In situ oxygen,magnesium, and silicon isotopic compositions of the FUN inclusion Vigarano 1623-5

Oxygen, magnesium, and silicon isotopic abundances in Vigarano 1623-5 were studied using secondary ion mass spectrometry to investigate correlations between isotopic and petrologic properties of this unique forsterite-bearing FUN inclusion. Vigarano 1623-5 displays large, correlated mass-dependent fractionation effects, tightly linked to mineralogy within distinct petrologic units of the inclusion. The pyroxene-rich and melilite-rich interior parts of the inclusion display highly mass-fractionated isotopic compositions of oxygen, magnesium, and silicon, consistent with Rayleigh distillation during evaporation of a melt with initial oxygen composition close to a solar composition. However, the chemical composition, enriched in magnesium and silicon, suggests a precursor already fractionated by prior melt evaporation. A discontinuous igneous rim was produced by a flash-melting event followed by isotopic exchange in the rim melilite with planetary-like oxygen, mechanical fragmentation, and reassembly with an accretionary rim of heterogeneous materials. Al-rich minerals in 1623-5 show evidence for having crystallized with live ²⁶Al but at less than the “canonical” level of most CV calcium-aluminum-rich inclusions. However, well-defined ²⁶Al-²⁶Mg isochrons are not found and temporal implications are ambiguous.     

Temporal evolution of lead isotope ratios in sediments of the Central Portuguese Margin: A fingerprint of human activities

Stable Pb isotope ratios (²⁰⁶Pb/²⁰⁷Pb, ²⁰⁸Pb/²⁰⁶Pb), ²¹⁰Pb, Pb, Al, Ca, Fe, Mn and Si concentrations were measured in 7 sediment cores from the west coast of the Iberian Peninsula to assess the Pb contamination throughout the last 200 years. Independently of their locations, all cores are characterized by increasing Pb/Al rends not related to grain-size changes. Conversely, decreasing trends of ²⁰⁶Pb/²⁰⁷Pb were found towards the present. This tendency suggest a change in Pb sources reflecting an increased proportion derived from anthropogenic activities. The highest anthropogenic Pb inventories for sediments younger than 1950s were found in the two shallowest cores of Cascais and Lisboa submarine canyons, reflecting the proximity of the Tagus estuary. Lead isotope signatures also help demonstrate that sediments contaminated with Pb are not constrained to estuarine–coastal areas and upper parts of submarine canyons, but are also to transferred to a lesser extent to deeper parts of the Portuguese Margin.     

Redox-dependent removal of 27 organic trace pollutants: compilation of results from tank aeration experiments

The biodegradation of various wastewater-derived organic trace pollutants occurring in different aquatic compartments of the environment was previously reported to be influenced by the prevailing redox conditions. However, comparative studies on the redox-dependent degradation behavior of organic trace pollutants are scarce. The objective of the study presented herein, was to compile and evaluate data from several comparable previous tank experiments, thus, providing an overview on the redox-dependent removal of a total of 27 wastewater-derived trace compounds, including phenazone type compounds, antimicrobials, ß-blockers, psychoactive drugs and sulfonamides. Removal rate constants were fitted assuming first-order degradation kinetics. Six compounds were identified to be removed solely under oxic, three compounds solely under anoxic conditions. Others persisted under all experimental conditions, while some were removed under both oxic and anoxic conditions.     

Comparison and Combination of Coastal and Off-Shore Tide Gauge Measurements from Eivissa Island,Western Mediterranean

Two sea-level records, spanning eight months of simultaneous data in 2002, have been derived from pressure tide gauge measurements at Sant Antoni harbor (Eivissa Island, Western Mediterranean) and off Es Vedrà island, 15 km SW from Sant Antoni. The two time series are compared and used to characterize the sea-level variability in the Balearic Sea. The main forcings for the observed variations, astronomic tides, and meteorologic forcing by the inverse barometer effect are quantified. In a further step, an amplitude transfer function is determined, reflecting the frequency dependent amplification or damping of the nontidal sea-level residuals between both locations due to their local topography. The interpretation of the obtained transfer function indicates sea-level modulating topographic specifics not only for the coastal record at Sant Antoni, but also at the Es Vedrà site. In general, the application of such a transfer function allows the prediction of off-shore sea-level variations from coastal tide gauge measurements. In the present study, ellipsoidal sea-surface heights for Es Vedrà are inferred from Sant Antoni tide gauge data with an accuracy of about 1.5 cm by applying the determined transfer function and a geoid model.     

A spatially resolved high spectral resolution study of Neptune’s stratosphere

Using TEXES, the Texas Echelon cross Echelle Spectrograph, mounted on the Gemini North 8-m telescope we have mapped the spatial variation of H₂, CH₄, C₂H₂ and C₂H₆ thermal-infrared emission of Neptune. These high-spectral-resolution, spatially resolved, thermal-infrared observations of Neptune offer a unique glimpse into the state of Neptune’s stratosphere in October 2007, L_S = 275.4° just past Neptune’s southern summer solstice (L_S = 270°). We use observations of the S(1) pure rotational line of molecular hydrogen and a portion of the ν₄ band of methane to retrieve detailed information on Neptune’s stratospheric vertical and meridional thermal structure. We find global-average temperatures of 163.8 ± 0.8, 155.0 ± 0.9, and 123.8 ± 0.8 K at the 7.0 × 10⁻³-, 0.12-, and 2.1-mbar levels with no meridional variations within the errors. We then use the inferred temperatures to model the emission of C₂H₂ and C₂H₆ in order to derive stratospheric volume mixing ratios (hence forth, VMR) as a function of pressure and latitude. There is a subtle meridional variation of the C₂H₂ VMR at the 0.5-mbar level with the peak abundance found at −28° latitude, falling off to the north and south. However, the observations are consistent within error to a meridionally constant C₂H₂ VMR of at 0.5 mbar. We find that the VMR of C₂H₆ at 1-mbar peaks at the equator and falls by a factor of 1.6 at −70° latitude. However, a meridionally constant VMR of at the 1-mbar level for C₂H₆ is also statistically consistent with the retrievals. Temperature predictions from a radiative-seasonal climate model of Neptune that assumes the hydrocarbon abundances inferred in this paper are lower than the measured temperatures by 40 K at 7 × 10⁻³ mbar, 30 K at 0.12 mbar and 25 K at 2.1 mbar. The radiative-seasonal model also predicts meridional temperature variations on the order of 10 K from equator to pole, which are not observed. Assuming higher stratospheric CH₄ abundance at the equator relative to the south pole would bring the meridional trends of the inferred temperatures and radiative-seasonal model into closer agreement.We have also retrieved observations of C₂H₄ emission from Neptune’s stratosphere using TEXES on the NASA Infrared Telescope Facility (IRTF) in June 2003, L_S = 266°. Using the observations from the middle of the planet and an average of the middle three latitude temperature profiles from the 2007 observations (9.5° of L_S later, the seasonal equivalent of 9.5 Earth days within Earth’s seasonal cycle), we infer a C₂H₄ VMR of at 1.5 × 10⁻³ mbar, a value that is 3.25 times that predicted by global-average photochemical models.     

Detecting thermal anomalies within the Molasse Basin, southern Germany

The groundwater flow regime at great depth within the Molasse Basin (SW Germany) was studied. Data relevant for a flow model at 600–1,600 m depth are sparse in the western part of the basin. However, temperature measurements are available covering much of the area at a wide range of depths. Therefore, a thermal 3D steady-state model was set up with the aim of comparing modeled with observed subsurface temperatures. Stratigraphic information from many boreholes was also available, but only a few values of rock thermal conductivity and heat-production rate could be obtained. Some strong thermal residual anomalies were identified with respect to the purely conductive model, especially along fault zones, and within stratigraphic layers with high hydraulic conductivity. These anomalies can be explained by various advective heat-transport mechanisms, yet most explanations can be eliminated. The most plausible constellation explaining the major positive thermal anomalies of 10 Kelvin and more is a fault zone of E–W strike, intersected by an aquifer with flow parallel to the fault zone. This concept was investigated by using a simplified type model. In spite of some shortcomings, the method presented here can be used to identify temperature anomalies, and to identify possible explanations.     

Galaxy distribution in a 36□° field near the north galactic pole

The results of galaxy counts on plates taken with the Tautenburg Schmidt telescope in a 36□° region around the globular cluster M3 are presented and discussed. More than 26000 galaxies on four blue plates (covering the whole region) and nearly 18000 galaxies on two red plates (covering half the region) have been counted in 5′ × 5′ cells. The discussion in the present paper includes a first determination of the two-point correlation function and a dispersion curve analysis. The results are not very different from those obtained for the Jagiellonian field. It is suggested that counting errors may influence the conclusions drawn for the space distribution of galaxies and its possible secular change.     

Weitere OB-Assoziationen in den äußersten Randzonen von M 31

In comparing a U- and a B-plate of the Tautenburg 2 m Schmidt telescope 7 scattered groupings of blue objects have been discovered in the outer regions of the large Andromeda nebula. A closer investigation showed these objects to be apparently so far not known OB associations, well fitting to a spiral structure. With distances from the centre of the Andromeda nebula between R = 22.8 kpc and R = 27.9 kpc the objects still surpass the most distant association OB 188 of VAN den BERGH (R = 25.0 kpc).     

On the structure of the low surface brightness dwarf galaxies in the M81 group

A detailed photometry of spheroidal dwarf galaxies in the M81 group has been carried out. The integral characteristics and the structural parameters of the spheroidal dwarfs has been determined. Their luminosity profiles are well fitted to a King law. The investigated spheroidal dwarfs together with the prototypes of the Local Group form a common sequence according to their main parameters. The observational data presented show that dSphs are not linked evolutionary with normal E and dE galaxies, but probably form a separate branch together with irregular low surface brightness dwarfs.     

Structural investigations in the central part of the coma cluster on the base of equidensity diagrams. II

On the base of Tautenburg UBV-Schmidt plates equidensitometric diameters of galaxies of ROOD and BAUM 's list are given and the ellipticities in the three colours are determined. It was found that there is no difference in the ellipticities depending on the colours, on the average. The percentage of spherical objects (ε = 0.00) was found to 21.5 per cent. The surface brightness for 213 objects in the system V is given. The mean surface brightness is 22.75 mag/□′ with a dispersion of 2.5 mag/□′. It shows only a very slight dependence on the integrated magnitude.