Microbial Degradation of Tar Oil Compounds under Different Redox Conditions

The microbial transformation of typical tar oil compounds such as acridine, benzo(b)thiophene, dibenzofuran, indane, and indene under different redox conditions was investigated in microcosm studies. Under aerobic conditions the inherent contamination in polluted soil as well as the added N‐, S‐, O‐ heterocyclic and homocyclic compounds were transformed predominantly apart from thiophene. 1‐Indanone was detected by RP‐HPLC‐DAD and GC‐MS as an intermediate metabolite from indane and indene. Under nitrate and sulfate reducing conditions indane, benzo(b)thiophene, and dibenzofuran were transformed in assays with the polluted soil samples from well B 65 and B 66 within 426 days, whereas they were persistent in assays with the highly polluted soil B 67. All heterocyclic and homocyclic compounds added to the non‐contaminated soil from well B 85 were not degraded under nitrate and sulfate reducing conditions, too. The results indicate that for the decision, wether natural attenuation can be implemented in the remediation of contaminated site, in addition to BTEX and PAHs especially the fate of further tar oil compounds in anoxic aquifers has to be considered.     

Late Pleistocene outburst floods from Issyk Kul,Kyrgyzstan?

Elevated shorelines and lake sediments surrounding Issyk Kul, the world's second largest mountain lake, record fluctuating lake levels during Quaternary times. Together with bathymetric and geochemical data, these markers document alternating phases of lake closure and external drainage. The uppermost level of lake sediments requires a former damming of the lake's western outlet through the Boam gorge. We test previous hypothesised ice or landslide dam failures by exploring possible links between late Quaternary lake levels and outbursts. We review and recompile the chronology of reported changes in lake site, and offer new ages of abandoned shorelines using ¹⁴C in bivalve and gastropod shells, and plant detritus, as well as sand lenses in delta and river sediments using Infrared Stimulated Luminescence. Our dates are consistent with elevated lake levels between ~45 ka and 22 ka. Cosmogenic ¹⁰Be and ²⁶Al exposure ages of fan terraces containing erratic boulders (>3 m) downstream of the gorge constrain the timing of floods to 20.5–18.5 ka, postdating a highstand of Issyk Kul. A flow‐competence analysis gives a peak discharge of >10⁴ m³ s^–1 for entraining and transporting these boulders. Palaeoflood modelling, however, shows that naturally dammed lakes unconnected to Issyk Kul could have produced such high discharges upon sudden emptying. Hence, although our data are consistent with hypotheses of catastrophic outburst floods, average lake‐level changes of up to 90 mm yr^–1 in the past 150 years were highly variable without any outbursts, so that linking lake‐level drops to catastrophic dam breaks remains ambiguous using sedimentary archives alone. This constraint may readily apply to other Quaternary lakes of that size elsewhere. Nonetheless, our reconstructed Pleistocene floods are among the largest reported worldwide, and motivate further research into the palaeoflood hydrology of Central Asia. Copyright © 2017 John Wiley & Sons, Ltd.     

碳酸盐风化碳汇与森林碳汇的对比——碳汇研究思路和方法变革的必要性

目前,全球碳循环研究主要集中在海洋碳汇以及陆地土壤和植被碳汇,而对岩石风化碳汇仅考虑地质长时间尺度的硅酸盐风化作用,而认为碳酸盐风化在长时间尺度上对碳汇无贡献。然而,碳酸盐相对于硅酸盐有快得多的溶解速度,且对全球变化(特别是气候和CO2变化)的响应迅速,同时由于生物作用和人为活动的影响,使得碳酸盐风化碳汇的能力需要重新评价。最新的研究发现,由碳酸盐溶解、全球水循环及水生生物光合利用溶解无机碳共同作用,即水-岩-气-生相互作用形成的大气碳汇,远远大于之前只估计了河流输运的无机碳汇,其量级与森林碳汇量相当,因此有必要对传统的碳汇研究思路和方法进行某些变革,这有可能为解决所谓的全球“碳失汇”问题找到一条出路。      

Jurassic strike slip versus subduction in the Eastern Alps

Late Jurassic formations of the Northern Calcareous Alps (NCA) contain ample evidence of synsedimentary tectonics in the form of elongate basins filled with turbidites, debris flows and slumps. Clasts are derived from the Mesozoic of the NCA; they commonly measure tens of metres in diameter and occasionally form kilometre-size bodies. These sedimentologic observations and the presumed evidence of Late Jurassic high-pressure metamorphism recently led to the hypothesis of a south-dipping Jurassic subduction zone with accretionary wedge in the southern parts of the NCA. We present new ⁴⁰Ar/³⁹Ar dates from the location of the postulated high-pressure metamorphism that bracket the age of this crystallization not earlier than 114–120 Ma. The event is therefore part of the well-documented mid-Cretaceous metamorphism of the Austro-alpine domain. Thus, there is currently no evidence of Late Jurassic high-pressure metamorphism to support the subduction hypothesis. The sediment record of the Late Jurassic deformation in the NCA, including the formation of local thrust sheets, is no conclusive evidence for subduction. All these phenomena are perfectly compatible with synsedimentary strike-slip tectonics. Large strike-slip fault zones with restraining and releasing bends and associated flower structures and pull-apart basins are a perfectly viable alternative to the subduction model for the Late Jurassic history of the NCA. However, in contrast to the Eastern Alps transect, where arguments for a Jurassic subduction are missing, a glaucophane bearing Jurassic high-pressure metamorphism in the Meliatic realm of the West Carpathians is well documented. There, the high-pressure/low-temperature slices occur between the Gemeric unit and the Silica nappe system (including the Aggtelek-Rudabanya units), which corresponds in facies with the Juvavic units in the southern part of the NCA. To solve the contrasting palaeogeographic reconstructions we propose that the upper Jurassic left lateral strike-slip system proposed here for the Eastern Alps continued eastwards and caused the eastward displacement of the Silica units into the Meliatic accretionary wedge.     

Über stratigraphische Untersuchungsmethoden in rezenten Tiefseesedimenten

Zusammenfassung Durch Bestimmung der Foraminiferenanzahl in I g Sediment wird die biostratigraphische Untersuchungsmethode, die mittels einer qualitativen und quantitativen Erfassung der Foraminiferenfauna in den Tiefseekernen der deutschen Meteor-Expedition und schwedischen Albatroß-Expedition durchgeführt werden ist, auf ihre Richtigkeit hin geprüft. Die Untersuchung hat die Anwendbarkeit dieser stratigraphischen Methode bestätigt. Sie hat daneben wiederum gezeigt, daß die Verbreitung und Entwicklung der einzelnen Foraminiferenarten vor allem von der Temperatur des Meerwassers abhängig sind; andere Faktoren wie Phosphatgehalt des Wassers usw. scheinen in dieser Hinsicht eine mehr untergeordnete Rolle zu spielen. Unter gewissen Voraussetzungen können Tiefseekerne durch Bestimmung der Foraminiferenanzahl je 1 g Sediment in groben Zügen stratigraphisch gegliedert werden; auch kann die Individuenanzahl der einzelnen Foraminiferenarten aus der Foraminiferenanzahl in 1 g Sediment und aus der prozentualen Zusammensetzung der Gesamtfauna errechnet werden. Mit den hier gewonnenen Erkenntnissen wird versucht, die engen Bezichungen zwischen dem prozentualen Anteil der Warmwasserforaminiferen in der Gesamtfauna und dem CO₂-Gehalt des Sedimentes, dieOvey im Kern 241 der schwedischen Albatroß-Expedition beobachtet hat, zu deuten.Herrn Professor Dr.Carl W. Correns zum 60. Geburtstag gewidmet.     

Identifying causes of ground-penetrating radar reflections using time-domain reflectometry and sedimentological analyses

Ground-penetrating radar (GPR) is a geophysical technique widely used to study the shallow subsurface and identify various sediment features that reflect electromagnetic waves. However, little is known about the exact cause of GPR reflections because few studies have coupled wave theory to petrophysical data. In this study, a 100- and 200-MHz GPR survey was conducted on aeolian deposits in a quarry. Time-domain reflectometry (TDR) was used to obtain detailed information on the product of relative permittivity (ɛ_r) and relative magnetic permeability (μ_r), which mainly controls the GPR contrast parameter in the subsurface. Combining TDR data and lacquer peels from the quarry wall allowed the identification of various relationships between sediment characteristics and ɛ_rμ_r. Synthetic radar traces, constructed using the TDR logs and sedimentological data from the lacquer peels, were compared with the actual GPR sections. Numerous peaks in ɛ_rμ_r, which are superimposed on a baseline value of 4 for dry sand, are caused by potential GPR reflectors. These increases in ɛ_rμ_r coincide with the presence of either organic material, having a higher water content and relative permittivity than the surrounding sediment, or iron oxide bands, enhancing relative magnetic permeability and causing water to stagnate on top of them. Sedimentary structures, as reflected in textural change, only result in possible GPR reflections when the volumetric water content exceeds 0·055. The synthetic radar traces provide an improved insight into the behaviour of radar waves and show that GPR results may be ambiguous because of multiples and interference.     

Catabolic and anabolic energy for chemolithoautotrophs in deep-sea hydrothermal systems hosted in different rock types

Active deep-sea hydrothermal vents are hosted by a range of different rock types, including basalt, peridotite, and felsic rocks. The associated hydrothermal fluids exhibit substantial chemical variability, which is largely attributable to compositional differences among the underlying host rocks. Numerical models were used to evaluate the energetics of seven inorganic redox reactions (potential catabolisms of chemolithoautotrophs) and numerous biomolecule synthesis reactions (anabolism) in a representative sampling of these systems, where chemical gradients are established by mixing hydrothermal fluid with seawater. The wide ranging fluid compositions dictate demonstrable differences in Gibbs energies (ΔG_r) of these catabolic and anabolic reactions in three peridotite-hosted, six basalt-hosted, one troctolite-basalt hybrid, and two felsic rock-hosted systems. In peridotite-hosted systems at low to moderate temperatures (<∼45 °C) and high seawater:hydrothermal fluid (SW:HF) mixing ratios (>10), hydrogen oxidation yields the most catabolic energy, but the oxidation of methane, ferrous iron, and sulfide can also be moderately exergonic. At higher temperatures, and consequent SW:HF mixing ratios <10, anaerobic processes dominate the energy landscape; sulfate reduction and methanogenesis are more exergonic than any of the aerobic respiration reactions. By comparison, in the basalt-hosted and felsic rock-hosted systems, sulfide oxidation was the predominant catabolic energy source at all temperatures (and SW:HF ratios) considered. The energetics of catabolism at the troctolite-basalt hybrid system were intermediate to these extremes. Reaction energetics for anabolism in chemolithoautotrophs—represented here by the synthesis of amino acids, nucleotides, fatty acids, saccharides, and amines—were generally most favorable at moderate temperatures (22-32 °C) and corresponding SW:HF mixing ratios (∼15). In peridotite-hosted and the troctolite-basalt hybrid systems, ΔG_r for primary biomass synthesis yielded up to ∼900 J per g dry cell mass. The energetics of anabolism in basalt- and felsic rock-hosted systems were far less favorable. The results suggest that in peridotite-hosted (and troctolite-basalt hybrid) systems, compared with their basalt (and felsic rock) counterparts, microbial catabolic strategies—and consequently variations in microbial phylotypes—may be far more diverse and some biomass synthesis may yield energy rather than imposing a high energetic cost.     

Meteorological causes of Harmattan dust in West Africa

We investigated the temporal dynamics of dust entrainment in the Bodélé Depression, Central Sahara, to better understand the intra-annual variability of aerosol emission in the world's largest dust source. The linkages between dust entrainment and large-scale meteorological factors were examined by correlating several meteorological variables in the Mediterranean and Africa north of the equator with the aerosol concentrations in the Bodélé Depression separately for winter and summer. The methodological tools applied are NCEP/NCAR reanalysis data and the aerosol index of the Total Ozone Mapping Spectrometer (TOMS-AI), available for 15 years from 1978 to 1993. We found that dust mobilisation during the Harmattan season is highly dependent on air pressure variability in the Mediterranean area. High pressure to the north of the Bodélé intensifies the NE trade winds, leading to an increased entrainment of dust in the Bodélé Depression. In summer, dust mobilization cannot be explained by the large scale meteorological conditions. This highlights the importance of local to regional wind systems linked to the northernmost position of the intertropical convection zone (ITCZ) during this time.     

Geochronological constraints on the evolution of the Periadriatic Fault System (Alps)

Fault rocks from various segments of the Periadriatic fault system (PAF; Alps) have been directly dated using texturally controlled Rb-Sr microsampling dating applied to mylonites, and both stepwise-heating and laser-ablation ⁴⁰Ar/³⁹Ar dating applied to pseudotachylytes. The new fault ages place better constraints on tectonic models proposed for the PAF, particularly in its central sector. Along the North Giudicarie fault, Oligocene (E)SE-directed thrusting (29-32 Ma) is currently best explained as accommodation across a cogenetic restraining bend within the Oligocene dextral Tonale-Pustertal fault system. In this case, the limited jump in metamorphic grade observed across the North Giudicarie fault restricts the dextral displacement along the kinematically linked Tonale fault to ~30 km. Dextral displacement between the Tonale and Pustertal faults cannot be transferred via the Peio fault because of both Late Cretaceous fault ages (74-67 Ma) and sinistral transtensive fault kinematics. In combination with other pseudotachylyte ages (62-58 Ma), widespread Late Cretaceous-Paleocene extension is established within the Austroalpine unit, coeval with sedimentation of Gosau Group sediments. Early Miocene pseudotachylyte ages (22-16 Ma) from the Tonale, Pustertal, Jaufen and Passeier faults argue for a period of enhanced fault activity contemporaneous with lateral extrusion of the Eastern Alps. This event coincides with exhumation of the Penninic units and contemporaneous sedimentation within fault-bound basins.