Die äußersten Endmoränen der jüngsten Vereisung Norddeutschlands

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Characterisation of Fulvic Acids and Glycyrrhizic Acid by Time‐of‐Flight Secondary Ion Mass Spectrometry

Fulvic acids of different origin, spray deposited on polished silicon after dissolution in high‐purity water without any additives, were analysed by time‐of‐flight secondary ion mass spectrometry (TOF‐SIMS) in combination with oblique 24...36 keV SF₅⁺ ion bombardment. The observed, highly reproducible mass spectra cover more than five orders of magnitude in dynamic range, without background subtraction. Apart from lines due to atomic ions and low‐mass ion fragments, the mass spectra exhibit broad maxima between m/z 200...350, mainly due to a beat‐like superposition of lines at every single mass number, up to at least m/z 400. In the negative ion spectra the beats have a spacing of m/z 14, corresponding to a CH₂‐unit. The high‐mass tails of the spectra extend well beyond m/z 5000, with similar slopes in the positive and the negative ion mass spectra. The negative spectra appear to be less affected by fragmentation products than the positive spectra. Fulvic acids (FAs) of different origin show distinctly different spectra, with mean masses ranging between m/z ≈ 450 and 580 (for a low‐mass cut‐off m/z 150). To further verify the ability of TOF‐SIMS to detect molecules and clusters with masses significantly above the maxima of the FA spectra, samples of glycyrrhizic acid (GA, as GA ammonium salt with molecular weight 840) were also analysed. Parent ions as well as multimers (GA)_n were observed as positive and negative ions, up to n = 4 (m/z 3320). The results are compared with spectra recently obtained by other mass spectrometric techniques.     

Recursive evaluation of interaction forces and property matrices from unit-impulse response functions of unbounded medium based on balancing approximation

Starting from the unit-impulse response matrix of the unbounded medium, a discrete-time formulation permitting the recursive evaluation of the interaction forces and a continuous-time formulation yielding property matrices corresponding to a model with a finite number of degrees of freedom are discussed. This is achieved using the balancing approximation method which is easily automated, guarantees stability and leads to highly accurate results. © 1998 John Wiley & Sons Ltd.     

Spring-dashpot-mass models for foundation vibrations

The foundation on deformable soil, which, in general, radiates energy, can be represented in structural dynamics as a simple spring-dashpot-mass model with frequency-independent coefficients. For the two limiting cases of a site, the homogeneous half-space and the homogeneous layer fixed at its base, the coefficients are specified in tables for varying parameters such as ratios of dimensions and Poisson's ratio. Rigid foundations on the surface and with embedment are considered for all translational and rotational motions. In a practical analysis of soil–structure interaction this dynamic model of the foundation is coupled directly to that of the structure, whereby a standard dynamics program is used. © 1997 by John Wiley & Sons, Ltd.     

Isotopic and noble gas study of Chalk groundwater in the London Basin, England

The chemical and isotopic composition of groundwater from 52 sites in the London (U.K.) area was determined as part of a project aimed at assessing the spatial variation in the age of Chalk groundwater, and in determining the relationship between fracture and matrix groundwater in this dual porosity system.Systematic changes in groundwater chemistry take place in the downgradient direction in response to several chemical processes. These processes include early concentration by evaporation and congruent dissolution of calcite followed by widespread incongruent dissolution and ion exchange in addition to local oxidation-reduction reactions, gypsum dissolution and saline intrusion. As a result of the above processes, Chalk groundwater follows an evolutionary path from Ca bicarbonate type to Na bicarbonate type.The age of Chalk groundwater was modelled using¹⁴C, δ¹³C,³H, δ²H and δ¹⁸0. There is a general increase in the groundwater age in a downgradient direction with the oldest water found in N central areas of the basin. Groundwater in the unconfined zones and in areas S of the Greenwich fault is almost entirely of unevolved, modem composition. Carbon-14 modelling suggests that Chalk groundwater in the S basin is generally less than 10000 a old while that in the north is generally between 10000 and 25000 a old. The presence of³H in concentrations of up to 7 TU in groundwater which yields ages of several 1000 a, however, indicates that mechanisms exist for the rapid introduction of recent groundwater to the confined aquifer. Results of palaeorecharge temperature determinations using δ²H, δ¹⁸0 and noble gas analytical results suggest that significant Devensian recharge did indeed occur in the aquifer.A model of the development of the Chalk recognizes that it is a classic dual porosity aquifer in which groundwater flow occurs predominantly in the fracture system. The upper 50 m of the aquifer was flushed with fresh water during the 2–3 × 10⁶ a of the Quaternary and therefore meteoric water largely replaced the Tertiary and Cretaceous marine water that previously saturated the system. Most processes which control the chemistry of the groundwater occur in the matrix where the surface area is exceptionally high. Although fracture flow dominates the flow regime, diffusion from the matrix into the fracture porosity controls the chemistry of Chalk groundwater.     

Accurate GPS measurement of the location and orientation of a floating platform

Abstract

This article describes the design and initial tests of the GPS portion of a system for making seafloor geodesy measurements. In the planned system, GPS antennas on a floating platform will be used to measure the location of an acoustic transducer, attached below the platform, which interrogates an array of transponders on the seafloor. Since the GPS antennas are necessarily some distance above the transducer, a short‐baseline GPS interferometer consisting of three antennas is used to measure the platform's orientation.

A preliminary test of several crucial elements of the system was performed at the Scripps Institution of Oceanography (SIO) in December 1989. The test involved a fixed antenna on the pier and a second antenna floating on a buoy about 80 m away. GPS measurements of the vertical component of this baseline, analyzed independently by two groups using different software, agree with each other and with an independent measurement within a centimeter.

The first test of an integrated GPS/acoustic system took place in the Santa Cruz Basin off the coast of southern California in May 1990. In this test a much larger buoy, designed and built at SIO, was equipped with three GPS antennas and an acoustic transducer that interrogated a transponder on the ocean floor. Preliminary analysis indicates that the horizontal position of the transponder can be determined with a precision of about a centimeter. Further analysis will be required to investigate the magnitude of systematic errors.     

Vulnerability and risk: comparing assessment approaches

The concepts vulnerability and risk are of great importance in the fields of climate change and natural hazards. Confusion is asserted in the terminology used by the respective communities, and a large conceptual literature has not solved this problem. This affects the communication within and between the two communities and the comparison of results from vulnerability and risk assessments. This paper argues that the main difference between methods to assess vulnerability and risk in the climate and the disaster communities is not a conceptual one, but rather different terminologies are used. This point is made using a formal framework of vulnerability to climate change that makes the structure of vulnerability and risk assessments explicit. The framework distinguishes three assessment approaches in the field of vulnerability to climate change, which recur—under different labels—in the risk assessment approaches analysed. While within each community, the same terms are ambiguously used to refer to more than one assessment approach, the confusion is enhanced between the two communities by using different labels for very similar approaches. As an application of the results, similarities and differences between two assessment tools are analysed: the Dynamic Interactive Vulnerability Assessment model (DIVA) for the case of vulnerability to climate change and the CATastrophe SIMulation model (CatSim) for risk of natural hazards.