Geometry and architectural associations of co-genetic debrite–turbidite beds in basin-margin strata, Carboniferous Ross Sandstone (Ireland): Applications to reservoirs located on the margins of structurally confined submarine fans

Co-genetic debrite–turbidite beds are most commonly found in distal basin-plain settings and basin margins. This study documents the geometry, architectural association and paleogeographic occurrence of co-genetic debrite–turbidite beds in the Carboniferous Ross Sandstone with the goal of reducing uncertainty in the interpretation of subsurface data in similarly shaped basins where oil and gas is produced.The Ross Sandstone of western Ireland was deposited in a structurally confined submarine basin. Two outcrops contain co-genetic debrite–turbidite beds: Ballybunnion and Inishcorker. Both of the exposures contain strata deposited on the margin of the basin. An integrated dataset was used to characterize the stratigraphy of the Ballybunnion exposure. The exposure is divided into lower, middle, and upper units. The lower unit contains laminated shale with phosphate nodules, structureless siltstone, convolute bedding/slumps, locally contorted shale, and siltstone turbidites. The middle unit contains co-genetic debrite–turbidite beds, siltstone turbidites, and structureless siltstone. Each co-genetic debrite–turbidite bed contains evidence that fluid turbulence and matrix strength operated alternately and possibly simultaneously during deposition by a single sediment-gravity-flow event. The upper unit contains thin-bedded sandy turbidites, amalgamated sandy turbidites, siltstone turbidites, structureless siltstone, and laminated shale. A similar vertical facies pattern is found at Inishcorker.Co-genetic debrite–turbidite beds are only found at the basin-margin. We interpret these distinct beds to have originated as sand-rich, fully turbulent flows that eroded muddy strata on the slope as well as interbedded sandstone and mudstone in axial positions of the basin floor forming channels and associated megaflute erosional surfaces. This erosion caused the axially dispersing flows to laterally evolve to silt- and clay-rich flows suspended by both fluid turbulence and matrix strength due to a relative increase in clay proportions and associated turbulence suppression. The flows were efficient enough to bypass the basin center/floor, physically disconnecting their deposits from coeval lobes, resulting in deposition of co-genetic debrite–turbidite beds on the basin margin. The record of these bypassing flows in axial positions of the basin is erosional surfaces draped by thin siltstone beds with organic debris.A detailed cross-section through the Ross Sandstone reveals a wedge of low net-to-gross, poor reservoir-quality strata that physically separates sandy, basin-floor strata from the basin margin. The wedge of strata is referred to as the transition zone. The transition zone is composed of co-genetic debrite–turbidite beds, structureless siltstone, slumps, locally contorted shale, and laminated shale. Using data from the Ross Sandstone, two equations are defined that predict the size and shape of the transition zone. The equations use three variables (thickness of basin-margin strata, thickness of coeval strata on the basin floor, and angle of the basin margin) to solve for width (w) and trajectory of the basinward side of the low net-to-gross wedge (β). Beta is not a time line, but a facies boundary that separates sandy basin floor strata from silty basin-margin strata. The transition zone is interpreted to exist on lateral and distal margins of the structurally confined basin.Seismic examples from Gulf of Mexico minibasins reveal a wedge of low continuity, low amplitude seismic facies adjacent to the basin margin. Strata in this wedge are interpreted as transition-zone sediments, similar to those in the Ross Sandstone. Besides defining the size and shape of the transition zone, the variables “w” and “β” define two important drilling parameters. The variable “w” corresponds to the minimum distance a well bore should be positioned from the lateral basin margin to intersect sandy strata, and “β” corresponds to the deviation (from horizontal) of the well bore to follow the interface between sandy and low net-to-gross strata. Calculations reveal that “w” and “β” are related to the relative amount of draping, condensed strata on the margin and the angle of the basin margin. Basins with shallowly dipping margins and relatively high proportions of draping, clay-rich strata have wider transition zones compared to basins with steeply dipping margins with little draping strata. These concepts can reduce uncertainty when interpreting subsurface data in other structurally confined basins including those in Gulf of Mexico, offshore West Africa, and Brunei.     

Methylmercury production in sediments of Chesapeake Bay and the mid-Atlantic continental margin

Methylmercury (MeHg) concentration and production rates were studied in bottom sediments along the mainstem of Chesapeake Bay and on the adjoining continental shelf and slope. Our objectives were to 1) observe spatial and temporal changes in total mercury (HgT) and MeHg concentrations in the mid-Atlantic coastal region, 2) investigate biogeochemical factors that affect MeHg production, and 3) examine the potential of these sediments as sources of MeHg to coastal and open waters. Estuarine, shelf and slope sediments contained on average 0.5 to 1.5% Hg as MeHg (% MeHg), which increased significantly with salinity across our study site, with weak seasonal trends. Methylation rate constants (k_meth), estimated using enriched stable mercury isotope spikes to intact cores, showed a similar, but weaker, salinity trend, but strong seasonality, and was highly correlated with % MeHg. Together, these patterns suggest that some fraction of MeHg is preserved thru seasons, as found by others [Orihel, D.M., Paterson, M.J., Blanchfield, P.J., Bodaly, R.A., Gilmour, C.C., Hintelmann, H., 2008. Temporal changes in the distribution, methylation, and bioaccumulation of newly deposited mercury in an aquatic ecosystem. Environmental Pollution 154, 77] Similar to other ecosystems, methylation was most favored in sediment depth horizons where sulfate was available, but sulfide concentrations were low (between 0.1 and 10 μM). MeHg production was maximal at the sediment surface in the organic sediments of the upper and mid Bay where oxygen penetration was small, but was found at increasingly deeper depths, and across a wider vertical range, as salinity increased, where oxygen penetration was deeper. Vertical trends in MeHg production mirrored the deeper, vertically expanded redox boundary layers in these offshore sediments. The organic content of the sediments had a strong impact on the sediment:water partitioning of Hg, and therefore, on methylation rates. However, the HgT distribution coefficient (K_D) normalized to organic matter varied by more than an order of magnitude across the study area, suggesting an important role of organic matter quality in Hg sequestration. We hypothesize that the lower sulfur content organic matter of shelf and slope sediments has a lower binding capacity for Hg resulting in higher MeHg production, relative to sediments in the estuary. Substantially higher MeHg concentrations in pore water relative to the water column indicate all sites are sources of MeHg to the water column throughout the seasons studied. Calculated diffusional fluxes for MeHg averaged  1 pmol m^− 2 day^− 1. It is likely that the total MeHg flux in sediments of the lower Bay and continental margin are significantly higher than their estimated diffusive fluxes due to enhanced MeHg mobilization by biological and/or physical processes. Our flux estimates across the full salinity gradient of Chesapeake Bay and its adjacent slope and shelf strongly suggest that the flux from coastal sediments is of the same order as other sources and contributes substantially to the coastal MeHg budget.     

Dissolved aluminium and the silicon cycle in the Arctic Ocean

Concentrations of dissolved (0.2 µm filtered) aluminium (Al) have been determined for the first time in the Eurasian part of the Arctic Ocean over the entire water column during expedition ARK XXII/2 aboard R.V. Polarstern (2007). An unprecedented number of 666 samples was analysed for 44 stations along 5 ocean transects. Dissolved Al in surface layer water (SLW) was very low, close to 1 nM, with lowest SLW concentrations towards the Canadian part of the Arctic Ocean and higher values adjacent to and in the shelf seas. The low SLW concentrations indicate no or little influence from aeolian dust input. Dissolved Al showed a nutrient-type increase with depth up to 28 nM, but large differences existed between the different deep Arctic basins. The differences in concentrations of Al between water masses and basins could largely be related to the different origins of the water masses. In the SLW and intermediate water layers, Atlantic and Pacific inflows were of importance. Deep shelf convection appeared to influence the Al distribution in the deep Eurasian Basin. The Al distribution of the deep Makarov Basin provides evidence for Eurasian Basin water inflow into the deep Makarov Basin. A strong correlation between Al and Silicon (Si) was observed in all basins. This correlation and the nutrient-like profile indicate a strong biological influence on the cycling and distribution of Al. The biological influence can be direct by the incorporation of Al in biogenic silica, indirect by preferential scavenging of Al onto biogenic siliceous particles, or by a combination of both processes. From the slope of the overall Al–Si relationship in the intermediate water layer (AIDW; ~ 200–2000 m depth), an Al/Si ratio of 2.2 atoms Al per 1000 atoms Si was derived. This ratio is consistent with the range of previously reported Al/Si uptake ratio in biogenic opal frustules of diatoms. In the deepest waters (>2000 m depth) a steeper slope of the Al–Si relationship of 7.4 to 13 atoms Al per 1000 atoms Si likely results from entrainment of cold shelf water into the deep basins, carrying the signal of dissolution of terrigenous particles with a much higher Al:Si ratio of crustal abundance. Only a small enrichment with such crustal Al and Si component may readily account for the higher Al:Si slope in the deepest waters.     

Numerical simulation of sloshing waves in a 3D tank based on a finite element method

The sloshing waves in a three dimensional (3D) tank are analysed using a finite element method based on the fully non-linear wave potential theory. When the tank is undergoing two dimensional (2D) motion, the calculated results are found to be in very good agreement with other published data. Extensive calculation has been made for the tank in 3D motion. As in 2D motion, in addition to normal standing waves, travelling waves and bores are also observed. It is found that high pressures occur in various circumstances, which could have important implications for many engineering designs.     

Nonlinear Effect of Wave Propagation in Shallow Water

—In this paper,a nonlinear model is presented to describe wave transformation in shallow wat-er with the zero-vorticity equation of wave-number vector and energy conservation equation.Thenonlinear effect due to an empirical dispersion relation(by Hedges)is compared with that of Dalrymple＇sdispersion relation.The model is tested against the laboratory measurements for the case of a submergedelliptical shoal on a slope beach,where both refraction and diffraction are significant.The computation re-sults,compared with those obtained through linear dispersion relation.show that the nonlinear effect ofwave transformation in shallow water is important.And the empirical dispersion relation is suitable for re-searching the nonlinearity of wave in shallow water.     

The Optimal Design of TMD for Offshore Structures

This paper presents the optimal design procedure of Tuned Mass Damper(TMD)for re-ducing vibration of an actual steel jacket offshore platform excited by random wave loading.In this study,a frequency domain is taken.The force on the structure is determined by use of the linearized Morisonequation for an input Power Spectral Density(PSD)of wave elevation.The sensitivity of optimum valuesof TMD to characteristic parameters of random wave spectrum is analyzed.An optimized TMD designfor the modeled platform is given based on design conditions and the findings of the study.     

A Probabilistic Model for Fatigue Crack Propagation Analysis

A simple probabilistic model for predicting crack growth behavior under random loading is pre-sented.In the model,the parameters c and m in the Paris-Erdogan Equation are taken as random variables,and their stochastic characteristic values are obtained through fatigue crack propagation tests on an offshorestructural steel under constant amplitude loading.Furthermore,by using the Monte Carlo simulation tech-nique,the fatigue crack propagation life to reach a given crack length is predicted.The tests are conducted toverify the applicability of the theoretical prediction of the fatigue crack propagation.     

Factors governing abundance of hydrolyzable amino acids in the sediments from the N.W. European Continental Margin (47–50°N)

Fifty-six samples representing 6 sediment cores taken along the N.W. European Continental Margin from the shelf, slope and abyssal plain of the Goban Spur and Meriadzek Terrace were quantitatively analysed for total hydrolyzable amino acids (THAA) and clay minerals. In descending order, the five most abundant amino acids making up more than 70% of the total were: aspartic acid, glycine, serine, alanine and glutamic acid. Clay mineral proportions were typical for the N.E. Atlantic, in order of descending abundance: illite, kaolinite, chlorite, smectite and mixed layers.The Meriadzek Terrace area is characterised by fine grain suspension sedimentation with a low pelagic carbonate input and the lowest content of THAA. In contrast, the Goban Spur transect is characterised by much higher carbonate inputs and more vigorous hydrodynamics as judged from granulometry and the high abundance of minerals of shelf and continental origin and a generally higher THAA content. The pelagic portion of THAA deposited at the sea floor is more readily mineralised during early diagenesis than the more ‘refractory', clay mineral-associated continental portion. Along this margin the average mineralization of THAA down to 25 cm in the sediment is about 54%. There is a significant affinity between chlorites and amino acids which we suggest may involve the formation of ionic bonds between the octahedral layers of the clay and the amino acids.