The latitudinal distribution of carbon monoxide across the pacific from California to Antarctica

The results of a research study of the carbon monoxide concentration from California to 90° S, Antarctica are presented. The data both extend and support other research studies of the latitudinal distribution of carbon monoxide in that higher concentrations are evident over the Northern Hemisphere than over the Southern Hemisphere. Carbon monoxide concentrations range between 50 to 60 ppb with a few peaks into the 60s in the latitudinal area south of the ITCZ and values of 80 ppb or higher at latitudes north of Hawaii. A comparison is also made of carbon monoxide and ozone concentrations along the flight tract between California and Antarctica, over the Ellsworth Mountains of Antarctica, and between 78° S and the South Pole. These ozone-carbon monoxide data show statistically significant negative correlations in the upper troposphere and lower stratosphere over Antarctica. It is believed that this is a good indication of mixing across the tropopause.     

Structure proof and significance of stereoisomeric 28,30-bisnorhopanes in petroleum and petroleum source rocks

Two C₂₈H₄₈-pentacyclic triterpanes were isolated from Monterey shale. X-ray crystallography of a crystal containing both compounds proved their structures as 17β,18α,21α(H)-28,30-bisnorhopane and 17β,18α,21β(H)-28,30-bisnorhopane. Several differences are found between 28,30-bisnorhopanes and the regular hopanes. Unlike the regular hopane epimers, for practical purposes the three epimeric 28,30-bisnorhopanes [17α,21β(H)-, 17β,21α(H)-, and 17β,21β(H)-]cannot be distinguished by their mass spectra. Special conditions are needed to separate them by gas chromatography. The diagenetically first-formed epimer is thought to be 17α,21β(H)- because it predominates in immature shales. The order of thermodynamic stability is 17β,2lα(H) < > 17α,21β(H) > 17β,21β(H), and all three epimers are present in petroleum. 25,28,30-Trisnorhopanes can be analyzed in similar fashion and are found to have similar thermodynamic characteristics. The percent of the ring D/E cis epimer of 28,30-bisnorhopane and/or 25,28,30-trisnorhopane is a useful maturation parameter similar to the 20S/20R sterane ratio. Evidence indicates 25-demethylation of 28,30-bisnorhopane to 25,28,30-trisnorhopane during advanced stages of biodegradation. Hence, percent ring $\text{D}\text{E}$cis 25,28,30-trisnorhopane has an application to maturation assessment in heavily biodegraded oils.     

Meeresoptische Messungen während schwerer Stürme auf der Forschungsplattform “Nordsee” vom 14. November bis zum 8. Dezember 1980

Ocean Dynamics - Meeresoptische Messungen auf der Forschungsplattform “Nordsee” haben gezeigt, daß dort während schwerer Stürme, hauptsächlich durch den Einfluß...     

Field verification of a theoretical model to predict the dynamic response of a soft clay deposit

A 40-m thick clay deposit was subjected to sinusoidal excitations using a foundation block and an eccentric mass type vibrator. The response of the foundation block and the surrounding soil was measured using geophones inside the soil and on the surface. The phase shift between the excitation signal and the response signal, the accelerations of the foundation block and the particle velocities in the soil are compared with those obtained from a frequency-dependent numerical model based on the exact analytical solution for the boundary value problem of a rectangular foundation resting on a linear elastic halfspace.     

Transmission electron microscopic study of antiphase domains in CaAl2Ge2O8-Feldspar

Transmission electron microscopic study of synthetic CaAl₂Ge₂O₈-feldspar revealed two types of antiphase domains: type “b”-antiphase domains with the displacement vector 1/2 [110] and type “c”-antiphase domains with the displacement vector 1/2 [111]. The “b”-domains were on the order of 0.1 μm in size, while the “c”-domains displayed wall to wall distances mostly between 0.1 and 1 μm. The formation of the two types of antiphase domains is due to reductions in translational symmetry associated with the phase transitions \(C\bar 1 \to I\bar 1 \to P\bar 1\) . The antiphase domain textures of CaAl₂Ge₂O₈-feldspar are very similar to the textures found in natural and synthetic anorthite, CaAl₂Si₂O₈.     

Magmatism and metamorphism in the Ladakh Himalayas (the Indus-Tsangpo suture zone)

Ladakh (India) provides a complete geological section through the northwestern part of the Himalayas from Kashmir to Tibet. Within this section the magmatic, metamorphic and geotectonic evolution of the northern Himalayan orogeny has been studied using petrographic, geochemical and isotope analytical techniques.The beginning of the Himalayan cycle was marked by large basaltic extrusions (Panjal Trap) of Permian to Lower Triassic age at the “northern” margin of the Gondwana continent (Indian Shield). These continental type tholeiitic basalts were followed by a more alkaline volcanism within the Triassic to Jurassic Lamayuru unit of the Gondwana continental margin.Lower Jurassic to Cretaceous oceanic crust and sediments (ophiolitic mélange s.s.) accompany the Triassic to Cretaceous flysch deposits within the Indus-Tsangpo suture zone, the major structural divide between the Indian Shield (High Himalaya) and the Tibetan Platform. So far, no relic of Paleozoic oceanic crust has been found.Subduction of the Tethyan oceanic crust during Upper Jurassic and Cretaceous time produced an island arc represented by tholeiitic and calc-alkaline volcanic rock series (Dras volcanics) and related intrusives accompanied by volcaniclastic flysch deposits towards the Tibetan continental margin.Subsequent to the subduction of oceanic crust, large volumes of calc-alkaline plutons (Trans-Himalayan or Kangdese plutons) intruded the Tibetan continental margin over a distance of 2000 km and partly the Dras island arc in the Ladakh region.The collision of the Indian Shield and Tibetan Platform started during the middle to upper Eocene and caused large-scale, still active intracrustal thrusting as well as the piling up of the Himalayan nappes. The tectonically highest of these nappes is built up of oceanic crust and huge slices of peridotitic oceanic mantle (Spongtang klippe).In the High Himalayas the tectonic activity was accompanied and outlasted by a Barrovian-type metamorphism that affected Triassic sediments of the Kashmir-Nun-Kun synclinorium up to kyanite/staurolite grade and the deeper-seated units up to sillimanite grade. Cooling ages of micas are around 20 m.y. (muscovite) and 13 m.y. (biotite). Towards the Indus-Tsangpo suture zone metamorphism decreases with no obvious discontinuity through greenschist, prehnite-pumpellyite to zeolite grade. Remnants of possibly an Eo-Himalayan blueschist metamorphism have been found within thrust zones accompanying ophiolitic mélange in the suture zone.     

Very high CO2 cordierite from Norwegian Lapland: Mineralogy,petrology, and carbon isotopes

The most CO₂-rich cordierite thus far encountered in nature with about 2.2 wt.% CO₂ and 0.3 wt.% H₂O occurs as large poikiloblasts in a strange non-foliated reaction rock that dissects well-foliated granulites being part of the classical Lapland granulite area described by Eskola. The cordierite is optically positive with the highest optic angle 2V _x (106°) and birefringence (– = 0.017) ever measured on natural cordierites, but it is also optically very heterogeneous due to secondary loss of CO₂ along fractures and zones paralleling the fluid-bearing channels. Based on the optical properties of the degassed Lapland cordierite and on literature data a ternary diagram is given, which shows the variations of this cordierite in 2V _x and birefringence as a function of channel-filling with both CO₂ and H₂O.Following Losert (1971) the cordierite coexists with calcite, a thus far unique mineral assemblage that is probably only stable at very high CO₂ pressures. In the present case, the of the cordierite (0.75) indicates, on the basis of literature data, a coexisting fluid with >0.95.The carbon isotope composition ¹³C of CO₂ in cordierite lies near –7, that of the calcite is slightly lighter than about –9. Thus, at least for the CO₂ in cordierite, a deep-seated origin may be possible.Based on the geologic occurrence it is speculated that the cordierite-bearing reaction rock could perhaps represent an annealed channel of late degassing in the granulitic lower crust.     

Correlation of the Quaternary terrace sequence in the Lower Rhine valley and northern Alpine foothills of central Europe

Thirteen glacial terraces are known from the western part of the northern Alpine foothills between the Lech and Iller Rivers. In the Lower Rhine region of West Germany, a similar number of terraces are capped by interglacial floodloams and soils. Whereas the environment during individual interglaciations did not differ substantially, the glaciations were progressively more severe. The Main Terrace system of the Rhine may be an exception. The duration of the Quaternary, starting at the base of Praetiglian, is estimated at approximately 2 million yr by paleomagnetic dating. The major cold-warm climatic cycles of the earliest Pleistocene lasted approximately 100,000 yr, the same as those of the Brunhes Chron. The intervening Main Terrace system has not yet been climatically subdivided. Correlation with the Netherlands is possible because of an abundance of paleobotanic and paleomagnetic evidence. In the Alpine foothills, stratigraphically useful indicators of warm climates are missing, but analogies in terrace development permit comparison with the Lower Rhine and Danube. The terrace sequence in the Alpine foothills is incomplete, as are those along most of the other rivers in Europe. Some of the older terraces may have been eroded.