Permian coal measure sandstone fissure water (referred to as “coal measure water,” that is, water in coal measures) is one of the important water sources for industrial and agricultural activities in mining areas. However, the regional high-pressure grouting, one of the most widely used floor control methods, may affect the coal measure water which is connected with limestone aquifer. This study used Taoyuan mine, a typical coal mine in Huaibei coalfield, as the research area to study the influencing mechanism of a grouting treatment on the hydrogeochemical evolution of coal measure water. The hydrogeochemical characteristics and water-rock interaction mechanism of the coal measure water before and during the treatment were evaluated using a Piper trigram, ion combination ratio, and hydrogen-oxygen stable isotope. The anions and cations in the coal measure water before and during the treatment had the same trends at SO42− > HCO3− > Cl− and Na+ > Ca2+ > Mg2+, respectively. Hydrochemical types of coal measure water before treatment were mainly SO4·Cl-Ca·Mg, SO4·Cl-Na, and HCO3-Na, and during treatment they were mainly SO4·Cl-Na and HCO3-Na. The formation of chemical components of coal measure water before treatment was mainly caused by carbonate dissolution, sulfate dissolution, and pyrite oxidation. During the treatment, sulfate dissolution and pyrite oxidation were the main geochemical processes, and ion exchange was enhanced. Atmospheric precipitation was the source of all water samples, and all showed an obvious 18O drift. 相似文献
A reasonable and quantitative result on the variation of polar wobble excited by the oceans is not available at present. Numerous researches have shown that atmospheric motion is the greatest excitation source for the seasonal variations in the polar wobble and that oceanic motion is one of the main remaining excitation sources. The excitation of variation in the annual polar wobble caused by oceans from 1992 to 2004 both globally and in latitude dependence, have been studied in depth by means of the new generation of SODA oceanic data assimilation (SODA-1.4.2 and SODA-1.4.3) and the ECCO oceanic data assimilation. The result shows that the variation in the seasonal polar wobble excited by the SODA oceans is very close to that of the residual after the action of the atmosphere and land water is deducted from the geodesic excitation function for a large part of the investigated time interval, and that there is overall agreement between the two as regards the annual amplitude and phase. In addition, in comparison with the result of early SODA-Bata 7, the new generation of SODA oceanic excitation has achieved obvious improvements. The latitude distributions of the excitations of the annual polar wobble by the SODA and ECCO oceans are consistent in the Greenwich direction, while having obvious differences in the direction of 90° E. 相似文献
On the basis of detailed geological studies of the Wulong gold deposit, three metallogenic stages can be identified. With quartz fluid inclusions as an object of study, the authors investigated phase characteristics, compositional variations, temperature and pressure changes, fluid evolution, Pb isotope tracing and Rb-Sr isotopic dating of fluid inclusions entrapped in the above three metallogenic stages. The results show that Na+ is decreased obviously with metallogenic evolution, while K+ and other cations and gas compositions (H2, CO, CH4 and CO2) are increased slightly, and that the temperature and salinity vary in a pulsating manner along with the metallogenic evolution. Inverse calculation of hydrogen and oxygen isotopes indicate that at the first metallogenic stage the fluids were magmatic water, at the second stage they were dominated by magmatic water with a minor amount of meteoric water involved, and at the third stage, i.e., the final stage of metallogenesis, the fluids were composed complete 相似文献
Sulfur oxides (SOX) emissions embodied in trade (SEET) may play an important role in affecting national responsibilities toward pollutant emission reduction within the context of global greenhouse gas emission policy. This paper analyzes the change of the SEET associated with energy consumption from the perspective of a country and a sector between 1995 and 2011, exploring the evolution characteristic of the sources and flows of the SEET for 39 countries, as well as measuring the production-based and consumption-based global SOX emissions’ inventory and investigating the impact of international trade on the allocation of national pollutant emissions’ reduction obligations. One important finding is that the volume of SOX emissions embodied in global trade increased dramatically from 1995 to 2011, and the global SOX emissions stemming from anthropogenic energy consumption are mostly from China and the USA. Another important finding is that, referring to specific sectors, whether seen from the total SEET or from the sources of SEET or from the total SOX emissions occurring from economic consumption and production, energy sectors, like electricity, gas, and water supply and coke, refined petroleum, and nuclear fuel, are the main contributors to the increase in the global SOX emissions. Notably, however, our results show that the sector of agriculture, hunting, forestry, and fishing should be allocated more SOX emission reduction responsibilities under a consumption-based emissions’ accounting inventory.