Knowledge based systems for risk assessment of the subsurface of contaminated sites

Computer-based risk evaluation methods are practical tools to compare automatically and evaluate contaminated sites. HYDRISK is an example of adequate knowledge-based systems: HYDRISK evaluates hydrogeological properties and chemical criteria relevant to contaminant transport with respect to the necessary remedial actions. It works at a high investigative level and enables geologists and engineers to draw differentiated conclusions for selecting remediation methods for the contaminated site. HYDRISK emphasizes space and time dependent aspects of the contaminant transport. It is supported by a geographic information system (GIS) to display the evaluation results. Some ideas on considering the spatiotemporal variability of relevant parameters by means of geostatistical methods and numerical models will be given.     

Infrared spectroscopy of Triassic conodonts: a new tool for assessing conodont diagenesis

The Fourier transform infrared spectra of individual conodonts with various CAI values indicate definite changes in conodont francolite during diagenesis. Steady decarbonation can be observed in the increasing intensity of the band with the wavenumber 2340 an^-1, which is assigned to trapped molecular CO₂. Carbon dioxide originates from decomposing CO^2-₃-ions occupying the B-site in francolite. Furthermore, the intensity of the water-deformation band at 1644 cm^-1 decreases with higher CAI values. These changes of intensity can be quantified by calculating the maximum extinction (E_max) for the corresponding absorption maxima and correlated with the CAI. Unaltered conodonts have a relative variable water 'content' and very little CO₂. Up to a CAI value of 4 conodont francolite continuously expells water and carbon dioxide is trapped. Conodonts with CAI = 5 have similar water 'contents' to CAI = 4 conodonts, but decarbonation continues to take place during this stage of diagenesis.     

Sequestration of a Biologically Labile Organic Carbon in Soils by Humified Organic Matter

In a long-term (one year) experiment, a sandy Podzol and a silty-loamy Loess soil were treated with labile (polysaccharides, AG) and stable (mature compost, CMP, and two humic acids from compost, HAC, and lignite, HAL) organic matter and the organic carbon (OC) lost by mineralization was periodically evaluated. The stable materials alone induced a significant reduction of OC losses in Podzol CMP <, HAL, <, HAC, Control), whereas the same treatments, except for CMP, produced an OC loss larger than control in Loess. This was attributed to the diverse textural and physical status of the two soils. The added stable organic matter became protected in the Podzol soil within the aggregates formed by the interaction with the coarse inorganic phase, while it was more easily decomposed in the Loess soils due to the strength of the native humic-clay complexes. In both soils, when the stable organic materials were mixed with polysaccharides (AG), the OC losses from this labile fraction were significantly reduced, being CMP more OC sequestering than HAC and HAL, in the order. These results confirmed that labile organic matter in soils can be protected from biodegradation by repartition into the hydrophobic domains of the stable, humified organic matter. This study suggests that mature compost and humic acids may usefully integrate management practices aimed to sequester organic carbon in soils.     

Towards a better understanding of magnesium-isotope ratios from marine skeletal carbonates

This study presents magnesium stable-isotope compositions of various biogenic carbonates of several marine calcifying organisms and an algae species, seawater samples collected from the western Dutch Wadden Sea, and reference materials. The aim of this study is to explore the influence of mineralogy, taxonomy and environmental factors (e.g., seawater isotopic composition, temperature, salinity) on magnesium-isotopic (δ²⁶Mg) ratios of skeletal carbonates. Using high-precision multi-collector inductively coupled plasma mass spectrometry, we observed that the magnesium-isotopic composition of seawater from the semi-enclosed Dutch Wadden Sea is identical to that of open marine seawater. We further found that a considerable component of the observed variability in δ²⁶Mg values of marine skeletal carbonates can be attributed to differences in mineralogy. Furthermore, magnesium-isotope fractionation is species-dependent, with all skeletal carbonates being isotopically lighter than seawater. While δ²⁶Mg values of skeletal aragonite and high-magnesium calcite of coralline red algae indicate the absence or negligibility of metabolic influences, the δ²⁶Mg values of echinoids, brachiopods and bivalves likely result from a taxon-specific level of control on Mg-isotope incorporation during biocalcification. Moreover, no resolvable salinity and temperature effect were observed for coralline red algae and echinoids. In contrast, Mg-isotope data of bivalves yield ambiguous results, which require further validation. The data presented here, point to a limited use of Mg isotopes as temperature proxy, but highlight the method’s potential as tracer of seawater chemistry through Earth’s history.     

Entstehung und Alter der Oberharzer Gänge

Ohne Zusammenfassung     

Protokoll der wissenschaftlichen Sitzung am 4. und 5. Januar 1937

Ohne Zusammenfassung