Hydrogeochemistry of fluoride in the Quequen river basin: natural pollutants distribution in the argentine pampa

Fluoride pollution is a widespread problem in Argentina, as it is in many areas of the World. Former investigations have demonstrated that the dissolution of volcanic glass disseminated in the loess-like sediments is the main source of fluoride in the Argentine pampas. Nevertheless, fluoride distribution is erratic and the factors controlling it are not yet well-known. A large amount of hydrochemical data collected in the Quequen Grande river catchment is used in order to contribute to the understanding of fluoride distribution and mobility in groundwater in the Argentine pampas. The Quequen Grande river catchment is 10,000 km². It extends between two low hills ranges of Precambrian metamorphic rocks and sedimentary Paleozoic rocks, filled by a thick sequence of Cenozoic sediments, mainly silts and silt-clayed, with sand layers. These sediments form a multilayer phreatic aquifer, which is recharged from precipitation infiltration, discharging through streams directly into the sea. Fluoride concentration in surface water (n = 353) ranges between 0 and 6.5 mg/l, with an average value of 2.14 mg/l. Groundwater concentration (n = 135) is from 0 up to 5.7 mg/l, with an average of 1.84 mg/l. Considering the statistic distribution of fluoride, two groups of samples can be determined. A dominant group between 0 and 3 mg/l, with a mean value around 1.5 mg/l, corresponding to samples widely distributed in the catchment; and a second one group with fluoride contents between 3 and 6 mg/l, corresponding to a smaller area in the central-west border. Two different sources are proposed. Volcanic glass dissolution is responsible for dominant values in the catchment, while the weathering of biotite from the Paleozoic bedrock can be assumed to account for the higher concentrations in the second group.     

An efficient technique for pre-selecting low-redshift damped Lyα systems

The number of z ∼ 1 damped Lyα systems (DLAs, log  N (H  i ) ≥ 20.3) per unit redshift is approximately 0.1, making them relatively rare objects. Large, blind QSO surveys for low-redshift DLAs are therefore an expensive prospect for space-borne ultraviolet telescopes. Increasing the efficiency of these surveys by pre-selecting DLA candidates based on the equivalent widths (EWs) of metal absorption lines has previously been a successful strategy. However, the success rate of DLA identification is still only ∼35 per cent when simple EW cut-offs are applied, the majority of systems having 19.0 < log  N (H  i ) < 20.3. Here, we propose a new way to pre-select DLA candidates. Our technique requires high-to-moderate-resolution spectroscopy of the Mg  ii λ2796 transition, which is easily accessible from the ground for 0.2 ≲ z ≲ 2.4. We define the D -index, the ratio of the line equivalent width to velocity spread, and measure this quantity for 19 DLAs and eight sub-DLAs in archival spectra obtained with echelle spectrographs. For the majority of absorbers, there is a clear distinction between the D -index of DLAs compared with sub-DLAs (Kolmogorov–Smirnov probability = 0.8 per cent). Based on this pilot data sample, we find that the D -index can select DLAs with a success rate of up to 90 per cent, an increase in selection efficiency by a factor of 2.5 compared with a simple EW cut. We test the applicability of the D -index at lower resolution and find that it remains a good discriminant of DLAs for full width at half-maximum (FWHM) ≲ 1.5 Å. However, the recommended D -index cut-off between DLAs and sub-DLAs decreases with poorer resolution and we tabulate the appropriate D -index values that should be used with spectra of different resolutions.     

Artificial ground motion compatible with specified ground shaking peaks and target response spectrum

1 Introduction Time history analysis is usually needed not only for the seismic design of important structures, such as nuclear plants, large concrete dams and super high-rise buildings, but also for seismic performance based design. Performance-based design requires tha knowledge of the entire process of nonlinear seismic responses of structures be obtained, which depends on the ground motion time history as input for this analysis. However, because the observed strong-motion recordings are l…     

Two contrasting petrotectonic domains in the Kokchetav megamélange (north Kazakhstan): Difference in exhumation mechanisms of ultrahigh‐pressure crustal rocks,or a result of subsequent deformation?

Abstract In northern Kazakhstan the WNW striking Kokchetav megamélange includes different crustal sequences with high‐pressure/ultrahigh‐pressure (HP/UHP) remnants of their 540–520 Ma subduction metamorphism. Two domains separated by the north‐east trending Chaglinka fault are distinguished. The western domain exhibits NE–SW structures within a single Kumdy–Kol megaunit of diamond‐bearing UHP metasediments and high‐temperature (HT) eclogites. The eastern domain consists of the composite Kulet megaunit with the Kulet UHP unit (coesite‐bearing metasediments, whiteschists and eclogites), the Enbek–Berlyk medium‐pressure (MP) unit (kyanite‐bearing, high‐alumina rocks with interleaved coronitic metagabbro), and ortho‐ and paragneisses with eclogites and amphibolites included. All eclogites in the eastern domain are of the relatively low temperature (LT) type. Sillimanite is common and appears after kyanite in the sheared MP unit. A regional and moderately ESE plunging linear fabric coincides with the fold‐axis of the foliation poles from the eastern domain. Whether this also reflects a regional top to the WNW transport, as inferred from the dextral strike‐slip on steeply to SSW dipping foliation, needs further study. Top to the WNW shear is shown by weakly inclined low pressure (LP) cordierite rocks that flank the eastern domain in the south. Some new ³⁹Ar/⁴⁰Ar mica cooling ages (519, 521 Ma) from the Kulet UHP micaschists reflect the same early stage evolutionary event as was previously shown for the Kumdy–Kol UHP rocks (515, 517 Ma) in the west. Similar ³⁹Ar/⁴⁰Ar ages (500, 517 Ma) are recorded by micas and amphibole that outline a top to NNW shear fabric in the non‐subducted Proterozoic basement, north of the megamélange. A 447 Ma overprint of the MP sequences is considered to reflect the strike‐slip deformation with sillimanite and the reworking of an early kyanite‐bearing tectonite. Biotites from the LP cordierite rocks yielded approximately 400 Ma ³⁹Ar/⁴⁰Ar ages. In case they reflect the WNW shear deformation, the latter is considered to be associated with a regional granite magmatism (420–460 Ma) extending south of the eastern domain. In their present different structural domains the Kulet and Kumdy–Kol UHP units display a similar early stage event. Subsequent LP deformation, which is likely to be associated with regional granite magmatism (420–460 Ma), is assumed to have obliterated any common or uniform early exhumation structure for the whole megamélange. The north‐east structured Kumdy–Kol domain is assumed to have preserved the most information about the early stage exhumation. This domain is at an angle to the regional WNW strike of the megamélange.