ELNES spectroscopy of mixed Si coordination minerals

 Si K- and L-edge ELNES spectroscopy and multiple-scattering (MS) calculations are used to examine mixed Si coordination compounds varying in Si^VI:Si^IV ratio. As in previous studies, the edges are influenced mainly by silicon coordination (tetrahedral vs. octahedral), as supported by the MS calculations. We demonstrate two methods semi-quantitatively to extract the value of Si^VI/(Si^VI+Si^IV): (1) A linear relationship between the L_2,3-L₁ splitting and Si^VI/(Si^VI+Si^IV) is observed, (2) a fitting method based on the coaddition of reference tetrahedral and octahedral Si spectra is applied to both Si K- and L-edge ELNES spectra. Received: February 10, 1997 / Revised, accepted: May 23, 1997     

The local structure of Ca-Na pyroxenes. I. XANES study at the Na K-edge

 X-ray absorption Na K-edge spectra have been recorded on synthetic endmember jadeite and on a series of natural Ca-Na pyroxenes compositionally straddling the Jd-Di join. The C2/c members of the series are systematically different from the P2/n members. Differences can be interpreted and explained by comparing the experimental spectra with theoretical spectra. These have been calculated by the multiple-scattering formalism from the atomic positional parameters determined by single-crystal X-ray diffraction structure refinement on the same samples. In the full multiple scattering region of the spectra (1075 to 1090 eV) C-pyroxenes exhibit three features which reflect the 6-2 configuration of the O back-scattering atoms around the Na absorber located at the center of the cluster (site M2 of the jadeite structure). P-pyroxenes show more complicated spectra in which at least four (possibly five) features can be recognized; they reflect the two types of configuration (6-2 and 4-2-2) of O around Na in the two independent M2 and M21 eight-fold coordinated sites of the omphacite structure. A weak, sometimes poorly resolved peak at 1079 eV is diagnostic and discriminates C- from P-pyroxenes. The Garnet Ridge C2/c impure jadeite exhibits a spectrum which is intermediate between those of jadeite and omphacite. The Hedin-Lundqvist potential proves best for these insulating materials and allows multiple-scattering calculations agreeing well with experiments. Received: July 11, 1996/Revised, accepted: October 21, 1996     

柱撑蒙脱石制备与表征

本文采用多种方法制备keggin离子，并探索出制备稳定keggin离子的适宜酸碱度，用此柱化剂制备出层间距为2．4～2．5nm的柱撑蒙脱石。应用X射线走向衍射技术、红外光谱、差热分析对往撑蒙脱石进行表征，用BET、吡啶吸附考察了其表面物理化学性质。结果表明，用Keggin离子制备出的柱撑蒙脱石其层间距在自然状态下为2．4～2．5nm，350C灼烧，层间距稳℃定在1．8nm，且具有耐热性能好、较大的比表面积和较强的Lewis酸位中心等特点．     

法国GUERET花岗岩内黑云母的结构特征研究

应用形态数学、图象分析及立体学原理，通过岩石薄片研究，对Gueret花岗岩内黑云母的结构特征进行了定量分析，揭示了黑云母矿物粒子在花岗岩中的密度、粒径、形状及空间分布的规律。根据岩石薄片上黑云母的灰度特征，应用直接成象方法获得其灰度图象，用自动阈值方法可用来提取黑云母粒子从而构成二值图象。借助MIPS图象分析系统，可以评价花岗岩薄片样本图象中所有黑云母粒子的参数，包括面积、周长等。花岗岩内黑云母矿物的密度、粒径 形状及空间分布的分析，揭示了其各向异性特征；同时，威布尔、正态及泊橙模型可分别用来描述黑云母矿物的粒径、形状及空间分布特征。     

生物礁岩分类方案

本文系统地提出了一个生物礁岩分类的新方案。生物礁岩首先根据次生组分的有无分为原生礁岩和次生礁岩。次生礁岩根据次生组分来源分为骨源次生礁岩和礁源次生礁岩。次生礁岩的二级分类根据次生组分的含量进行。骨源次生礁岩分为骨屑岩和含骨屑礁（灰）岩、倒骨央和含倒骨礁（灰）岩；礁源次生礁岩分为礁屑岩和含礁屑礁（灰）岩。骨屑岩根据次生组分的粒度分为巨骨砾（屑灰）岩、骨砾（屑灰）岩、细骨砾（屑灰）岩、骨砂（屑灰）岩；     

福建省东部及邻区岩浆活动的构造环境与热变质作用

研究区自加里东期运动以来，经历了复杂的构造－岩浆－热演化过程。在分析岩浆活动特征及其形成的构造环境的基础上，探讨了研究区沉积岩系及其中有机质的热变质作用。     

小应力变化触发大地震的研究

近年来,地震的孕育和发生是否可以用临界现象来模拟的问题引起地震学家的广泛关注.研究这个问题的方法之一是检验小应力变化是否确实触发大地震发生.这种检验必须具备两个条件:第一是作用在地震孕震断层上的小应力变化,第二是选择地震发生需要不同环境应力水平的地震.相同量级的小应力变化对于不同环境应力水平下发生地震的影响如果没有区别,则触发效应不存在;如果有明显差别,则触发效应存在.     

山西省主要河流流域面雨量预报业务流程

以T213、HLAFS模式、MM5中尺度模式输出的格点资料以及日本降水量格点资料为基础，将影响山西降水的天气动力模型归纳为诊断模型，从中引出多个能够全面反映降水模型特征的综合物理因子；根据各种数值模式输出的降水量预报性能和质量优劣特点，依据数值模式的形势场预报优于要素场预报的现实，构造在不同环流形势背景下，启动不同预报方程的面雨量预报业务流程，有效地遏止了在环流形势调整时预报输出不能快速响应的弱点，提高了点和面雨量预报的准确度。