综合评价方法在水质评价应用中的比较研究

以黄河某取水口监测点19981999年的水质为评价对象,利用灰色关联分析法、模糊综合评价法和物元分析法分别进行了综合评价,结果表明,模糊综合评价和物元分析法的评价结果一致,"中心化"灰色关联法评价结果与上述两方法的评价结果一致.     

中国北方磷矿矿床类型及成矿规律

通过对中国北方内生磷灰石、变质及沉积型磷矿成矿特征及典型矿床的研究,建立了各种类型磷矿床的成矿模式和找矿模型、确定了各类型矿床的时空分布规律以及矿床的共生规律,为开展磷矿的找矿工作具有重要参考价值。     

中国北方磷矿成矿预测

在中朝准地台、塔里木准地台边缘深断裂附近和台中隆起带以及天山-兴安、祁连-秦岭、额尔古纳几个地槽褶皱区的中间地带,不同程度地具备中国北方三种主要类型磷矿的成矿条件。研究分析认为中国北方的内生磷矿具有良好的找矿前景,绿岩带型磷矿和古元古代沉积变质磷矿显示一定的找矿潜力,沉积型磷矿一般品位低、规模小。通过归纳,在中国北方划分出磷矿的二级城矿区4个、三级成矿带15个、四级成矿亚带19个。圈定成矿预测区A级2个,B级C级各23个。确定了21处可开展进一步工作的地区。     

Paleoenvironmental implications of the guano phosphatic cementation on Dongdao Island in the South China Sea

The phosphatic cement in the bioclastic sediment sequence on the northeastern shore of Dongdao Island in the South China Sea was studied and its paleoenvironmental implications discussed. Petrological characteristics and major, trace, REE element data unequivocally supported the notion that phosphatization was closely associated with avian guano decomposition and leaching, whereas carbon and oxygen isotope results further revealed that meteoric water were involved in these processes. AMS ¹⁴C dates on the brown phosphate cements indicate that they were formed around 5700, 5000–5100 and 2900 yr BP, respectively. The multi-episodes of phosphatization very likely correspond to intermittent seabird occupation on this island — possibly reflecting Holocene sea-level oscillation and/or long term climate changes in the South China Sea that have controlled seabird habitat. The phosphate cementation, which occurs widely in tropical islands, may be another useful monitor for sea-level and/or paleoclimate changes.     

Nonlinear influences on ocean waves observed by X-band radar

The purpose of this study is to discuss the influence of signal nonlinearity upon X-band radar observations. A method for estimating the degree of nonlinearity by bispectral analysis was applied and discussed. We found that bispectral analyses from spatial radar backscatter series are similar to results obtained from water level time series. In addition, the average nonlinear degree from radar backscatter is related to wind speed. The accuracy of wave observations derived by consideration of the nonlinear effect from radar backscatter was also investigated. The estimated error in wave height from the radar data is also related to the degree of nonlinearity. In order to improve accuracy, the modulation transfer function method was applied in order to eliminate the influence of nonlinearity.     

Interaction of linear waves with an array of infinitely long horizontal circular cylinders in a two-layer fluid of infinite depth

The linear water wave scattering and radiation by an array of infinitely long horizontal circular cylinders in a two-layer fluid of infinite depth is investigated by use of the multipole expansion method. The diffracted and radiated potentials are expressed as a linear combination of infinite multipoles placed at the centre of each cylinder with unknown coefficients to be determined by the cylinder boundary conditions. Analytical expressions for wave forces, hydrodynamic coefficients, reflection and transmission coefficients and energies are derived. Comparisons are made between the present analytical results and those obtained by the boundary element method, and some examples are presented to illustrate the hydrodynamic behavior of multiple horizontal circular cylinders in a two-layer fluid. It is found that for two submerged circular cylinders the influence of the fluid density ratio on internal-mode wave forces is more appreciable than surface-mode wave forces, and the periodic oscillations of hydrodynamic results occur with the increase of the distance between two cylinders; for four submerged circular cylinders the influence of adding two cylinders on the wave forces of the former cylinders is small in low and high wave frequencies, but the influence is appreciable in intermediate wave frequencies.     

Analysis of second-order resonance in wave interactions with floating bodies through a finite-element method

A time-domain method is employed to analyse the resonant oscillations of the liquid confined within the two floating bodies. The velocity potentials at each time step are obtained through a finite-element method (FEM) with quadratic shape functions. The matrix equation of the FEM is solved through an iteration. The radiation condition is satisfied through a combination of the damping zone method and the Sommerfeld–Orlanski equation. A detailed analysis is made for two rectangular floating cylinders undergoing forced oscillation. The first-order potential reveals the resonant behaviour of the wave motion at certain frequencies ω_i, which is similar to sloshing in a tank. More interestingly, the second-order theory further reveals that when the oscillation frequency is at ω_i/2 or half of the resonant frequency, no first-order resonance is observed as expected, but the second-order resonant motion becomes evident, which does not seem to have been extensively investigated so far. Detailed results for two rectangular cylinders are provided to show some insights into the resonant effect due to the interaction between the bodies. The first- and second-order resonant phenomena have been observed and the result has shown that the second-order components have significant influence on the wave and force in some cases, especially at the second-order resonance.     

Dissolved inorganic carbon (DIC) and its carbon isotopic composition in sediment pore waters from the Shenhu area,northern South China Sea

The Shenhu area is one of the most favorable places for the occurrence of gas hydrates in the northern continental slope of the South China Sea. Pore water samples were collected in two piston cores (SH-A and SH-B) from this area, and the concentrations of sulfate and dissolved inorganic carbon (DIC) and its carbon isotopic composition were measured. The data revealed large DIC variations and very negative δ ¹³C-DIC values. Two reaction zones, 0–3 mbsf and below 3 mbsf, are identified in the sediment system. At site SH-A, the upper zone (0–3 mbsf) shows relatively constant sulfate and DIC concentrations and δ ¹³C-DIC values, possibly due to bioturbation and fluid advection. The lower zone (below 3 mbsf) displays good linear gradients for sulfate and DIC concentrations, and δ ¹³C-DIC values. At site SH-B, both zones show linear gradients, but the decreasing gradients for δ ¹³C-DIC and SO₄ ²⁻ in the lower zone below 3 mbsf are greater than those from the upper zone, 0–3 mbsf. The calculated sulfate-methane interface (SMI) depths of the two cores are 10.0 m and 11.1 m, respectively. The depth profiles of both DIC and δ ¹³C-DIC showed similar characteristics as those in other gas hydrate locations in the world oceans, such as the Blake Ridge. Overall, our results indicate an anaerobic methane oxidation (AMO) process in the sediments with large methane flux from depth in the studied area, which might be linked to the formation of gas hydrates in this area.     

Geochemistry of pore waters from the Xisha Trough, northern South China Sea and their implications for gas hydrates

This paper reports all available geochemical data on sediments and pore waters from the Xisha Trough on the northern continental margin of the South China Sea. The methane concentrations in marine sediments display a downhole increasing trend and their carbon isotopic compositions (δ ¹³C = −25 to −51‰) indicate a thermogenic origin. Pore water Cl⁻ concentrations show a range from 537 to 730 mM, and the high Cl⁻ samples also have higher concentrations of Br⁻, Na⁺, K⁺, and Mg²⁺, implying mixing between normal seawater and brine in the basin. The SO₄ ²⁻ concentrations of pore waters vary from 19.9 to 36.8 mM, and show a downhole decreasing trend. Calculated SMI (sulfate-methane interfaces) depths and sulfate gradients are between 21 and 47 mbsf, and between −0.7 and −1.7 mM/m, respectively, which are similar to values in gas hydrate locations worldwide and suggest a high methane flux in the basin. Overall, the geochemical data, together with geological and geophysical evidence, such as the high sedimentation rates, high organic carbon contents, thick sediment piles, salt and mud diapirs, active faulting, abundant thermogenic gases, and occurrence of huge bottom simulating reflector (BSR), are suggestive of a favorable condition for occurrence of gas hydrates in this region.     

海底孔内水合物观测系统与钻井实施

通过耦合布设海底表面和孔内水合物观测系统获取物理、化学、微生物等数据是了解掌握海洋水合物环境动态变化、碳循环规律和资源开发技术的有效手段,据此初步提出了一套海底孔内水合物观测系统,并指出了系统的关键技术难点。而在钻井布设该孔内观测系统时,要注意防止井内安全事故的发生,充分评估安放位置处含水合物地层的地质力学稳定性并采取适当的钻井和完井方式稳定或强化含水合物地层以支撑孔内观察仪器,实现孔内长期监测。最后讨论了在我国南海实施孔内水合物观测系统的必要性,并提出了初步想法。