Atomistic model of diopside-K-jadeite (CaMgSi<Subscript>2</Subscript>O<Subscript>6</Subscript>-KAlSi<Subscript>2</Subscript>O<Subscript>6</Subscript>) solid solution

Atomistic model was proposed to describe the thermodynamics of mixing in the diopside-K-jadeite solid solution (CaMgSi₂O6-KAlSi₂O₆). The simulations were based on minimization of the lattice energies of 800 structures within a 2 × 2 × 4 supercell of C2/c diopside with the compositions between CaMgSi₂O₆ and KAlSi₂O₆ and with variable degrees of order/disorder in the arrangement of Ca/K cations in M2 site and Mg/Al in Ml site. The energy minimization was performed with the help of a force-field model. The results of the calculations were used to define a generalized Ising model, which included 37 pair interaction parameters. Isotherms of the enthalpy of mixing within the range of 273–2023 K were calculated with a Monte Carlo algorithm, while the Gibbs free energies of mixing were obtained by thermodynamic integration of the enthalpies of mixing. The calculated T-X diagram for the system CaMgSi₂O₆-KAlSi₂O₆ at temperatures below 1000 K shows several miscibility gaps, which are separated by intervals of stability of intermediate ordered compounds. At temperatures above 1000 K a homogeneous solid solution is formed. The standard thermodynamic properties of K-jadeite (KAlSi₂O₆) evaluated from quantum mechanical calculations were used to determine location of several mineral reactions with the participation of the diopside-K-jadeite solid solution. The results of the simulations suggest that the low content of KalSi₂O₆ in natural clinopyroxenes is not related to crystal chemical factors preventing isomorphism, but is determined by relatively high standard enthalpy of this end member.     

Indebted to Fair Trade? Coffee and crisis in Nicaragua

This paper explores the following general question: Why are Fair Trade coffee farmers in Nicaragua burdened by debt? Nearly five years from “the end” of the coffee crisis, peasant farming households committed to Fair Trade standards continue to struggle with a legacy of indebtedness caused by years of low farm-gate prices and declining productivity between 2000 and 2004. Through ethnographic observation and interviews with peasant farmers in Nicaragua, I explore how farmers experience a simple reproduction squeeze that hinders them from “bootstrapping” their own economic development. I argue that the effort to raise the Fair Trade minimum price and premium for coffee through Fair Trade Labelling Organizations International (FLO) in 2008 demonstrated a good first step toward improving farm-gate prices, however, these gains must be understood in the context of long-term indebtedness as well as rising production costs and household consumption costs.     

Reconciling indigenous need with the urban welfare state? Evidence of culturally-appropriate services and spaces for Aboriginals in Winnipeg, Canada

Despite the increasing urbanization of the Aboriginal population in Canada over the past 50 years, most municipalities have not developed services and programs designed to meet their unique social and cultural needs. Faced with numerous health and social problems, the Aboriginal population is mainly forced to rely on the non-Aboriginal social services sector. However, little is known about the extent to which such sectors seek to accommodate Aboriginal populations in their programming. We examine the extent to which the recovery system makes space for Aboriginal healing through the provision of culturally-appropriate services and programming. Through the use of 24 in-depth interviews with staff members at seven treatment facilities in Winnipeg (Canada), we find an entrenched reluctance, indifference and lack of desire to create Aboriginal spaces of healing in treatment, save for one facility where Aboriginal healing spaces serve as a focal point of treatment. We discuss the implications in terms of the effectiveness of the non-Aboriginal recovery system (along with other social services) in meeting the needs of Canada’s urban Aboriginal population.     

Using numerical deformation–fluid-flow simulations to understand and target gold mineralisation around basalt domes in the Stawell Zone, Central Victoria, Australia

We present 3-D deformation–fluid-flow numerical models which place constraints on the importance of basalt dome shape and syn-mineralising shortening direction in localising structurally controlled gold mineralisation around basalt domes near Stawell, Victoria, Australia. Gold mineralisation in the Magdala ore-body at the Stawell Mine occurs predominantly within a thin altered unit named the Magdala Facies which blankets the basalt domes. In numerical models of the Magdala Dome models only the east–northeast–west–northwest and east–west shortened models record high fluid-flow rates in areas of known mineralisation which is consistent with the syn-mineralisation shortening directions. In models of the Kewell Dome (a prospect to the north), the position of areas of high fluid-flow rate when shortened in the east–northeast–west–northwest and east–west direction, combined with information from limited drilling indicated the potential for gold mineralisation at the south-west end of the dome. Diamond drill holes in this area yielded significant gold values.     

Cycles and shifts: 1,300 years of multi-decadal temperature variability in the Gulf of Alaska

The Gulf of Alaska (GOA) is highly sensitive to shifts in North Pacific climate variability. Here we present an extended tree-ring record of January–September GOA coastal surface air temperatures using tree-ring width data from coniferous trees growing in the mountain ranges along the GOA. The reconstruction (1514–1999), based on living trees, explains 44% of the temperature variance, although, as the number of chronologies decreases back in time, this value decreases to, and remains around ∼30% before 1840. Verification of the calibrated models is, however, robust. Utilizing sub-fossil wood, we extend the GOA reconstruction back to the early eighth century. The GOA reconstruction correlates significantly (95% CL) with both the Pacific Decadal Oscillation Index (0.53) and North Pacific Index (−0.42) and therefore likely yields important information on past climate variability in the North Pacific region. Intervention analysis on the GOA reconstruction identifies the known twentieth century climate shifts around the 1940s and 1970s, although the mid-1920s shift is only weakly expressed. In the context of the full 1,300 years record, the well studied 1976 shift is not unique. Multi-taper method spectral analysis shows that the spectral properties of the living and sub-fossil data are similar, with both records showing significant (95% CL) spectral peaks at ∼9–11, 13–14 and 18–19 years. Singular spectrum analysis identifies (in order of importance) significant oscillatory modes at 18.7, 50.4, 38.0, 91.8, 24.4, 15.3 and 14.1 years. The amplitude of these modes varies through time. It has been suggested (Minobe in Geophys Res Lett 26:855–858, 1999) that the regime shifts during the twentieth century can be explained by the interaction between pentadecadal (50.4 years) and bidecadal (18.7 years) oscillatory modes. Removal of these two modes of variance from our GOA time series does indeed remove the twentieth century shifts, but many are still identified prior to the twentieth century. Our analysis suggests that climate variability of the GOA is very complex, and that much more work is required to understand the underlying oscillatory behavior that is observed in instrumental and proxy records from the North Pacific region.

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Mercury Redox Chemistry in the Negro River Basin, Amazon: The Role of Organic Matter and Solar Light

Pristine water bodies in the Negro River basin, Brazilian Amazon, show relatively high concentrations of mercury. These waters are characterized by acidic pH, low concentrations of suspended solids, and high amounts of dissolved organic matter and are exposed to intense solar radiation throughout the year. This unique environment creates a very dynamic redox chemistry affecting the mobility of mercury due to the formation of the dissolved elemental species (Hg⁰). It has been shown that in this so-called black water, labile organic matter from flooded forest is the major scavenger of photogenerated H₂O₂. In the absence of hydrogen peroxide, these black waters lose their ability to oxidize Hg⁰ to Hg²⁺, thus increasing Hg⁰ evasion across the water/atmosphere interface, with average night time values of 3.80 pmol m^?2 h^?1. When the dry period starts, labile organic matter inputs gradually diminish, allowing the increasing concentration of H₂O₂ to re-establish oxidative water conditions, inhibiting the metal flux across the water/atmosphere interface and contributing to mercury accumulation in the water column.     

Multigrid preconditioned conjugate-gradient solver for mixed finite-element method

The mixed finite-element approximation to a second-order elliptic PDE results in a saddle-point problem and leads to an indefinite linear system of equations. The mixed system of equations can be transformed into coupled symmetric positive-definite matrix equations, or a Schur complement problem, using block Gauss elimination. A preconditioned conjugate-gradient algorithm is used for solving the Schur complement problem. The mixed finite-element method is closely related to the cell-centered finite difference scheme for solving second-order elliptic problems with variable coefficients. For the cell-centered finite difference scheme, a simple multigrid algorithm can be defined and used as a preconditioner. For distorted grids, an additional iteration is needed. Nested iteration with a multigrid preconditioned conjugate gradient inner iteration results in an effective numerical solution technique for the mixed system of linear equations arising from a discretization on distorted grids. Numerical results show that the preconditioned conjugate-gradient inner iteration is robust with respect to grid size and variability in the hydraulic conductivity tensor.     

Geological observations in high‐grade mid‐Proterozoic rocks from Else Platform,northern Prince Charles mountains region,east Antarctica

Granulite facies rocks on Else Platform in the northern Prince Charles Mountains, east Antarctica, consist of metasedimentary gneiss extensively intruded by granitic rocks. The dominant rock type is a layered garnetbiotite‐bearing gneiss intercalated with minor garnet‐cordierite‐sillimanite gneiss and calc‐silicate. Voluminous megacrystic granite intruded early during a mid‐Proterozoic (ca 1000 Ma) granulite event, M₁, widely recognized in east Antarctica. Peak metamorphic conditions for M₁ are in the range of 650–750 MPa at ～800°C and were associated with the development of a gneissic foliation, S₁ and steep east‐plunging lineation, L₁. Strain partitioning during progressive non‐coaxial deformation formed large D₂ granulite facies south‐dipping thrusts, with a steep, east‐plunging lineation. In areas of lower D₂ strain, large‐scale upright, steep east‐plunging fold structures formed synchronously with the D₂ high‐strain zones. Voluminous garnet‐bearing leucogneiss intruded at 940 ±20 Ma and was deformed in the D₂ high‐strain zones. Textural relationships in pelitic rocks show that peak‐M2 assemblages formed during increasing temperatures via reactions such as biotite + sillimanite + quartz ± plagioclase = spinel + cordierite + ilmenite + K‐feldspar + melt. In biotite‐absent rocks, re‐equilibration of deformed M₁ garnet‐sillimanite‐ilmenite assemblages occurred through decompressive reactions of the form, garnet + sillimanite + ilmenite = cordierite + spinel + quartz. Pressure/temperature estimates indicate that peak‐M₂ conditions were 500–600 MPa and 700±50°C. At about 500 Ma, north‐trending granitic dykes intruded and were deformed during D₃‐M₃ at probable upper amphibolite facies conditions. Cooling from peak D₃‐M₃ conditions was associated with the formation of narrow greenschist facies shear zones, and the intrusion of pegmatite. Cross‐cutting all features are abundant north‐south trending alkaline mafic dykes that were emplaced over the interval ca 310–145 Ma, reflecting prolonged intrusive activity. Some of the dykes are associated with steeply dipping faults that may be related to basin formation during Permian times and later extension, synchronous with the formation of the Lambert Graben in the Cretaceous.     

Quaternary corals from reefs in the Wakatobi Marine National Park,SE Sulawesi,Indonesia, show similar growth rates to modern corals from the same area

We have used digital photography, image analysis and measurements in the field to determine the growth rates of Quaternary corals in the Wakatobi Marine National Park, Indonesia, and compared them to growth rates of similar corals in the same area. In the Quaternary deposits it was possible to measure the growth rates of two massive coral genera Porites and Favites. For each genus, the corals reworked from better‐illuminated upslope environments had higher growth rates than the in situ fossil corals. The calculated radial growth rates for the in situ Porites are slightly lower than, but of the same order of magnitude as, the modern Porites growing in 10 m water depth at Hoga (10.04 ± 3.34 mm yr^?1 ± 1 s.d.; n = 3) and Kaledupa (15.26 ± 4.83 mm yr^?1 ± 1 s.d.; n = 3). Sedimentation rates and underwater visibility are inferred to have been similar in the fossil site to that at the modern Kaledupa site. Decreasing light penetration due to increased water depth is inferred to have been a major influence on growth rates. The in situ massive corals with good growth banding are inferred to have grown in a comparable environment to modern Kaledupa and Hoga. The study highlights that it is possible to compare coral growth rates, and their influencing parameters, from modern and well‐preserved ancient examples. Copyright © 2006 John Wiley & Sons, Ltd.