Revised marine reservoir offset (ΔR) values for molluscs and marine mammals from Arctic North America

Appropriate marine–terrestrial reservoir offset (ΔR) values are essential for accurate calibration of marine radiocarbon dates. However, ΔR values are only valid for the specific calibration curve that their calculation is based on. Here, we present revised ΔR values for the Marine20 calibration curve from Arctic North America, based on previously published ¹⁴C dates on pre-bomb live-collected marine molluscs (n = 124) and cetaceans (beluga whales; tooth dentine; n = 12), and bowhead whale–driftwood age comparisons from the same glacio-isostatically uplifted shorelines (n = 18). Molluscan-based ΔR are: Chukchi/Beaufort sea coasts, 265±116 ¹⁴C years; NW Canadian Arctic Archipelago, 188±91 ¹⁴C years; NE Baffin Island, 81±18 ¹⁴C years; SE Baffin Island, 14±58 ¹⁴C years; Hudson Strait, −73±64 ¹⁴C years; Ungava Bay, 0±86 ¹⁴C years; Foxe Basin, 175±89 ¹⁴C years; Hudson Bay, −21±72 ¹⁴C years; James Bay, 209±114 ¹⁴C years; West Greenland, −93±111 ¹⁴C years. Species-specific marine mammal ΔR terms are 107±59 ¹⁴C years for beluga and 24±58 ¹⁴C years for bowheads. Our revised ΔR values are applicable for as long as the same broad oceanographic conditions (circulation, ventilation) have persisted, i.e. through the Holocene. While molluscan values are applicable to other marine carbonate (e.g. foraminifera), cetacean ΔR are valid only for the species they were calculated for and should not be applied to other marine mammals. Importantly, the ΔR terms calculated here are only valid for Marine20 and should not be used with earlier or later calibration curves.     

Periglacial and Fluvial Factors Controlling the Sedimentation of Pleistocene Breccia in NW Poland

Breccias were investigated on the terrace of the Toruń‐Eberswalde ice‐marginal valley at Rozwarzyn (NW Poland). Breccia layers include soft‐sediment clasts with diameters between 2 and 256 mm and soft‐sediment megaclasts with diameters from 256 mm to 7 m. The shape of the soft‐sediment clasts and megaclasts (derived from frozen sediments) in the breccia is diverse: from angular and irregular in the case of debris‐flow breccias to slightly rounded and tabular in fluvial breccias. These two types of breccias were developed during the Late Weichselian when the periglacial climate favored extensive lateral erosion by currents of frozen braided channels in the ice‐marginal valley. The dual presence of breccias of fluvial and debris‐flow origin in channel deposits is unique for Quaternary sediments. Zones of breccias existed in the channels where scours and obstacle marks related to megaclasts developed. The study of breccias shed new light on the fluvial processes in ice‐marginal valleys during the Pleistocene and can be considered as diagnostic for fluvio‐periglacial conditions.     

Lithological and geochemical record of anthropogenic changes in recent sediments of a small and shallow lake (Lake Pusty Staw,northern Poland)

The article presents the results of lithological and geochemical investigations of recent sediments of Lake Pusty Staw. The analysed sediments document about 300 years of the history of this lake. Historical materials indicate that significant changes in the catchment of the lake took place from the beginning of the 18th century (deforestation and afforestation) followed by 19th century tourist development, and 20th century industrialisation. The sediments were dated using the ²¹⁰Pb and ¹³⁷Cs method and core lithology. These made it possible to establish a reliable chronology to the year 1730. The calculated sedimentation rates ranged between 0.17 and 0.83 cm year^–1. There was a period of intensified erosion caused by land clearance between 1734 and 1810, which resulted in an acceleration in sedimentation rate (0.36 cm year^–1) and a change of lithological type of sediment from detritus gyttja to clayey gyttja. On the basis of Cu, Zn, Cd and Pb content in the sediments, it was determined that the beginning of pollution of the lake dates back to the 19th century and was caused probably by the existence of a health resort. A systematic increase in pollution occurred in the 20th century as a result of industrial plants. Normalised with respect to Al, the content of heavy metals in polluted sediments was from several to twenty times higher than in sediments of the preindustrial period, and a comparison of historical materials with changes of sediments in most cases made it possible to identify the direct causes of the increase in pollution.     

Binary gas sorption/desorption experiments on a bituminous coal: Simultaneous measurements on sorption kinetics,volumetric strain and acoustic emission

There is still no clear understanding of the specific interactions between coal and gas molecules. In this context sorption–desorption studies of methane and carbon dioxide, both in a single gas environment and gas mixtures, are of fundamental interest. This paper presents the results of unique simultaneous measurements of sorption kinetics, volumetric strain and acoustic emission (AE) on three tetragonal coal samples subjected to sorption of carbon dioxide and methane mixtures. The coal was a high volatile bituminous C coal taken from the Budryk mine in the Upper Silesia Basin, Poland. Three different gas mixtures were used in the sorption tests, with dominant CO₂, with dominant CH₄ and a 50/50 mixture.The experimental set-up was designed specially for this study. It consisted of three individual units working together: (i) a unit for gas sorption experiments using a volumetric method, (ii) an AE apparatus for detecting, recording and analysing AE, and (iii) a strain meter for measuring strains induced in the coal sample by gas sorption/desorption. All measurements were computer aided.The experiments indicated that the coal tested showed preferential sorption of CH₄ at 2.6 MPa pressure and exhibited comparable affinities for CH₄ and CO₂ at higher pressures (4.0 MPa). The results of chromatographic analysis of the gas released on desorption suggested that the desorption of methane from the coal was favoured. The relationship between the volumetric strain and the amount of sorbed gas was found to be non-linear. These results were contrary to common opinions on the coal behaviour. Furthermore, it appeared that the swelling/shrinkage of coal was clearly influenced by the network of fractures. Besides, the AE and strain characteristics suggested common sources of sorption induced AE and strain.The present results may have implications for the sequestration of carbon dioxide in coal seams and enhanced coalbed methane recovery (ECBM).     

Hyperspectral imaging of sedimentary bacterial pigments: a 1700-year history of meromixis from varved Lake Jaczno,northeast Poland

Hypoxia in freshwater systems is currently spreading globally and putting water quality, biodiversity and other ecosystem services at risk. Such adverse effects are of particular concern in permanently stratified meromictic lakes. Yet little is known about when and how meromixis and hypoxia became established (or vanished) prior to anthropogenic impacts, or how human activities such as deforestation, erosion and nutrient cycling affected the mixing regimes of lakes. We used calibrated hyperspectral imaging (HSI) data in the visible and near infrared range from a fresh, varved sediment core taken in Lake Jaczno, NE Poland, to map sedimentary pigments at very high resolution (sub-varve scale) over the past 1700 years. HSI-inferred bacteriopheophytin a (bphe a, produced by anoxygenic phototrophic bacteria) serves as a proxy for meromixis, whereas HSI-inferred green pigments (chlorophyll a and diagenetic products) can be used as estimators of aquatic productivity. Meromixis was established and vanished long before significant human disturbance in the catchment was observed in the late eleventh century AD. Under pre-anthropogenic conditions, however, meromixis was interrupted frequently, and the lake mixing regime flickered between dimixis and meromixis. During two periods with intense deforestation and soil erosion in the catchment, characterised by sedimentary facies rich in clay and charcoal (AD 1070–1255 and AD 1670–1710), the lake was mostly dimictic and better oxygenated than in periods with relative stability and a presumably closed forest around the lake, i.e. without human disturbances. After ca. AD 1960, meromixis became established quasi-permanently as a result of eutrophication. The persistent meromixis of the last ~60 years is unusual with respect to the record of the last 1700 years.     

Application of electrical and electromagnetic methods to study sedimentary covers in high mountain areas

The results of geophysical studies conducted with selected electrical and electromagnetic methods in the Kondratowa Valley in the Tatra Mountains (the Carpathian Mountains, Poland) are presented in the article. The surveys were performed with the following methods: electrical resistivity tomography (ERT), georadar (GPR) and conductivity meter (CM). The objective of the noninvasive geophysical measurements was to determine the thickness of the Quaternary postglacial sediments that fill the bottom of the valley and to designate the accumulation of boulders deposited on Quaternary sediments. The results of ERT surveys conducted along the axis of the valley allowed to determine the changeability of the thickness of the postglacial sediments and allowed to designate a few areas of occurrence of boulders. The ERT, GPR and CM surveys conducted across the valley allowed to designate with high accuracy the thickness of the accumulation of boulders sliding down the valley bottom from the couloirs surrounding the valley.     

Toxicity studies of elemental sulfur in marine sediments

Elemental sulfur(ES) is a component essential for proper development of animals, but it can be toxic for aquatic organisms. The objectives of the study reported here included determination of ES concentrations in sediment collected in the area of the Gulf of Gdansk(Baltic Sea) and search for the possible correlations with the ecotoxicity results. Sediment samples were collected from four locations: the Vistula River mouth, in the Port Basin, in the area of discharge of the treated wastewater from the Wastewater Treatment Plant(WWTP) and in the area of the sunken World War Ⅱ s/s 'Stuttgart' shipwreck. The levels of elemental sulfur were determined using a gas chromatograph coupled with a mass spectrometer(GC-MS). Toxicity of marine sediment samples was estimated for three biotest organisms-bioluminescent bacteria Vibrio fischeri, crustacean Heterocypris incongruens, and Synapis alba plant. The highest toxicity of sediments for all indicator organisms was observed in samples taken at the place of the shipwreck(2-100%). The same samples had a high sulfur content(16.7-143.2 μg/g dry weight(d.w.))therefore, it was decided to investigate whether the presence of ES in the sediment in the studied area can have an impact on the results of the ecotoxicity determination in real samples. However, the removal of sulfur from the samples resulted in no significant changes in the level of toxicity of the samples. In this research it could not be confirmed that the presence of elemental sulfur is the only factor responsible for the observed sediment toxicity. It seems that other compounds or their mixtures present in the sediment may have a significant influence on the results obtained.     

Deep lithospheric structure beneath the Polish part of the East European Craton as a result of magnetotelluric surveys

Studia Geophysica et Geodaetica - A fundamental tectonic boundary between the Precambrian East European Craton (EEC) and the younger Phanerozoic mountain belts of Europe runs through Poland....