Comparison of arsenic concentrations in simultaneously-collected groundwater and aquifer particles from Bangladesh,India, Vietnam,and Nepal

One of the reasons the processes resulting in As release to groundwater in southern Asia remain poorly understood is the high degree of spatial variability of physical and chemical properties in shallow aquifers. In an attempt to overcome this difficulty, a simple device that collects groundwater and sediment as a slurry from precisely the same interval was developed in Bangladesh. Recently published results from Bangladesh and India relying on the needle-sampler are augmented here with new data from 37 intervals of grey aquifer material of likely Holocene age in Vietnam and Nepal. A total of 145 samples of filtered groundwater ranging in depth from 3 to 36 m that were analyzed for As (1–1000 μg/L), Fe (0.01–40 mg/L), Mn (0.2–4 mg/L) and S (0.04–14 mg/L) are compared. The P-extractable (0.01–36 mg/kg) and HCl-extractable As (0.04–36 mg/kg) content of the particulate phase was determined in the same suite of samples, in addition to Fe(II)/Fe ratios (0.2–1.0) in the acid-leachable fraction of the particulate phase. Needle-sampler data from Bangladesh indicated a relationship between dissolved As in groundwater and P-extractable As in the particulate phase that was interpreted as an indication of adsorptive equilibrium, under sufficiently reducing conditions, across 3 orders of magnitude in concentrations according to a distribution coefficient of 4 mL/g. The more recent observations from India, Vietnam and Nepal show groundwater As concentrations that are often an order of magnitude lower at a given level of P-extractable As compared to Bangladesh, even if only the subset of particularly reducing intervals characterized by leachable Fe(II)/Fe >0.5 and dissolved Fe >0.2 mg/L are considered. Without attempting to explain why As appears to be particularly mobile in reducing aquifers of Bangladesh compared to the other regions, the consequences of increasing the distribution coefficient for As between the particulate and dissolved phase to 40 mL/g for the flushing of shallow aquifers of their initial As content are explored.     

Geochronology of Pliocene volcanism in the Dzhavakheti Highland (the Lesser Caucasus). Part 1: Western part of the Dzhavakheti Highland

Isotopic-geochronological study of the Pliocene magmatic activity in western part of the Dzhavakheti Highland (northwestern region of the Lesser Caucasus) is carried out. The results obtained imply that the Pliocene magmatic activity lasted in this part of the highland approximately 2 million years from 3.75 to 1.75–1.55 Ma. As is established, the studied volcanic rocks correspond in composition mostly to K-Na subalkaline and more abundant normal basalts. Time constraints of main phases in development of basic volcanism within the study region are figured out. We assume that individual pulses of silicic to moderately silicic volcanism presumably took place in the Dzhavakheti Highland about 3.2 and 2.5 Ma ago.     

Comparative analyses of East Texas forest cover maps generated from Landsat and AVHRR data

Comparing satellite data derived map products are affected by differences in data characteristics, image acquisition dates, processing techniques, and classification schemes used for assigning pixels to a thematic class. By comparing two forest maps generated from Landsat Enhanced Thematic Mapper Plus (ETM+) and Advanced Very High Resolution Radiometer (AVHRR) images acquired on the same day, and processed using identical classification scheme and methods these differences were minimized. The ETM+ derived map had higher classification accuracy values and more precise area estimates than the AVHRR derived map. In the ETM+ derived map, 87 of the 599 verification data were misclassified, whereas in the AVHRR derived map, 155 of the 469 verification data were misclassified. Detailed error analyses by land cover class revealed that a land use based definition of forest accounted for 74% (64 out of 87) and 57% (89 out of 155) of the classification errors in ETM+ and AVHRR derived maps, respectively.     

Numerical estimation of REV and permeability tensor for fractured rock masses by composite element method

The Monte Carlo method is used to generate parent stochastic discrete fracture network, from which a series of fractured rock samples of different sizes and orientations are extracted. The fracture network combined with a regular grid forms composite element mesh of the fractured rock sample, in which each composite element is composed of sub‐elements incised by fracture segments. The composite element method (CEM) for the seepage is implemented to obtain the nodal hydraulic potential as well as the seepage flow rates through the fractured rock samples. The application of CEM enables a large quantity of stochastic tests for the fractured rock samples because the pre‐process is facilitated greatly. By changing the sizes and orientations of the samples, the analysis of the seepage characteristics is realized to evaluate the variation of the permeability components, the existence of the permeability tensor and the representative element volume. The feasibility and effectiveness are illustrated in a numerical example. Copyright © 2008 John Wiley & Sons, Ltd.     

A combined numerical tidal model for the Hangzhou Bay and Qiantang River

-In order to avoid prescribing open boundary condition on the upstream side of the Hangzhou Bay, in numerical simulation of the tides and residual currents of the Bay, a 1-D model for the Qiantang River is connected to the 2-D model for the Hangzhou Bay. The harmonic constants of diurnal constituent [ (K1 O1)/2],semidiurnal constituent (M2) and shallow water constituent (M4) are obtained. The results produced by the combined model are in better agreement with the observed ones than those produced solely by the original 2-D model. The combined model gives much more reliable results for tide-induced residual water level and current.     

Thickening of the oceanic layer in the Pacific Ocean

A statistical analysis of published seismic refraction results in the Pacific Ocean confirms the existence of a progressive thickening of the oceanic layer with age, following an inverse exponential law. There is no strong indication in the Pacific data of an increase in the thickness of layer 2 with decreasing spreading rate.Contribution No. 93 of the Département Scientifique of the Centre Océanologique de Bretagne, B.P. 337, 29200, Brest, France.     

黄海的风、潮混合特征及其对冷水团边界的影响

本文第一作者早在1985年就提出,潮混合效应控制着夏季黄海冷水团的边界及海面冷水分布(赵保仁,1985)。1987年又进一步通过水文调査资料和卫星图片给出了黄海周围的浅水陆架锋(或称潮汐锋)的分布及强锋区的跨锋断面中的温度、盐度和坏流结构特征,并指出夏季的黄海沿岸流在性质上属沿锋面运动的强流(赵保仁,1987a,b),而后又对黄海西部的陆架锋进行了一次专门调査(赵保仁等,1991)。此外,他还指出黄海的强温跃层的形成和转移现象也与潮混合现象密切相关(赵保仁,1989)。因此,研究潮混合现象对阐明发生在黄海的多水文物理现象都是至关重要的。 为深入了解黄海的潮混合特征,作者把渤海、黄海和东海作为一个整体完成了一次精度较高的潮汐、溯流数值计算,在潮汐、潮流的分布方面,揭示了前人尚未阐明的一些特征。本文根据这些数值结果,计算了近最大潮流流速和层化参数,阐明了渤海、黄海和东海的潮混合特征及其对降温期黄海冷水团分布变化的影响。此外,还用 Sim pson等人(1981)的能量模式计算了南黄海西部的风、潮混合效率。     

Dynamic Response Analysis of Interaction System of R.C. Gravity Single-Leg Platform

In this paper, the responses of the interaction system of R.C. gravity single-leg platform to seismic excitation are mainly analysed. A set of nonlinear equations for the interaction system are established by using the wave, one is the soil-structure interaction and the other is the fluid-structure interaction. The seismic response of the interaction system is analysed for the influence of the asymmetric structure, fluid action, etc. with the input of seismic SH waves in any direction. The numerical results are given for a simple example.