How does landfill leachate affect the chemical processes in a lake system downgradient from a landfill site?

A field study on the geochemical properties of a chemically-stressed limnic environment was performed in Lake Silbersee, which receives leachate water of high inorganic loading from an upgradient landfill site. The highly concentrated sulfate ion in groundwater, when entering the pore water system of the lake, gives rise to an intensive microbial sulfate reduction. A diagenetic approach was used to explain the existence of a marine-like aqueous system within a geologically slightly acidic aquifer, consisting of a well-buffered lake water and an alkalinity producing, excess sulphide containing sediment pore water system.     

Neue Ergebnisse zur Tektonik der Allgäuer und Vilser Alpen

Zusammenfassung Eine Neuuntersuchung der Tektonik in den Vilser Alpen und im Hochvogelgebiet, wo die Frage seit langer Zeit diskutiert wird, ob dort die Allgäu- und Lechtal-Decke getrennte Einheiten bilden, oder stratigraphisch untrennbar zusammenhängen, erbrachte eine eindeutige Entscheidung für den Deckenbau. Der Verlauf der Deckengrenze konnte zwischen Hochvogel und Hohenschwangauer Alpen präzisiert werden. Der interne Falten- und Schuppenbau der Lechtal-Decke hat nirgends zur Bildung von tektonisch tieferen Teildekken geführt, die internen Verschuppungen besitzen nur ein geringes Ausmaß.

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A new investigation of the tectonics in the Vilser Alps and in the Mt. Hochvogel area where since a long time a discussion was going on if the thrust sheets of Allgäu and Lechtal-Decke are separate units or connected by stratigraphic sequences, a definite decision could be made in favour of the nappe structure in this part of the Northern Calcareous Alps. The internal structure of the Lechtal-Decke thrust sheet is characterized by local imbricate structure which originate from sheared folds.

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Résumé On a dicuté depuis longtemps dans les Vilser Alpen et dans la région du Mont Hochvogel le problème, si les nappes de Allgäu et Lechtal-Decke sont des unités separées ou qu'ils forment une partie inséparable par des séquences stratigraphiques. Une nouvelle examen de la tectonique a affirmé la structure de nappes dans cette région des Alpes Calcaires du Nord. La structure intérieure de la nappe de Lechtal-Decke est caracterisée par une structure écaillée locale, qui se developpe de plis cisaillés.

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The latitudinal distribution of carbon monoxide across the pacific from California to Antarctica

The results of a research study of the carbon monoxide concentration from California to 90° S, Antarctica are presented. The data both extend and support other research studies of the latitudinal distribution of carbon monoxide in that higher concentrations are evident over the Northern Hemisphere than over the Southern Hemisphere. Carbon monoxide concentrations range between 50 to 60 ppb with a few peaks into the 60s in the latitudinal area south of the ITCZ and values of 80 ppb or higher at latitudes north of Hawaii. A comparison is also made of carbon monoxide and ozone concentrations along the flight tract between California and Antarctica, over the Ellsworth Mountains of Antarctica, and between 78° S and the South Pole. These ozone-carbon monoxide data show statistically significant negative correlations in the upper troposphere and lower stratosphere over Antarctica. It is believed that this is a good indication of mixing across the tropopause.     

Structure proof and significance of stereoisomeric 28,30-bisnorhopanes in petroleum and petroleum source rocks

Two C₂₈H₄₈-pentacyclic triterpanes were isolated from Monterey shale. X-ray crystallography of a crystal containing both compounds proved their structures as 17β,18α,21α(H)-28,30-bisnorhopane and 17β,18α,21β(H)-28,30-bisnorhopane. Several differences are found between 28,30-bisnorhopanes and the regular hopanes. Unlike the regular hopane epimers, for practical purposes the three epimeric 28,30-bisnorhopanes [17α,21β(H)-, 17β,21α(H)-, and 17β,21β(H)-]cannot be distinguished by their mass spectra. Special conditions are needed to separate them by gas chromatography. The diagenetically first-formed epimer is thought to be 17α,21β(H)- because it predominates in immature shales. The order of thermodynamic stability is 17β,2lα(H) < > 17α,21β(H) > 17β,21β(H), and all three epimers are present in petroleum. 25,28,30-Trisnorhopanes can be analyzed in similar fashion and are found to have similar thermodynamic characteristics. The percent of the ring D/E cis epimer of 28,30-bisnorhopane and/or 25,28,30-trisnorhopane is a useful maturation parameter similar to the 20S/20R sterane ratio. Evidence indicates 25-demethylation of 28,30-bisnorhopane to 25,28,30-trisnorhopane during advanced stages of biodegradation. Hence, percent ring $\text{D}\text{E}$cis 25,28,30-trisnorhopane has an application to maturation assessment in heavily biodegraded oils.     

Meeresoptische Messungen während schwerer Stürme auf der Forschungsplattform “Nordsee” vom 14. November bis zum 8. Dezember 1980

Ocean Dynamics - Meeresoptische Messungen auf der Forschungsplattform “Nordsee” haben gezeigt, daß dort während schwerer Stürme, hauptsächlich durch den Einfluß...     

Transmission electron microscopic study of antiphase domains in CaAl2Ge2O8-Feldspar

Transmission electron microscopic study of synthetic CaAl₂Ge₂O₈-feldspar revealed two types of antiphase domains: type “b”-antiphase domains with the displacement vector 1/2 [110] and type “c”-antiphase domains with the displacement vector 1/2 [111]. The “b”-domains were on the order of 0.1 μm in size, while the “c”-domains displayed wall to wall distances mostly between 0.1 and 1 μm. The formation of the two types of antiphase domains is due to reductions in translational symmetry associated with the phase transitions \(C\bar 1 \to I\bar 1 \to P\bar 1\) . The antiphase domain textures of CaAl₂Ge₂O₈-feldspar are very similar to the textures found in natural and synthetic anorthite, CaAl₂Si₂O₈.     

Correlation of the Quaternary terrace sequence in the Lower Rhine valley and northern Alpine foothills of central Europe

Thirteen glacial terraces are known from the western part of the northern Alpine foothills between the Lech and Iller Rivers. In the Lower Rhine region of West Germany, a similar number of terraces are capped by interglacial floodloams and soils. Whereas the environment during individual interglaciations did not differ substantially, the glaciations were progressively more severe. The Main Terrace system of the Rhine may be an exception. The duration of the Quaternary, starting at the base of Praetiglian, is estimated at approximately 2 million yr by paleomagnetic dating. The major cold-warm climatic cycles of the earliest Pleistocene lasted approximately 100,000 yr, the same as those of the Brunhes Chron. The intervening Main Terrace system has not yet been climatically subdivided. Correlation with the Netherlands is possible because of an abundance of paleobotanic and paleomagnetic evidence. In the Alpine foothills, stratigraphically useful indicators of warm climates are missing, but analogies in terrace development permit comparison with the Lower Rhine and Danube. The terrace sequence in the Alpine foothills is incomplete, as are those along most of the other rivers in Europe. Some of the older terraces may have been eroded.