Isotopic and thermochronologic evidence of extremely cold lithosphere associated with a slab flattening in the Central Andes of Argentina

We present mineralogic, isotopic and thermochronologic analyses on psammopelitic and tuffaceous levels from the Bermejo and Vinchina basins – both foreland depocentres of the Central Andes of Argentina – that define a low‐temperature regime for the crust akin to a slab shallowing and flattening process. The contents of illite in illite/smectite interstratified (I/S) show a progressive illitization into the deeper parts of both basins. The distribution of I/S is compatible with theoretical simulations and predicted heat flow values of ca. 26 mW m^?2 in the 8–3.4 Ma interval for the Vinchina Basin and ca. 42 mW m^?2 since 9 Ma for the Bermejo Basin. The latter shows heat flow values that are comparable to those reported by magnetotelluric analysis (36–40 mW m^?2) in agreement with previously published heat flow calculations along the modern Andean foreland. The Rb–Sr isochrones in psammopelites (<2 μm fractions) show ages between 125 and 165 Ma, whereas the K–Ar ages decrease as the grain size is smaller (136–224 Ma for 1–2 μm, 112–159 Ma for 0.2–1 μm, 76–116 Ma for <0.2 μ and 39.3–42 Ma for <0.1 μm). These ages are significantly older than the sedimentation in the basins (ca. 16 Ma for the Vinchina Basin; U–Pb age), and can be explained by the presence of a significant amount of detrital components, mainly illite, even in the finer fractions. The preservation of detrital ages is consistent with the shallow diagenesis related to a low‐temperature regime, proposed here for the basins. Younger K–Ar ages (21.3–12 Ma) were obtained for a basal tuffaceous level. Clay mineralogy and R0 ordering in the deepest part of the Vinchina Basin, together with the evolution model of I/S with depth, suggest that the burial temperatures would have not exceeded ca. 100°C in agreement with (U–Th)/He analyses performed on apatite extracted from two tuffaceous units. Thermal indicators from both studied basins confirm the existence of a low‐temperature regime during flat subduction.     

Using cosmo-skymed images to detect wet snow cover on the Kraków Ice Field,King George Island,Antarctica

This work analysed the spatio-temporal variation of snow cover on the Kraków Ice Field, located in the King George Island, Antarctica. High spatial resolution images of COSMO-SkyMed were used in this study. These X-band images are vertically and horizontally co-polarized and their intensity data were converted to amplitude (dB). The COSMO-SkyMed images were classified by a minimum distance algorithm and post-classified based on knowledge of adjacency relationships of snow zones. Hypsometric, slope, aspect and solar radiation maps to support the interpretation of backscatter patterns in the COSMO-SkyMed images. Three radar zones were classified in these images: percolation, slush and wet snow radar zone. Positive surface air temperatures and rainfall events, registered from a meteorological station, lead to increase in wet snow and slush zones. The COSMO-SkyMed images and minimum distance algorithm were adequate to discriminate the snow cover and to assess the supraglacial melting pattern during the ablation season in the study area.     

Antifouling effect of bioactive compounds from selected marine organisms in the Obhur Creek,Red Sea

Three species of sponges and a tunicate were collected from Obhur creek of Jeddah coast for this bioactivity study. In order to assess the antifouling efficacy of selected marine organisms, methanolic extracts of these organisms were tested against different fouling bacterial forms and II-instar stage of the barnacle, Balanus amphitrite. Antibiosis, bioactivity and followed by multivariate analyses were carried out to check the efficacy of antifouling effect of the selected marine organisms. Principal component analysis revealed the exemplary antifouling efficacy of the sponge extracts of Stylissa sp. observed followed by Hyrtios sp. against bacterial forms in the laboratory study. De-trended correspondence analysis confirmed that the contribution of antifouling efficacy of the selected sponge extracts was observed to be more towards Bacillus sp., Vibrio sp. and Alteromonas sp. Moreover, the efficacy of Hyrtios sp. extract(20.430 μg m L~(-1)) followed by Stylissa sp.(30.945 μg m L~(-1)) showed higher against barnacle instar compared with other extracts in the bioactivity assay. Bray-Curtis cluster analysis under paired linkage categorized all the sponge extracts into one major cluster with 75% similarity, and one outlier tunicate. More than 80% similarity observed between Hyrtios sp. and Stylissa sp. Fourier transform infrared spectroscopy(FTIR) showed that the contribution of major peaks found in the marine organisms were towards sulfones, sulfoxides, cyanates and ketones.     

An optimized spatial proximity model for fine particulate matter air pollution exposure assessment in areas of sparse monitoring

GIS-based proximity models are one of the key tools for the assessment of exposure to air pollution when the density of spatial monitoring stations is sparse. Central to exposure assessment that utilizes proximity models is the ‘exposure intensity–distance’ hypothesis. A major weakness in the application of this hypothesis is that it does not account for the Gaussian processes that are at the core of the physical mechanisms inherent in the dispersion of air pollutants.

Building upon the utility of spatial proximity models and the theoretical reliability of Gaussian dispersion processes of air pollutants, this study puts forward a novel Gaussian weighting function-aided proximity model (GWFPM). The study area and data set for this work consisted of transport-related emission sources of PM_2.5 in the Houston-Baytown-Sugar Land metropolitan area. Performance of the GWFPM was validated by comparing on-site observed PM_2.5 concentrations with results from classical ordinary kriging (OK) interpolation and a robust emission-weighted proximity model (EWPM). Results show that the fitting R² between possible exposure intensity calculated by GWFPM and observed PM_2.5 concentrations was 0.67. A variety of statistical evidence (i.e., bias, root mean square error [RMSE], mean absolute error [MAE], and correlation coefficient) confirmed that GWFPM outperformed OK and EWPM in estimating annual PM_2.5 concentrations for all monitoring sites. These results indicate that a GWFPM utilizing the physical dispersing mechanisms integrated may more effectively characterize annual-scale exposure than traditional models. Using GWFPM, receptors’ exposure to air pollution can be assessed with sufficient accuracy, even in those areas with a low density of monitoring sites. These results may be of use to public health and planning officials in a more accurate assessment of the annual exposure risk to a population, especially in areas where monitoring sites are sparse.     

Correlation factors for impurity diffusion on the sublattice of dodecahedral sites in garnet

The method of Koiwa and Ishioka (Philos Mag A 47:927–938, 1983) is used, with slight modification, to evaluate the correlation factor for vacancy-mediated diffusion of impurity atoms on the sublattice of dodecahedral sites in garnet, as a function of the relevant vacancy-jump frequencies. The required values of the lattice Green’s function were obtained from multiple Monte Carlo simulations in lattices of progressively larger size, extrapolated to an infinite lattice using a model that linearizes the dependence of the functional value on lattice size. As Online Resources, codes are provided that permit evaluation of the correlation factor for any chosen set of vacancy-jump frequencies, for implementation in either Mathematica ^® or Matlab ^®.     

Large-amplitude periodic variations in the angular diameter of R Leonis

We report the first direct detection of long-term periodic diameter variations in a Mira variable. Angular diameter measurements of the 313-d period variable R Leonis at 833 nm and 940 nm obtained between 1996 February and 1997 June using the Cambridge Optical Aperture Synthesis Telescope (COAST) and the William Herschel Telescope (WHT) show a cyclic modulation of the apparent stellar diameter by approximately 35 per cent. The agreement between these new data and archival measurements from 1992 January suggests coherence in the modulation over a 5-yr period. Our data are consistent with recent models which suggest that, in photometric bands with only weak to moderate molecular contamination, periodic variations in stellar diameter of order 50 per cent can be maintained. The measurements indicate that the apparent stellar diameter was largest at visual phase 0.5 and that any phase shifts between the visual light curve and those at 833 and 940 nm were at most 0.05. The large offset (∼ 0.25) between the phase of the observed diameter maximum and that predicted for the photospheric continuum diameter variations suggests that our observations are more sensitive to the changing temperature structure of the outer atmosphere than to the deeper continuum-forming layers.     

Environmental magnetic record of Antarctic palaeoclimate from Eocene/Oligocene glaciomarine sediments, Victoria Land Basin

The onset of continent-wide glaciation in Antarctica is still poorly understood, despite being one of the most important palaeoclimatic events in the Cenozoic. The Eocene/Oligocene boundary interval has recently been recognized as a critical time for Antarctic climatic evolution, and it may mark the preglacial–glacial transition. Magnetic susceptibility, intensity of natural and artificial remanences, hysteresis parameters and magnetic anisotropy of the lower half (late Eocene/early Oligocene) of the CIROS-1 core (from McMurdo Sound, Antarctica) reveal alternating intervals of high and low magnetic mineral concentrations that do not correspond to lithostratigraphic units in the core. Pseudo-single-domain magnetite is the main magnetic mineral throughout the sequence, and sharp changes in magnetite concentration match changes in clay mineralogy beneath and at the Eocene/Oligocene boundary. The detrital magnetite originated from weathering of the Ferrar Group (which comprises basic extrusive and intrusive igneous rocks). Weathering processes and input of magnetite to the Victoria Land Basin were intense during periods when the Antarctic climate was warmer than today, but during intervals when the climate was relatively cool, chemical weathering of the Ferrar Group was suppressed and input of detrital magnetite to the Victoria Land Basin decreased. Our results also indicate that a cold and dry climate was not established in Antarctica until the Eocene/Oligocene boundary, with major ice sheet growth occurring at the early/late Oligocene boundary. Some earlier cold intervals are identified, which indicate that climate had begun to deteriorate by the middle/late Eocene boundary.