Palaeontological and facial features of the Upper Jurassic Hochstegen Marble (Tauern Window, Eastern Alps)

Micropalaeontological, microscopic and mineralogical investigations of the ductily deformed and greenschist-facies metamorphic Hochstegen Marble in the Tauern Window shed new light on its stratigraphy and fades.
New radiolarian and sponge spicule discoveries have been made in cherty limestone marbles. They confirm previous age assignments and permit for the first time a more exact micropalaeontological age determination of early Tithonian for the upper parts of the marble. Forty morphotypes of radiolarians could be distinguished; in one sample a Fisher diversity index of 6 is reached indicating deeper marine conditions. The spicule fauna is also diverse and shows affinity to the S-German Malm. In respect to all the data it can be presumed that carbonate sedimentation of the Hochstegen Marble took place in a deeper marine environment at the southern margin of the European continent (Helvetic realm) during the whole Late Jurassic.     

Measures of Parameter Uncertainty in Geostatistical Estimation and Geostatistical Optimal Design

Studies of site exploration, data assimilation, or geostatistical inversion measure parameter uncertainty in order to assess the optimality of a suggested scheme. This study reviews and discusses measures for parameter uncertainty in spatial estimation. Most measures originate from alphabetic criteria in optimal design and were transferred to geostatistical estimation. Further rather intuitive measures can be found in the geostatistical literature, and some new measures will be suggested in this study. It is shown how these measures relate to the optimality alphabet and to relative entropy. Issues of physical and statistical significance are addressed whenever they arise. Computational feasibility and efficient ways to evaluate the above measures are discussed in this paper, and an illustrative synthetic case study is provided. A major conclusion is that the mean estimation variance and the averaged conditional integral scale are a powerful duo for characterizing conditional parameter uncertainty, with direct correspondence to the well-understood optimality alphabet. This study is based on cokriging generalized to uncertain mean and trends because it is the most general representative of linear spatial estimation within the Bayesian framework. Generalization to kriging and quasi-linear schemes is straightforward. Options for application to non-Gaussian and non-linear problems are discussed.     

The effect of mechanical waves on empirical solar models

Empirical solar models contain the effect of heating due to radiative energy loss from acoustic waves. We estimate here the temperature difference between the radiative equilibrium model and the empirical model. At optical depth ₅₀₀₀ = 0.1 this difference is small, but near the temperature minimum (₅₀₀₀ = 10^–4) it reaches between 53 and 83 K. The temperature difference between the equator and the poles caused by a hypothetical difference in the heating is estimated.     

Spectral analysis of the 91bg-like Type Ia SN 2005bl: low luminosity, low velocities, incomplete burning

The properties of underluminous Type Ia supernovae (SNe Ia) of the 91bg subclass have yet to be theoretically understood. Here, we take a closer look at the structure of the dim SN Ia 2005bl. We infer the abundance and density profiles needed to reproduce the observed spectral evolution between −6 d and  +12.9 d  with respect to B maximum. Initially, we assume the density structure of the standard explosion model W7; then we test whether better fits to the observed spectra can be obtained using modified density profiles with different total masses and kinetic energies. Compared to normal SNe Ia, we find a lack of burning products especially in the rapidly expanding outer layers  ( v ≳ 15 000 km s⁻¹)  . The zone between ∼8500 and 15 000 km s⁻¹ is dominated by oxygen and includes some amount of intermediate-mass elements. At lower velocities, intermediate-mass elements dominate. This holds down to the lowest zones investigated in this work. This fact, together with negligible-to-moderate abundances of Fe-group elements, indicates large-scale incomplete Si burning or explosive O burning, possibly in a detonation at low densities. Consistently with the reduced nucleosynthesis, we find hints of a kinetic energy lower than that of a canonical SN Ia: the spectra strongly favour reduced densities at  ≳13 000 km s⁻¹  compared to W7, and are very well fitted using a rescaled W7 model with original mass  (1.38 M_⊙)  , but a kinetic energy reduced by ∼30 per cent (i.e. from  1.33 × 10⁵¹  to  0.93 × 10⁵¹ erg  ).     

A Three-year Study of Nonmethane Hydrocarbons in Surface Air over Saxony (Germany)

Measurements of the nonmethane hydrocarbon (NMHC) mixing ratio over a period of 42 months were carried out for the first time in the air of a research station situated in the former East Germany during the SANA project. Apart from four species, all other species analysed showed a statistically significant downward trend at the 95% significance level. The decrease of the hydrocarbon concentrations was superimposed by seasonal variations. A drop of about 40% of the annual mean values from 1993 to 1995 was observed. This development reflects the dramatic changes in traffic, industry, power economy, and agriculture in Saxony after the reunification of Germany. The remove of two-stroke engined cars is reflected in NMHC mixing ratio changes, as is the removal of obsolete chemical plants. Generally it was not possible to relate causes and effects of a single event, but in some cases major changes in concentrations and NMHC ratios occurred coincidentally with the disappearance of a specific emission source.     

Extension of the Paraná Basin to offshore Brazil: Implications for coalbed methane evaluation

Coalbed methane (CBM) is a worldwide exploration target of the petroleum industry. In Brazil, the most important coal-bearing succession is associated with the Permian Rio Bonito Formation of the Paraná Basin. The gas-prone areas are located at the southeastern margin of the Paraná Basin and possibly in the offshore region of the northern part of the Pelotas Basin. Coalfields end abruptly at the present day shoreline, a result of rifting of Gondwana and the evolution of the South Atlantic Ocean. All geologic indicators suggest that in pre-rift times the coal seams extended further eastwards, probably now lying deeply buried below the sedimentary succession of the Pelotas Basin. The present paper discusses structural, stratigraphic, seismic and aeromagenetic data that support the preservation of continental crust beneath ocean sediment. If the coal beds had similar lateral extent to known onshore coals, and coal beds extended across the projected extension of the Parana basin, and there was a conservative 5 m of cumulative coal thickness, then a potential methane volume can be estimated for this newly inferred resource. Average onshore coal gas content is 32 scf/ton (1.00 m³/ton). If this is similar in the offshore coal deposits, then the hypothetical methane volume in the offshore area could be in excess of 1.9 × 10¹² scf (56 × 10⁹ m³). Metamorphism from dikes associated with rifting are potential complicating factors in these deposits, and since no borehole reaching the deep-lying strata in the offshore area are available, this is a hypothetical gas resource with a certain level of uncertainty which should be tested in the future by drilling a deep borehole.     

The impact of salt water inflows on the distribution of polycyclic aromatic hydrocarbons in the deep water of the Baltic Sea

Salt-water inflows into the Baltic Sea are important events for renewing the deep and bottom waters of the deep basins of the Baltic Sea. These events occur only at irregular intervals. The last strong event was in January 1993 followed by minor inflows in winter 1993/1994. As a result of these inflows, the deep water of the central Baltic basins was completely renewed.Based on extensive observations of polycyclic aromatic hydrocarbons (PAHs) in water, fluffy layer material and surface sediments between 1992 and 1998, the transformation of PAHs and the modification of their distribution in the Baltic deep water is discussed in connection with the spreading of the inflowing highly saline and oxygen-rich water along its pathway from the sills into the central basins. In the course of the inflows in 1993/1994, the PAH concentration in the deep water of the different basins increased significantly. The concentrations were elevated, at least by a factor of 2 and as much as seven to eight times (for the four-ring PAHs) compared to the previous and the following years. Two hypotheses for the causes were discussed: the inflowing salt water may have entrained more highly polluted surface water in the western Baltic Sea, or it may have entrained contaminated fluffy layer material or sediment particles along the route of transport.     

Quaternary geology of the Amazonian Lowland

The Quaternary history of the Amazon lowlands is characterized by deposition of sediments of Andean provenance and by the influences of changing sea levels. Areas well above the present water tables were not reached by Pleistocene high-water stages. These areas have been intensively weathered since the Tertiary, forming hard lateritic weathering horizons. These weathering horizons are best explained by the relatively constant, humid tropical climate throughout the Quaternary. In the western Amazonian Lowland, flood plains corresponding to the different Pleistocene sea-level heights were formed. During low sea level, erosion in the drainage areas increased and the water levels of the central Amazon River system were lowered. Valleys drowned and lakes formed in the lower reaches of rivers and creeks during high sea-level stages. These lakes (ria lakes) remained in the valleys with rivers having a low sediment load. Seismic profiling (3.5 kHz) in some of these lakes clearly showed deposits of the three last periods of Quaternary high sea-level stages.     

Automated Extraction of a Five‐Year LA‐ICP‐MS Trace Element Data Set of Ten Common Glass and Carbonate Reference Materials: Long‐Term Data Quality,Optimisation and Laser Cell Homogeneity

LA‐ICP‐MS is increasingly applied to obtain quantitative multi‐element data with minimal sample preparation, usually achieved by calibration using reference materials (RMs). However, some ubiquitous RMs, for example the NIST SRM 61× series glasses, suffer from reported value uncertainties for certain elements. Moreover, no long‐term data set of analyses conducted over a range of ablation and tuning conditions exists. Thus, there has been little rigorous examination of the extent to which offsets between measured and reported values are the result of error in these values rather than analytically induced fractionation. We present new software (‘LA‐MINE’), capable of extracting LA‐ICP‐MS data with no user input, and apply this to our system, yielding over 5 years of data (~ 5700 analyses of ten glass and carbonate RMs). We examine the relative importance of systematic analytical bias and possible error in reported values through a mass‐specific breakdown of fourteen of the most commonly determined elements. Furthermore, these data, obtained under a wide range of different ablation conditions, enable specific recommendations of how data quality may be improved, for example the role of diatomic gas, the effect of differential inter‐glass fractionation factors and choice of transport tubing material. Finally, these data demonstrate that the two‐volume Laurin ablation cell is characterised by no discernible spatial heterogeneity in measured trace element ratios.