Late Mesozoic Huangbeiling S-type granite in the East Qinling Orogen,China: Geochronology,petrogenesis and implications for tectonic evolution

S-type granites are typical features of collisional orogenic belts and could provide insights into the tectonic process associated with the final phase of orogeny. The East Qinling Orogen, one of significant segments in the Central China Orogen, witnessed complex tectonic evolution during the Late Mesozoic. The rare S-type granites in this orogen can be used as important proxies to understand the Late Mesozoic tectonic processes. Although a few previous studies suggested that the Huangbeiling pluton in the East Qinling Orogen might be S-type granite, detailed studies are lacking. Thus, we report the results from a systematic petrological, whole-rock geochemical and zircon U-Pb-Lu-Hf isotopic studies on the Huangbeiling pluton, with a view to constrain the timing of magmatism, petrogenetic evolution and genetic type, and to evaluate the implications for Late Mesozoic tectonic evolution of the East Qinling Orogen. Zircon U-Pb analysis yield ²⁰⁶Pb/²³⁸U spot ages in the range of 156.7–132.2 Ma, with weighted ²⁰⁶Pb/²³⁸U mean ages varying from 146.8 to 141.9 Ma, suggesting the Huangbeiling pluton formed during the Late Jurassic to Early Cretaceous. Zircon Lu-Hf isotopic data show negative εHf(t) values of ?21.5 to ?14.9 and two-stage Hf model ages of 2546–2131 Ma, which are correlated with the Neoarchean to Paleoproterozoic (3.0–2.1 Ga) meta-sedimentary rocks from nearby Taihua Group, indicating that the magma was sourced from reworked ancient crustal components involving meta-sedimentary rocks. Whole-rock geochemical data display enrichment of LREEs, Pb, Hf and Y as well as depletion in HREEs, Ba and HFSEs (e.g., Ta, P, Ti), with weakly negative Eu anomalies. The Huangbeiling granitoids are identified as S-type granites, which generated through partial melting of lower-middle crust and upper crustal fractional crystallization in syn-collisional settings. In conjunction with published information related to the tectonic evolution of the East Qinling Orogen, we propose that the Late Mesozoic Huangbeiling S-type granites might response to the complex tectonic evolution related to extensional tectonics induced by multi-directional (intra-continental) subductions from the Yangtze and North China Cratons as well as the Paleo-Pacific Plate during the Late Mesozoic.     

Relative role of sea surface temperature and snow on Indian summer monsoon seasonal simulation using a GCM

Indian summer monsoon is a global scale phenomenon controlled by different land, ocean, and atmospheric parameters. Sea surface temperature (SST) and snow are two of the major parameters, which may alter the spatial and temporal patterns of circulation and rainfall during Indian summer monsoon. In the current paper, we study the monsoon variability using long integrations (20 years) of the Indian Institute of Technology Delhi (IITD) Spectral model at T80L18 resolution with observed and climatological SST and snow. Study shows response of IITD GCM in simulating the Indian summer monsoon rainfall and circulation relative to the snow and SST as boundary conditions. The model’s response to SST and snow is examined by conducting four types of experiments by varying observed and climatological values of snow and SST. This paper discusses the seasonal total rainfall for country as a whole and 850 and 200 hPa wind for the period of 20 years starting from 1985 to 2004. The model has been integrated in the ensemble mode with five different initial conditions from the last week of April and first week of May. The model is able to capture the climatological patterns of seasonal total rainfall and averaged wind at lower and upper levels. Observed snow in the presence of climatological SST as a boundary condition shows much impact on rainfall and circulation than observed SST in the presence of climatological snow. Model performance is good in simulating the normal and excess monsoon conditions; it shows poor skill in capturing deficit monsoon years.     

Phytoremediation by benthic microalgae (BMA) and light emitting diode (LED) in eutrophic coastal sediments

Ocean Science Journal - In this study, we examined whether phytoremediation using benthic microalgae (BMA) and a light emitting diode (LED) can remediate eutrophic sediments caused by promoting the...     

A review of the National Groundwater Monitoring Network in Korea

The drastic expansion of cities and the rapid economic growth in Korea have caused dramatic increases to demand from groundwater supplies for drinking, domestic, agricultural and industrial water usage. The Ministry of Construction and Transportation and the Korea Water Resources Corporation have constructed and operated the National Groundwater Monitoring Network (NGMN) throughout the country since 1995. The NGMN, an official project establishing a total of 320 groundwater monitoring stations, was completed in 2005. Each national groundwater monitoring station serves as a baseline and primary station to monitor long‐term general trends in water‐level fluctuations and in groundwater quality. The present NGMN and its monitoring capabilities were evaluated to enhance the efficiency of groundwater monitoring and to meet the new societal conditions. Based on reviews and evaluations, some suggestions and recommendations are made with regard to improvements of the national network, including the installation of rainfall gauges in groundwater monitoring stations, gathering groundwater data every hour instead of every 6 h as at present, involving major cations and anions in the regular and periodic chemical analyses, regular periodic analyses of collected groundwater data, and construction of 199 additional groundwater monitoring stations to supplement the existing groundwater monitoring network. Copyright © 2006 John Wiley & Sons, Ltd.     

Climatic natural disasters,political risk,and international trade

This paper statistically analyzes the effects of climatic natural disasters and political risk on bilateral trade in a large-N sample of countries and years. Our theory suggests that the effects of these forces on trade need to be studied together and that the two forces may interact with one another. In the statistical analysis, the unit of analysis is a pair of countries and the model is based on the trade gravity design. The results show that the direct effects of increases in the incidence of disasters and the political risk level in the importer or the exporter countries are negative, reducing trade. The results for the interaction between the two forces show (1) as the incidence of disasters increases, the marginal effect of political risk on trade becomes more negative, which indicates a greater decline in trade and (2) as political risk declines the marginal effect of disasters becomes less negative, indicating a smaller decline in trade. Additional analyses demonstrate the robustness of these results to changes in model specification, disaster measure, and estimation method. In the bigger picture, our findings suggest that if climate change increases the incidence of climatic disasters as projections of the global science suggest, the growth of economic globalization may decline, ceteris paribus.     

Hydrogeochemistry of seepage water collected within the Youngcheon diversion tunnel,Korea: source and evolution of SO4‐rich groundwater in sedimentary terrain

In the Youngcheon Diversion Tunnel area, South Korea, 46 samples of tunnel seepage water (TSW) and borehole groundwater were collected from areas with sedimentary rocks (mainly sandstone and shale) and were examined for hydrogeochemical characteristics. The measured SO₄ concentrations range widely from 7·7 to 942·0 mg/l, and exceed the Korean Drinking Water Standard (200 mg/l) in about half the samples. The TDS (total dissolved solid) content generally is high (171–1461 mg/l) from more shale‐rich formations and also reflects varying degrees of water–rock interaction. The water is classified into three groups: Ca? SO₄ type (61% of the samples collected), Ca? SO₄? HCO₃ type (15%) and Ca? HCO₃ type (24%). The Ca? HCO₃ type water (mean concentrations=369 mg/l Ca, 148 mg/l HCO₃ and 23 mg/l SO₄) reflected the simple reaction between CO₂‐recharged water and calcite, whereas the more SO₄‐rich nature of Ca? SO₄ type water (mean concentrations=153 mg/l Ca, 66 mg/l HCO₃ and 416 mg/l SO₄) reflected the oxidation of pyrite in sedimentary rocks and fracture zones. Pyrite oxidation resulted in precipitation of amorphous iron hydroxide locally within the tunnel as well as in high concentrations of Ca (mean 153 mg/l) and Na (mean 49 mg/l) for TSW, and is associated with calcite dissolution resulting in pH buffering. The pyrite oxidation required for the formation of Ca? SO₄ type water was enhanced by the diffusion of oxygenated air through the fractures related to the tunnel's construction. The subsequent outgassing of CO₂ into the tunnel resulted in precipitation of iron‐bearing carbonate. Copyright © 2001 John Wiley & Sons, Ltd.     

Changes of biochemical properties and heavy metal bioavailability in soil treated with natural liming materials

This study evaluated the efficiency of naturally occurring lime-based waste materials (oyster shells, eggshells, and mussel shells) on immobilization of selected heavy metals (Cd and Pb) and a metalloid (As) in a contaminated agricultural soil. A 30-day incubation experiment was performed using soil mixture with natural liming materials or calcite (CaCO₃) at 0, 1, 3, 5, and 10 wt %. Soil biochemical properties including pH, electrical conductivity (EC), exchangeable cations, organic matter (OM), total nitrogen (TN), microbial populations, and enzyme activities were determined to ensure the changes in soil quality during incubation. The results showed that the application of natural liming materials led to an increase in soil pH similar to that of CaCO₃. Soil concentrations of Cd, Pb, and As extracted with 0.1 or 1 M HCl, and diethylene triamine pentacetic acid (DTPA) were decreased significantly after adding liming materials, accompanied by increased microbial population and enzyme activities of dehydrogenase, phosphatase, β-glucosidase, and arylsulfatase. Additionally, eggshells and mussel shells induced significant increases in OM and TN in the soil. Application of natural liming materials offers a cost-effective way to immobilize heavy metals and metalloids in soils.     

Determination of Trace Elements in Geological Reference Materials G‐3, GSP‐2 and SGD‐1a by Low‐Dilution Glass Bead Digestion and ICP‐MS

We present a revised alkali fusion method for the determination of trace elements in geological samples. Our procedure is based on simple acid digestion of powdered low‐dilution (flux : sample ≈ 2 : 1) glass beads where large sample dilution demanded by high total dissolved solids, a main drawback of conventional alkali fusion, could be circumvented. Three geological reference materials (G‐3 granite, GSP‐2 granodiorite and SGD‐1a gabbro) decomposed by this technique and routine tabletop acid digestion were analysed for thirty trace elements using a quadrupole ICP‐MS. Results by conventional acid digestion distinctly showed poor recoveries of Zr, Hf and rare earth elements due to incomplete dissolution of resistant minerals. On the other hand, results obtained by our method were in reasonable agreement with reference data for most analytes, indicating that refractory minerals were efficiently dissolved and volatile loss was insignificant.     

Finite size effects on the Poynting–Robertson effect: A fully general relativistic treatment

Even since the first discovery of Poynting and Robertson, the radiation source has been treated as merely a point. Even in a very few studies where the size of the source has been taken into account, the treatment of the problem remained largely non-relativistic. In the present work, we address the issue of the finite size effects on the Poynting–Robertson effect in a fully relativistic manner for the first time. As a result, the emergence and the characteristic of the critical point/suspension orbit can be studied in a systematic and detailed manner.