Constraining water age dynamics in a south-eastern Australian catchment using an age-ranked storage and stable isotope approach

Improving our knowledge of the travel times of water through catchments is critical for the management and protection of water resources and to improve our understanding of fundamental catchment behaviour. In this study we use the age-ranked storage framework StorAge Selection (SAS) to investigate travel times in the Corin catchment, a headwater catchment in the south-east of Australia covered by native Eucalyptus species. Few studies have applied the SAS framework globally and in energy-intensive areas where catchment losses are heavily in favour of evapotranspiration relative to streamflow. A combination of observed and modelled values of oxygen-18 (δ¹⁸O ), the stable isotope in water, are used to constrain storage selection preferences of streamflow and evapotranspiration and the size of the catchment active storage. The highest performing parameter combinations that could reproduce δ¹⁸O in streamflow were dependent on a strong preference for young water in evapotranspiration, and a mixture of weak young and old water preference in streamflow. The mean travel time of streamflow over the study period 2007–2019, weighted by the flow rate, is limited to within a probable range of 2.81–9.77 years. The size of the active storage, a key parameter in the SAS framework, was poorly identified, and in combination with the isotopic inputs into the model, contributed to the uncertainty of the results. We discuss the implications of the results with respect to the study area, as well as within the context of SAS research globally and identify ways to improve the modelling process.     

Why the <Emphasis Type="Italic">Euler</Emphasis> scheme in particle tracking is not enough: the shallow-sea pycnocline test case

During the last decades, the Euler scheme was the common “workhorse” in particle tracking, although it is the lowest-order approximation of the underlying stochastic differential equation. To convince the modelling community of the need for better methods, we have constructed a new test case that will show the shortcomings of the Euler scheme. We use an idealised shallow-water diffusivity profile that mimics the presence of a sharp pycnocline and thus a quasi-impermeable barrier to vertical diffusion. In this context, we study the transport of passive particles with or without negative buoyancy. A semi-analytic solutions is used to assess the performance of various numerical particle-tracking schemes (first- and second-order accuracy), to treat the variations in the diffusivity profile properly. We show that the commonly used Euler scheme exhibits a poor performance and that widely used particle-tracking codes shall be updated to either the Milstein scheme or second-order schemes. It is further seen that the order of convergence is not the only relevant factor, the absolute value of the error also is.     

Contrasting biogeomorphic processes affecting salt‐marsh development of the Mokbaai,Texel, The Netherlands

The growth and decline of salt marshes may be the result of various interacting biogeomorphic processes and external factors. We present a case study of the Mokbaai on the Wadden island of Texel, where we assess the relative importance and the interaction between the biogeomorphic processes and various disturbances. We analysed changes in vegetation composition in the salt marsh and sedimentation–erosion patterns of the adjoining intertidal flat over a 30‐year period. Vegetation underwent regression in the lower parts of the marsh, i.e. the low marsh zone changed into pioneer zone. Comparing elevation measurements from 2013 and 1983 showed that the adjoining intertidal flats eroded 15–25 cm. Maintenance dredging of a nearby harbour might negatively impact the sediment balance indicating that the regression of the lower parts of the salt marsh is caused by a lack of sediment. Simultaneously, a change in the local hydrology led to vegetation succession into high and brackish salt marsh, increased organic sediment production and consequently cliff formation. The results from this case study show that, even in a relatively small salt marsh, changes in external factors may set in motion a series of biogeomorphic processes and feedbacks, leading to locally contrasting trends in spatiotemporal development. © 2016 The Authors. Earth Surface Processes and Landforms Published by John Wiley & Sons Ltd.     

An integrated field and numerical modelling study of controls on Late Quaternary fluvial landscape development (Tabernas,southeast Spain)

The variability of Quaternary landforms preserved in the Tabernas basin of southeast (SE) Spain raises numerous questions concerning the roles of external forcing mechanisms (e.g. tectonics and/or climate) and internal landscape properties (e.g. lithological controls) in the evolution of the basin‐wide fluvial system over Late Quaternary timescales. In this study, we apply the FLUVER2 numerical model to investigate the significance of these landscape controls upon patterns of landscape evolution. We highlight the complications of generating realistic input datasets for use in the modelling of long‐term landscape evolution (e.g. discharge and runoff datasets). Model outputs are compared to extensive field mapping of fluvial terraces, their sedimentary architecture and optically stimulated luminescence dating results of the terraces. The results demonstrate the significance of non‐linear rates of flexural tectonic uplift towards the west of the Tabernas Basin which have controlled base levels throughout the Quaternary and promoted the formation of a series of diverging fluvial terraces. Our numerical model results further highlight the importance of climate cycles upon river terrace formation. Basin‐wide aggradation events were modelled during the transition from Marine Isotope Stage (MIS) 6 to 5 and the Last Glacial Maximum (LGM) as supported by field evidence. This aggradational pattern supports the regional hypothesis of terrace formation during global glacial cycles and cold‐to‐warm stage transitions and supports the use of sea surface temperature climate proxy data in the modelling exercise. The availability of sediments derived from the surrounding hillslopes and adjacent alluvial fans explains the generation of substantial terrace aggradations. Copyright © 2015 John Wiley & Sons, Ltd.     

Global and hemispheric temperature reconstruction from glacier length fluctuations

Temperature reconstructions for recent centuries provide a historical context for the warming over the twentieth century. We reconstruct annual averaged surface temperatures of the past 400?years on hemispherical and global scale from glacier length fluctuations. We use the glacier length records of 308 glaciers. The reconstruction is a temperature proxy with decadal resolution that is completely independent of other temperature records. Temperatures are derived from glacier length changes using a linear response equation and an analytical glacier model that is calibrated on numerical model results. The global and hemispherical temperatures reconstructed from glacier length fluctuations are in good agreement with the instrumental record of the last century. Furthermore our results agree with existing multi-proxy reconstructions of temperature in the pre-instrumental period. The temperature record obtained from glacier fluctuations confirms the pronounced warming of the twentieth century, giving a global cumulative warming of 0.94?±?0.31?K over the period 1830–2000 and a cumulative warming of 0.84?±?0.35?K over the period 1600–2000.     

A surface structural model for ferrihydrite II: Adsorption of uranyl and carbonate

The adsorption of uranyl (UO₂²⁺) on ferrihydrite has been evaluated with the charge distribution (CD) model for systems covering a very large range of conditions, i.e. pH, ionic strength, CO₂ pressure, U(VI) concentration, and loading. Modeling suggests that uranyl forms bidentate inner sphere complexes at sites that do not react chemically with carbonate ions. Uranyl is bound by singly-coordinated surface groups present at particular edges of Fe-octahedra of ferrihydrite while another set of singly-coordinated surface groups may form double-corner bidentate complexes with carbonate ions. The uranyl surface speciation strongly changes in the presence of carbonate due to the specific adsorption of carbonate ions as well as the formation of ternary uranyl-carbonate surface complexes. Data analysis with the CD model suggests that a uranyl tris-carbonato surface complex, i.e. (UO₂)(CO₃)₃⁴⁻, is formed. This species is most abundant in systems with a high pH and carbonate concentration. This finding differs significantly from previous interpretations made in the literature. At high pH and low carbonate concentrations, as can be prepared in CO₂-closed systems, the model suggests the additional presence of a ternary uranyl-monocarbonato complex. The binding mode (type A or type B complex) is uncertain. At high uranyl concentrations, uranyl polymerizes at the surface of ferrihydrite giving, for instance, tris-uranyl surface complexes with and without carbonate. The similarities and differences between U(VI) adsorption by goethite and ferrihydrite are discussed from a surface structural point of view.     

On the chemical composition of anorthoclase from Mt. Kibo/Kilimanjaro (Tanzania)

The chemical composition of anorthoclase from Mt. Kibo has been studied by means of microprobe, X-ray fluorescence and optical emission analysis. The preparation technique for X-ray fluorescence analysis is shortly described.

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Zusammenfassung Neue Mikrosonden-, Röntgenfluorescenz- und Emissionsspektraldaten von Anorthoklas aus den Khombenporphyren des Kilimandscharo werden mit den klassischen Analysen von Fletcher und Hyland (1887/88) verglichen und ein Präparationsverfahren zur RF-Analyse kurz beschrieben.