Comparison of Organic Matter from Upper Jurassic Oil Shale of the East European Platform and the Bazhenov Formation by Molecular and Isotopic Data

The molecular and isotopic composition of an extract from the rocks of the Bazhenov Formation in the southeast part of Western Siberia, oils that are genetically related to this formation, and products of hydrous pyrolysis of the organic matter of oil shale (Middle Volgian) of the East European Platform were studied. Common features and differences in their molecular composition were shown. The carbon isotope composition for C₁₄–C₃₀n-alkanes was determined for the first time; a negative isotope anomaly was revealed for C₂₆n-alkane in all samples studied. It was concluded that in spite of the geographical distance, specific biota was revealed in the Volga Basin. This biota conditioned an isotopic indicator, which is genetically significant.     

Long-Term Geochemical Monitoring of the Source of the Angara River (Runoff from Lake Baikal)

The long-term data (1950–2017) on the chemical composition of the water from the source of the Angara River, which is the only run-off from Lake Baikal, a large and clean fresh water reservoir, are presented. The absence of water contamination despite the anthropogenic influence is shown. The similarity and constancy of the current composition of the waters in the lake and the Angara River are recorded. It is recommended to continue geochemical studies of this unique world heritage site.     

Occurrence Forms of Carbon,Sulfur, and Noble Metals in Deposits of the Black-Shale Formation by the Example of the Degdekan Gold-Ore Deposit (Northeastern Russia)

Pyrite crystals and ore-bearing shales of the Degdekan deposit were studied by means of XPS, SEM–EDX, EPMA, and AAS. Five peaks of carbon organic forms were identified, conforming to polymer compounds containing either double bonds of carbon or alkyne groups and compounds containing C–OH and C=O bonds, as well as, probably, small amounts of S-containing compounds and those with functional groups of carboxylic acids. Sulfate prevails over sulfite in pyrites; among the surface sulfide forms, disulfide prevails over monosulfide; the presence of polysulfide is registered. The occurrence of various chemical forms of sulfur on the surface might provide for concentrating of microelements including the noble metals (NMs) in their surface-bound forms. The regular behavior of NMs (Au, Pt, Pd, and Ru) depending on the grain sizes (specific surfaces) of pyrite crystals along with the narrow range of the ratios of structural and surface components of the concentrations of different NMs points to NM coprecipitation with pyrite during the same productive stage. No capture of NM-containing carbonaceous phases took place, which should violate the regularity of Au distribution in pyrites of the Sukhoi Log deposit.     

The Hirnantian δ<Superscript>13</Superscript>C Positive Excursion in the Nabiullino Section (South Urals)

The upper Sandbian, Katian, and Hirnantian complexes of conodonts in the upper Ordovician section of the western slope of the Southern Urals near the village of Nabiullino were studied. The δ¹³C positive excursion with a maximum of 3.3‰ associated with the global Hirnantian isotopic event, HICE, was fixed for the first time. This excursion shows the beginning of the Hirnantian stage in the terrigenous–carbonate section of the upper Ordovician in the Southern Urals. It coincides with the first occurrence of the Hirnantian conodont species of Gamachignathus ensifer and the conodonts of shallow-water biophacies, Aphelognathus-Ozarkodina, reflecting the global glacio-eustatic event.     

Sapphirine-Bearing Ultrahigh-Temperature Granulites of the Anabar Shield: Chemical Composition,U–Pb Zircon Ages,and <Emphasis Type="Italic">P</Emphasis>–<Emphasis Type="Italic">T</Emphasis> Conditions of Metamorphism

The results of thermobarometry yielded the P–T parameters of formation and evolution of sapphirine- bearing granulites in the Anabar shield with peak values of UHT metamorphism in the range of T = 920–1000°C at P = 9–11 kbar. Isotope–geochronological data indicate a polymetamorphic evolution of these rocks. Detrital zircon cores in the center of crystals yielded ages of 3.36, 2.75, 2.6, and 2.5 Ga. Later, superimposed metamorphic transformations of the detrital zircon formed rims dated to 2.4, 2.3, 2.2, and 1.83 Ga. A potential provenance source of the detrital zircons could be hypersthene plagiogneisses and metabasics of the Daldyn Group with a premetamorphic age no less than 3.32 Ga and products of their metamorphism of about 2.7 Ga old.     

<Superscript>230</Superscript>Th/U Chronology and Geochemistry of Irinovskoe Hydrothermal Field (Mid-Atlantic Ridge)

The results of ²³⁰Th/U dating and mineralogical–geochemical studies of sulfide ores from the Irinovskoe hydrothermal field and the Severo-Zapadnoe ore occurrence (Mid-Atlantic Ridge) are presented. Sulfides are represented primarily by copper–sulfide ores with 12–30% Cu content; sulfur- and zinc-sulfide ores are distributed less frequently. The analysis of a change in the composition of sulfides over time has made it possible to identify three stages of formation. Each stage assumes that mineral associations are changed from high-temperature (sulfur and copper sulfide) to medium temperature (Zn–Cu and Zn-sulfide) sulfide ores. The whole age range of formation of the hydrothermal deposits falls within the time interval of about 58000–8000 for the Irinovskoe field and 69000–11000 years ago for the Severo-Zapadnoe ore occurrence.     

Arcanite from Fumarole Exhalations of the Tolbachik Volcano (Kamchatka,Russia) and Its Crystal Structure

The crystal structure (R = 0.0194) of arcanite β-K₂SO₄ was studied on a single crystal from exhalations of the Arsenatnaya fumarole, Tolbachik Volcano (Kamchatka, Russia). The mineral crystallizes at a temperature of ≥350–430°C and associates with langbeinite, aphthitalite, hematite, tenorite, johillerite, and others. Arcanite is orthorhombic, Pnma, a = 7.4763(2) Å, b = 5.77262(16) Å, c = 10.0630(3) Å, V = 434.30(2) ų, Z = 4. Its structure contains isolated SO₄ tetrahedra, whereas K cations center ten- and nine-fold polyhedra.     

Middle–Late Paleozoic Duplex Rifting of the Barents Continental Margin and the Role Played in Formation of the East Barents Megabasin

Based on analysis and interpretation of seismic and other geological-geophysical data, duplex rifting is identified in the Paleozoic evolution of the South Barents Basin. Its first, pre–Late Devonian, phase was manifested on the southeastern side zone that limited the Pechora Plate structures. After a certain pause, a second, pre–Late Carboniferous phase involved the western Barents Sea region, including the slope of the Central Barents Rise and the western South Barents Basin. Thus, Late Paleozoic riftogenic structures in the western and southeastern South Barents Basin formed at different times. All this caused an asymmetric structure profile and asynchronicity of evolution of the rift system sides. In the Mesozoic, under the effect of formation of the Novaya Zemlya fold-and-thrust structure, the asymmetry of the riftogenic trough became even more contrasting.     

Main Stages of Evolution of Pacific Ferromanganese Stromatolites and Oncolites

As exemplified by cobalt–bearing Fe–Mn crusts (ferromanganese stromatolite) of the Magellan Seamounts (Clarion–Clipperton Province), the main stages of the structural evolution of bacterial communities have been recognized. It has been demonstrated that the change of the stages is caused by the effect of major tectonic, volcanic, and other geological events.