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991.
The incorporation of OH defects in quartz from the systems quartz–water, quartz–albite–water and granite–water at pressures between 5 and 25?kbar and temperatures between 800 and 1,000?°C was investigated by IR spectroscopy. The two most important OH absorption features can be assigned to hydrogarnet defects (absorption band at 3,585?cm?1) and coupled substitutions involving Al3+ (Al–H defects, absorption bands at 3,310, 3,378 and 3,430?cm?1). Al incorporation in quartz is controlled by mineral/melt partitioning (D Al Qz/Melt ?=?0.01) and exhibits a negative pressure dependence. This trend is not clearly reflected by the concentration of Al–H defects, which shows positive deviations from the theoretical 1:1 correlation of Al/H for some samples. In contrast to the Al–H defects, formation of hydrogarnet defects appears to be positively correlated to pressure and water activity, and may be used a petrological indicator. The overall water concentration exhibits only minor changes with pressure and temperature, but a clear correlation of water activity (controlled by various amounts of dissolved salts) and hydrogarnet substitution could be established. 相似文献
992.
The legacy of crystal-plastic deformation in olivine: high-diffusivity pathways during serpentinization 总被引:1,自引:1,他引:0
Oliver Plümper Helen E. King Christian Vollmer Quentin Ramasse Haemyeong Jung Håkon Austrheim 《Contributions to Mineralogy and Petrology》2012,163(4):701-724
Crystal-plastic olivine deformation to produce subgrain boundaries composed of edge dislocations is an inevitable consequence
of asthenospheric mantle flow. Although crystal-plastic deformation and serpentinization are spatio-temporally decoupled,
we identified compositional readjustments expressed on the micrometric level as a striped Fe-enriched (
[`(X)]\textFe \bar{X}_{\text{Fe}} = 0.24 ± 0.02 (zones); 0.12 ± 0.02 (bulk)) or Fe-depleted (
[`(X)]\textFe \bar{X}_{\text{Fe}} = 0.10 ± 0.01 (zones); 0.13 ± 0.01 (bulk)) zoning in partly serpentinized olivine grains from two upper mantle sections in
Norway. Focused ion beam sample preparation combined with transmission electron microscopy (TEM) and aberration-corrected
scanning TEM, enabling atomic-level resolved electron energy-loss spectroscopic line profiling, reveals that every zone is
immediately associated with a subgrain boundary. We infer that the zonings are a result of the environmental Fe2+Mg−1 exchange potential during antigorite serpentinization of olivine and the drive toward element exchange equilibrium. This
is facilitated by enhanced solid-state diffusion along subgrain boundaries in a system, which otherwise re-equilibrates via
dissolution-reprecipitation. Fe enrichment or depletion is controlled by the silica activity imposed on the system by the
local olivine/orthopyroxene mass ratio, temperature and the effect of magnetite stability. The Fe-Mg exchange coefficients
K\textD\textAtg/\textOl K_{\text{D}}^{{{\text{Atg}}/{\text{Ol}}}} between both types of zoning and antigorite display coalescence toward exchange equilibrium. With both types of zoning, Mn
is enriched and Ni depleted compared with the unaffected bulk composition. Nanometer-sized, heterogeneously distributed antigorite
precipitates along olivine subgrain boundaries suggest that water was able to ingress along them. Crystallographic orientation
relationships gained via electron backscatter diffraction between olivine grain domains and different serpentine vein generations
support the hypothesis that serpentinization was initiated along olivine subgrain boundaries. 相似文献
993.
Muthuvairavasamy Ramkumar Matthias Alberti Franz T. Fürsich Dhirendra Kumar Pandey 《Chemie der Erde / Geochemistry》2012,72(2):141-148
The Upper Callovian-Oxfordian strata of the Kachchh Basin, western India, record three positive excursions of phosphorus. They have been documented in three sections of the Chari Formation from different parts of the basin. Corroboration of field and petrographic data with trends of major and trace elemental data and elemental ratios of the strata revealed that these excursions were coeval with reduced chemical weathering in the source area and significant reduction of siliciclastic influx to the depositional sites. The study also revealed the intrabasinal source of P, and minor sea-level fluctuations and resultant episodic sediment recycling as the causative factors. Considering the geographic locations of the three sections, the phosphorus anomalies seem to be controlled by a regional and/or basin-scale process, if not linked with global signals. Temporal resolution of these anomalies suggests that the processes were episodic and related to short term climate/relative sea-level cycles, the durations of which could be unraveled with high-resolution biostratigraphic data. 相似文献
994.
Pharmaceuticals as indictors of sewage-influenced groundwater 总被引:1,自引:0,他引:1
Beate Müller Traugott Scheytt Martin Asbrand Andrea Mross de Casas 《Hydrogeology Journal》2012,20(6):1117-1129
A set of human pharmaceuticals enables identification of groundwater that is influenced by sewage and provides information on the time of recharge. As the consumption rates of the investigated pharmaceuticals have changed over time, so too has the composition of the sewage. At the study area, south of Berlin (Germany), irrigation was performed as a method of wastewater clean-up at sewage irrigation farms until the early 1990s. Today, treated wastewater is discharged into the surface-water-stream Nuthegraben. Groundwater and surface-water samples were analyzed for the pharmaceutical substances clofibric acid, bezafibrate, diclofenac, carbamazepine and primidone, the main ions and organic carbon. The pharmaceutical substances were detected at concentrations up to microgram-per-liter level in groundwater and surface-water samples from the Nuthegraben Lowland area and from the former irrigation farms. Concentrations detected in groundwater are generally much lower than in surface water and there is significant variation in the distribution of pharmaceutical concentrations in groundwater. Groundwater influenced by the irrigation of sewage water shows higher primidone and clofibric-acid concentrations. Groundwater influenced by recent discharge of treated sewage water into the surface water shows high carbamazepine concentrations while concentrations of primidone and clofibric acid are low. 相似文献
995.
W. Siebel C. K. Shang E. Thern M. Dani?ík J. Rohrmüller 《International Journal of Earth Sciences》2012,101(8):2105-2123
Correct interpretation of zircon ages from high-grade metamorphic terrains poses a major challenge because of the differential response of the U–Pb system to metamorphism, and many aspects like pressure–temperature conditions, metamorphic mineral transformations and textural properties of the zircon crystals have to be explored. A large (c. 450?km2) coherent migmatite complex was recently discovered in the Bohemian Massif, Central European Variscides. Rocks from this complex are characterized by granulite- and amphibolite-facies mineral assemblages and, based on compositional and isotopic trends, are identified as the remnants of a magma body derived from mixing between tonalite and supracrustal rocks. Zircon crystals from the migmatites are exclusively large (200–400?μm) and yield 207Pb/206Pb evaporation ages between 342–328?Ma and single-grain zircon fractions analysed by U–Pb ID-TIMS method plot along the concordia curve between 342 and 325?Ma. High-resolution U–Pb SHRIMP analyses substantiate the existence of a resolvable age variability and yield older 206Pb/238U ages (342–330?Ma, weighted mean age?=?333.6?±?3.1?Ma) for inner zone domains without relict cores and younger 206Pb/238U ages (333–320?Ma, weighted mean age?=?326.0?±?2.8?Ma) for rim domains. Pre-metamorphic cores were identified only in one sample (206Pb/238U ages at 375.0?±?3.9, 420.3?±?4.4 and 426.2?±?4.4?Ma). Most zircon ages bracket the time span between granulite-facies metamorphism in the Bohemian Massif (~345?Ma) and the late-Variscan anatectic overprint (Bavarian phase, ~325?Ma). It is argued that pre-existing zircon was variously affected by these metamorphic events and that primary magmatic growth zones were replaced by secondary textures as a result of diffusion reaction processes and replacement of zircon by dissolution and recrystallization followed by new zircon rim growth. Collectively, the results show that the zircons equilibrated during high-grade metamorphism and record partial loss of radiogenic Pb during post-peak granulite events and new growth under subsequent anatectic conditions. 相似文献
996.
Cüneyt Akal Osman Candan O. Ersin Koralay Roland Oberhänsli Fukun Chen Dejan Prelević 《International Journal of Earth Sciences》2012,101(1):177-194
Afyon Zone, which was derived from the Anatolide–Tauride platform during closure of the Neo-Tethys, is made up of pre-Mesozoic
basement and unconformably overlying Triassic–Early Tertiary cover series. The Afyon Zone contains widespread metavolcanic
rocks, which are dominated by rhyolite, dacite, and trachyandesite. They form a distinct volcanic succession, which is separated
from the underlying Silurian–Lower Carboniferous metacarbonates and meta-siliciclastics by a regional unconformity. Trachyandesitic
metavolcanics are made up of massive lava flows, pyroclastics and epiclastics, less frequently, domes and dikes, which were
developed on a deeply eroded subaerial landmass. U/Pb and Pb/Pb zircon geochronology yielded Lower Triassic (~250 Ma) ages,
which are interpreted as extrusion age of trachyandesitic volcanics. Based on the stratigraphic, geochronological, and geochemical
data, we suggest that these Lower Triassic magmatic rocks represent an extensional tectonic setting on the northern active
margin of the Gondwana, which led to the development of the northern branch of the Neo-Tethys. 相似文献
997.
998.
Integrated Water Resources Management under different hydrological,climatic and socio-economic conditions 总被引:2,自引:2,他引:0
999.
GIS-based landslide susceptibility mapping using bivariate statistical analysis in Devrek (Zonguldak-Turkey) 总被引:15,自引:10,他引:5
Devrek town with increasing population is located in a hillslope area where some landslides exist. Therefore, landslide susceptibility
map of the area is required. The purpose of this study was to generate a landslide susceptibility map using a bivariate statistical
index and evaluate and compare the results of the statistical analysis conducted with three different approaches in seed cell
concept resulting in different data sets in Geographical Information Systems (GIS) based landslide susceptibility mapping
applied to the Devrek region. The data sets are created from the seed cells of (a) crowns and flanks, (b) only crowns, and
(c) only flanks of the landslides by using ten different causative parameters of the study area. To increase the data dependency
of the analysis, all parameter maps are classified into equal frequency classes based directly on the percentile divisions
of each corresponding seed cell data set. The resultant maps of the landslide susceptibility analysis indicate that all data
sets produce fairly acceptable results. In each data set analysis, elevation, lithology, slope, aspect, and drainage density
parameters are found to be the most contributing factors in landslide occurrences. The results of the three data sets are
compared using Seed Cell Area Indexes (SCAI). This comparison shows that the crown data set produces the most accurate and
successful landslide susceptibility map of the study area. 相似文献
1000.
Simulation of DNAPL infiltration and spreading behaviour in the saturated zone at varying flow velocities and alternating subsurface geometries 总被引:3,自引:1,他引:2
Katharina Erning Sibylle Grandel Andreas Dahmke Dirk Schäfer 《Environmental Earth Sciences》2012,65(4):1119-1131
The influence of varying groundwater flow velocities on DNAPL infiltration and spreading behaviour was investigated by multiphase
modelling using TMVOC and PetraSim. The multiphase models were calibrated by results of previously conducted laboratory experiments
for the complete spatio-temporal range of the experiments. The small scale 2D scenario modelling was applied to qualify and
quantify changes in position, architecture, geometry and dissolution of a TCE body in a fully saturated homogeneous sandy
medium. The applied flow velocities ranging from 0.05 up to 40.00 m/day exhibited that the DNAPL TCE is affected even at the
lowest flow velocity in its position, its size and its architecture. Additionally, several impermeable lenses with simple
geometry were assumed in the model, to investigate the influence of stratified subsoil. In the experimental set-ups, the DNAPL
body reacts more sensitive to the applied groundwater flow velocities than to the geometrical set-up of the scenarios. A possible
consequence can be the transportation and displacement of a DNAPL pool due to natural or anthropogenic induced high groundwater
flow velocities, as by Pump and Treat facilities, complicating site investigation process and planning of remediation activities. 相似文献