Defining the Potential of Nanoscale Re‐Os Isotope Systematics Using Atom Probe Microscopy

Atom probe microscopy (APM) is a relatively new in situ tool for measuring isotope fractions from nanoscale volumes (< 0.01 μm³). We calculate the theoretical detectable difference of an isotope ratio measurement result from APM using counting statistics of a hypothetical data set to be ± 4δ or 0.4% (2s). However, challenges associated with APM measurements (e.g., peak ranging, hydride formation and isobaric interferences), result in larger uncertainties if not properly accounted for. We evaluate these factors for Re‐Os isotope ratio measurements by comparing APM and negative thermal ionisation mass spectrometry (N‐TIMS) measurement results of pure Os, pure Re, and two synthetic Re‐Os‐bearing alloys from Schwander et al. (2015, Meteoritics and Planetary Science, 50, 893) [the original metal alloy (HSE) and alloys produced by heating HSE within silicate liquid (SYN)]. From this, we propose a current best practice for APM Re‐Os isotope ratio measurements. Using this refined approach, mean APM and N‐TIMS ¹⁸⁷Os/¹⁸⁹Os measurement results agree within 0.05% and 2s (pure Os), 0.6–2% and 2s (SYN) and 5–10% (HSE). The good agreement of N‐TIMS and APM ¹⁸⁷Os/¹⁸⁹Os measurements confirms that APM can extract robust isotope ratios. Therefore, this approach permits nanoscale isotope measurements of Os‐bearing alloys using the Re‐Os geochronometer that could not be measured by conventional measurement principles.     

The Nordic geological surveys： Geology for society in practice

Since the mid-nineteenth century., when the first of the Nordic Geological Surveys were established, they have generated a substantial amount of information on the Earth＇s crust, its natural resources, its processes, and on the geological history of Nordic areas. The collective mission of the geological surveys is to carry out ＂Geology for Society＂, by doing research and providing services, and by making geological information and data easily accessible to all the varied end users in industry, government agencies, government institutes, public administrations, technical offices, academia and research institutes, as well as for private individuals. The present paper gives a brief overview of a few, selected, research areas and projects currently undertaken by the Nordic geological surveys. These serve as practical examples of how the Nordic geological surveys address important societal problems and challenges that require geological input for their solution.     

Exurbia from the bottom-up: Confronting empirical challenges to characterizing a complex system

We describe empirical results from a multi-disciplinary project that support modeling complex processes of land-use and land-cover change in exurban parts of Southeastern Michigan. Based on two different conceptual models, one describing the evolution of urban form as a consequence of residential preferences and the other describing land-cover changes in an exurban township as a consequence of residential preferences, local policies, and a diversity of development types, we describe a variety of empirical data collected to support the mechanisms that we encoded in computational agent-based models. We used multiple methods, including social surveys, remote sensing, and statistical analysis of spatial data, to collect data that could be used to validate the structure of our models, calibrate their specific parameters, and evaluate their output. The data were used to investigate this system in the context of several themes from complexity science, including have (a) macro-level patterns; (b) autonomous decision making entities (i.e., agents); (c) heterogeneity among those entities; (d) social and spatial interactions that operate across multiple scales and (e) nonlinear feedback mechanisms. The results point to the importance of collecting data on agents and their interactions when producing agent-based models, the general validity of our conceptual models, and some changes that we needed to make to these models following data analysis. The calibrated models have been and are being used to evaluate landscape dynamics and the effects of various policy interventions on urban land-cover patterns.     

Concentrations,physico-chemical states and mean residence times of 210Pb and 210Po in marine and estuarine waters

The concentrations and physico-chemical states of ²¹⁰Pb have been measured in Bikini Atoll and Washington State coastal waters, and ²¹⁰Po in Washington coastal waters. Lead-210 concentrations of 113–133 dpm · m^?3 were found in surface water collections near Bikini Atoll and 29–153 dpm · m^?3 in Bikini Lagoon. The concentrations of ²¹⁰Pb in near Bikini and in Washington State waters increased with depth in the upper 150m at a rate of 0.35–0.45dpm·m^?3 · m^?1. In the North Equatorial Current waters near Bikini Atoll ²¹⁰Pb was found associated predominantly with the soluble (colloidal) fraction, but in Washington coastal waters ²¹⁰Pb and ²¹⁰Po were found associated with the paniculate (> 0.3 μm) fraction. The mean residence times of ²¹⁰Pb, calculated from the atmospheric input to marine waters from precipitation and the concentrations measured in surface water, were consistent with the physico-chemical states of ²¹⁰Pb found in samples collected in deep ocean and coastal waters. Approximate values of the mean residence times were calculated, for the upper 50 m, to be as follows: 58 days in the Strait of Juan de Fuca, 128 days at the 5-mile (8 km) station off Cape Flattery (Washington), 163 days at the 12-mile (19 km) station off Cape Flattery, and 2.6 yr near Bikini Atoll. It appears that ²¹⁰Pb and ²¹⁰Po can be used to trace particle removal rates in the upper layers of marine waters.     

A procedure for evaluating seismic energy demand of framed structures

Energy serves as an alternative index to response quantities like force or displacement to include the duration‐related seismic damage effect. A procedure to evaluate the absorbed energy in a multistorey frame from energy spectra was developed. For low‐ to medium‐rise frames, it required a static pushover analysis of the structure to determine the modal yield force and ductility factor of an equivalent single‐degree‐of‐freedom system for the first two modes. The energy spectra were then used to determine the energy contribution of each mode. A procedure was also developed to distribute the energy along the frame height based on energy shapes. This study showed that the second‐mode response in some cases needs to be considered to reflect the energy (or damage) concentration in the upper floors. Copyright © 2002 John Wiley & Sons, Ltd.     

Geology and impact features of Vargeão Dome,southern Brazil

Abstract– Vargeão Dome (southern Brazil) is a circular feature formed in lava flows of the Lower Cretaceous Serra Geral Formation and in sandstones of the Paraná Basin. Even though its impact origin was already proposed in the 1980s, little information about its geological and impact features is available in the literature. The structure has a rim‐rim diameter of approximately 12 km and comprises several ring‐like concentric features with multiple concentric lineaments. The presence of a central uplift is suggested by the occurrence of deformed sandstone strata of the Botucatu and Pirambóia formations. We present the morphological/structural characteristics of Vargeão Dome, characterize the different rock types that occur in its interior, mainly brecciated volcanic rocks (BVR) of the Serra Geral Formation, and discuss the deformation and shock features in the volcanic rocks and in sandstones. These features comprise shatter cones in sandstone and basalt, as well as planar microstructures in quartz. A geochemical comparison of the target rock equivalents from outside the structure with the shocked rocks from its interior shows that both the BVRs and the brecciated sandstone have a composition largely similar to that of the corresponding unshocked lithologies. No traces of meteoritic material have been found so far. The results confirm the impact origin of Vargeão Dome, making it one of the largest among the rare impact craters in basaltic targets known on Earth.     

Initial results and progress of the Mississippi delta sediment pore water pressure experiment

Abstract

This report describes the instrumentation, initial results, and progress of an experiment designed to measure and monitor submarine sediment pore water and hydrostatic pressures in a selected area of the Mississippi Delta. The experiment also is intended to monitor significant pressure perturbations during active storm periods. Initial analysis of the data revealed excess pore water pressures in the silty clay sediment at selected depths below the mudline. Continuous monitoring of the pore water and hydrostatic pressures was expected to reveal important information regarding sediment pore water pressure variations as a function of the geological processes active in the Mississippi Delta.     

Flood‐based analysis of high‐magnitude sediment transport using a non‐parametric method

Upland erosion and the resulting reservoir siltation is a serious issue in the Isábena catchment (445 km² Central Spanish Pyrenees). During a three‐month period, water and sediment fluxes have been monitored at the catchment outlet (Capella), two adjacent subcatchments (Villacarli, 41 km²; Cabecera, 145 km²) and the elementary badland catchment Torrelaribera (8 ha). This paper presents the results of the monitoring, a method for the calculation of a sedigraph from intermittent measurements and the derived sediment yields at the monitored locations. The observed suspended sediment concentrations (SSCs) demonstrate the role of badlands as sediment sources: SSCs of up to 280 g l^?1 were encountered for Villacarli, which includes large badland areas. SSCs at the Cabecera catchment, with great areas of woodland, barely exceeded 30 g l^?1. SSCs directly at the sediment source (Torrelaribera) were comparable to those at Villacarli, suggesting a close connection within this subcatchment. At Capella, SSCs of up to 99 g l^?1 were observed. For all sites, SSC displayed only a loose correlation with discharge, inhibiting the application of a simple sediment rating curve. Instead, ancillary variables acting as driving forces or proxies for the processes (rainfall energy, cumulative discharge, rising/falling limb data) were included in a quantile regression forest model to explain the variability in SSC. The variables with most predictive power vary between the sites, suggesting the predominance of different processes. The subsequent flood‐based calculation of sediment yields attests high specific sediment yields for Torrelaribera and Villacarli (6277 and 1971 t km^?2) and medium to high yields for Cabecera and Capella (139 and 410 t km^?2) during the observation period. In all catchments, most of the sediment was exported during intense storms of late summer. Later flood events yield successively less sediment. Relating upland sediment production to yield at the outlet suggests considerable effects of sediment storage within the river channel. Copyright © 2008 John Wiley & Sons, Ltd.     

Chemical abundances determined from meteor spectra: I. Ratios of the main chemical elements

Abstract— Relative chemical abundances of 13 meteoroids were determined by averaging the composition of the radiating gas along the fireball path that originated during their penetration into the Earth's atmosphere. Mg, Fe, Ni, Cr, Mn, and Co abundances, relative to Si, are similar to those reported for CI and CM carbonaceous chondrites and interplanetary dust particles. In contrast, relative abundances of Ca and Ti in meteor spectra indicate that these elements suffer incomplete evaporation processes. The chemical composition of all meteoroids studied in this work differs from that of 1P/Halley dust.