correlation between molecular absorption spectral slope ratios and fluorescence humification indices in characterizing CDOM

Ultraviolet–visible absorption spectral slope ratios S_R (slope in 275–295 nm divided by slope in 350–400 nm) and humification index (HIX, integrated fluorescence emission in 435–480 nm divided by that in 435–480 and 300–345 nm) were compared when characterizing chromophoric dissolved organic matter (CDOM) in three humic acids and 44 whole water samples. HIX increased with increasing pH for humic acids, while their S_R showed much more complicated dependencies on pH. There was a negative correlation between S_R and HIX. S_R increased in the order terrestrial coal/peat < terrestrial soil/river < seawater, while HIX increased in the order seawater < terrestrial soil/river < terrestrial coal/peat. The comparative study in this work indicates that terrestrially derived CDOM has higher HIX and lower S_R than marine CDOM. Investigators may potentially use these two indices to compare qualitatively the character of CDOM in different sources (e.g., terrestrial vs. marine).     

盐碱水NaCl浓度和碱度对银鲫(Carassius auratus gibelio)幼鱼毒性的初步研究

通过对银鲫(Carassiusauratusgibelio)幼鱼(L=3.56±0.28cm)的NaCl浓度(pH=8.80±0.10)及碱度(pH=8.84±0.26)的急性毒性试验，用概率单位法求得其24，48，96h的半致死浓度(LC50值)NaCl浓度分别为11.53、10.77、8.58g/L；碱度分别为98.74、79.49、64.19mmol/L。在此基础上采用水生毒理联合效应相加指数法进行了氯化钠与碳酸氢钠浓度的联合毒性实验(浓度=11)，结果在96h内二者的关系全部为协同作用,且其协同性逐渐减弱并趋向于相加作用。