On the oxidation and burial of organic carbon in sediments of the Iberian margin and Nazaré Canyon (NE Atlantic)

As a contribution to the EC-OMEX-II program, sediment carbon and nitrogen budgets are presented for the Iberian Margin (northeastern Atlantic). The budgets for degradable organic carbon and associated nitrogen were calculated from sediment and pore water properties, using a steady-state version of a numerical coupled diagenetic model, OMEXDIA. Data were collected throughout the major upwelling period along five transects, four of which were located on the open margin and one positioned in a major submarine canyon, the Nazaré Canyon.A comparison of in situ oxygen profiles measured with monocathodic microelectrodes and with Clark type microelectrodes showed that monocathodic electrodes overestimate the oxygen concentration gradient near the sediment–water interface. This artifact probably results from the loss in sensitivity of the monocathodic microelectrode during profiling. Shipboard time course measurements with Clark type electrodes demonstrated transient conditions upon sediment retrieval on deck and indicated enhanced rates of oxygen consumption in the surface sediment, presumably as a result of lysis or exudation of oxidisable substrates by infauna. As a result, oxygen fluxes calculated from shipboard oxygen profiles overestimated in situ fluxes by up to a factor of 5 for water depths >1000 m.The sediments from the canyon and from a depositional area on the shelf were enriched in organic carbon (3–4.5 wt%) relative to the open margin stations (0.5–2 wt%) and showed C/N ratios exceeding Redfield stoichiometry for marine organic matter, indicating there was deposition of organic carbon of terrestrial origin in these areas. The oxidation of organic carbon on the open margin declined from ˜11 gCm⁻²y⁻¹ on the shelf to 2 gCm⁻²y⁻¹ at 5000 m water depth, and was dominated by aerobic oxidation. The reactivity of the degradable organic carbon at the time of deposition was <2.5 y⁻¹ on the shelf, and declined to <0.5 y⁻¹ offshore. The burial of refractory organic carbon at the stations along the open margin transects also declined with increasing water depth from ˜5 gCm⁻²y⁻¹ on the shelf to <1 gCm⁻²y⁻¹ at 2000 m depth, whereas the burial of particulate inorganic carbon declined from ˜20 gCm⁻²y⁻¹ to <5 gCm⁻²y⁻¹. A comparison of the estimated total organic carbon deposition and predicted delivery for the shelf suggest that 58 to 165 gCm⁻²y⁻¹ is oxidized in the water column, laterally advected, or focused into one of the canyons.Anaerobic oxidation, denitrification and, therefore, total oxidation of organic carbon was enhanced within the canyon relative to the open margin. Total organic carbon oxidation decreased with water depth from 22 gCm⁻²y⁻¹ at the head of the canyon to 3 gCm⁻²y⁻¹ over its fan. The reactivity of the organic carbon deposited in the canyon was lower than those of the shelf stations, suggesting that the canyon is being enriched in older, laterally advected organic matter. The burial of refractory organic carbon in sediments from the Nazaré Canyon was considerably higher than in the sediments from the open margin; it also decreased with depth from 20 gCm⁻²y⁻¹ at 343 m to ˜2.5 gCm⁻²y⁻¹ at 4298 m water depth. The burial of particulate inorganic carbon was slightly lower than that of refractory organic carbon.The burial of refractory organic carbon and the deposition of degradable organic carbon were both positively correlated with the sedimentation rates for the Iberian Margin, and indicated burial efficiencies were 0.6 to 48%. A single trend for burial efficiency versus sedimentation rate for both the canyon and the open margin indicates that the sedimentation rate was the master variable for the geographical distribution of organic carbon oxidation and carbon preservation on the NW Iberian Margin.     

Variation in curve numbers derived from plot runoff data for New South Wales (Australia)

The curve number method is a simple one parameter (the curve number) rainfall runoff model. While its theoretical underpinning has been questioned it remains a powerful hydrological tool in the absence of detailed data and is therefore used extensively in hydrological models. This study aims to characterize the variation in maximum retention values (S), which underlie curve numbers, for a range of agricultural treatments across a large spatial area in New South Wales (NSW), Australia. The data used for the analysis spans several decades of rainfall runoff observations. A range of different derivation methods result in variation in mean and variance of S. In particular, methods that emphasize the larger storms result in greater S and thus lower runoff. For larger spatial scales, emphasis on larger storms gives more reliable estimates of S. Systematic variation in S arises from variations in treatment, pre‐runoff soil moisture, rainfall depth, and variations in cover. On the basis of the analysis, a table of curve number values for different land uses found in NSW is presented. The resulting distributions of S and curve numbers provide guidance for rainfall runoff modelling studies in the agricultural important areas of NSW. Copyright © 2011 John Wiley & Sons, Ltd.     

Neoichnology and implications for stratigraphy of reworked Upper Oligocene oysters,Antigua, West Indies

The Late Oligocene oyster Hyotissa antiguensis (Brown) is locally common in the Antigua Formation of Hughes Point, eastern Antigua, Lesser Antilles; it was not commonly bored at that time. Its valves and shells are robust, and reworked into the shallow water near-shore environment in Antigua; it could potentially be incorporated into younger rocks. Its neoichnology includes clues that would facilitate identification of these oysters as reworked fossils. The suite of modern borings found in these specimens includes common Caulostrepsis taeniola Clarke, Gastrochaenolites isp. cf. G. turbinatus Kelly and Bromley and Entobia isp., and rare Oichnus simplex Bromley and Rogerella? isp. The latter three taxa are limited to oyster shell substrates. Of the common ichnotaxa, Caulostrepsis and Gastrochaenolites are particularly prominent in limestone clasts and limestone cemented to oyster shells, which would be an indicator of reworking if found in a post-Oligocene lithified deposit. Caulostrepsis and Gastrochaenolites are relatively less common in oyster shells and valves, and in many specimens are seen to terminate against the shell. Entobia is the only common boring limited to the shell substrate. The fidelity of preservation of modern borings is also superior in limestone clasts. This suite of borings is comparable with those found in the Neogene of the Antillean region.     

Building pit dewatering: application of transient analytic elements

Analytic elements are well suited for the design of building pit dewatering. Wells and drains can be modeled accurately by analytic elements, both nearby to determine the pumping level and at some distance to verify the targeted drawdown at the building site and to estimate the consequences in the vicinity. The ability to shift locations of wells or drains easily makes the design process very flexible. The temporary pumping has transient effects, for which transient analytic elements may be used. This is illustrated using the free, open-source, object-oriented analytic element simulator Tim(SL) for the design of a building pit dewatering near a canal. Steady calculations are complemented with transient calculations. Finally, the bandwidths of the results are estimated using linear variance analysis.     

Megamasers: Molecular Diagnostics of the Nuclear Ism

Molecular emissions are powerful tracers of intense heating and star-formation processes in galactic nuclei. In this paper we consider the characteristics of molecular Megamaser emission among the population of (Ultra-) Luminous Infrared Galaxies that are powered by intense star-formation or accretion onto a massive compact object. In addition, we consider the systematic behavior of the line emission of high-density tracer molecules. An evolutionary scenario is presented for ULIRGs that may explain the molecular line ratios observed in the population of FIR galaxies.     

Persistence of Artemisia steppe in the Tangra Yumco Basin,west-central Tibet,China: despite or in consequence of Holocene lake-level changes?

The closed Tangra Yumco Basin underwent the strongest Quaternary lake-level changes so far recorded on the Tibetan Plateau. It was hitherto unknown what effect this had on local Holocene vegetation development. A 3.6-m sediment core from a recessional lake terrace at 4,700 m a.s.l., 160 m above the present lake level of Tangra Yumco, was studied to reconstruct Holocene flooding phases (sedimentology and ostracod analyses), vegetation dynamics and human influence (palynology, charcoal and coprophilous fungi analyses). Peat at the base of the profile proves lake level was below 4,700 m a.s.l. during the Pleistocene/Holocene transition. A deep-lake phase started after 11 cal ka BP, but the ostracod record indicates the level was not higher than ~4,720 m a.s.l. (180 m above present) and decreased gradually after the early Holocene maximum. Additional sediment ages from the basin suggest recession of Tangra Yumco from the coring site after 2.6 cal ka BP, with a shallow local lake persisting at the site until ~1 cal ka BP. The final peat formation indicates drier conditions thereafter. Persistence of Artemisia steppe during the Holocene lake high-stand resembles palynological records from west Tibet that indicate early Holocene aridity, in spite of high lake levels that may have resulted from meltwater input. Yet pollen assemblages indicate humidity closer to that of present potential forest areas near Lhasa, with 500–600 mm annual precipitation. Thus, the early mid-Holocene humidity was sufficient to sustain at least juniper forest, but Artemisia dominance persisted as a consequence of a combination of environmental disturbances such as (1) strong early Holocene climate fluctuations, (2) inundation of habitats suitable for forest, (3) extensive water surfaces that served as barriers to terrestrial diaspore transport from refuge areas, (4) strong erosion that denuded the non-flooded upper slopes and (5) increasing human influence since the late glacial.     

Observations, Effects and Real Time Assessment of the March 11, 2011 Tohoku-oki Tsunami in New Zealand

The great Tohoku-oki earthquake of March 11, 2011 generated a devastating tsunami in the near field as well as substantial far-field effects throughout the Pacific Ocean. In New Zealand, the tsunami was widely observed and instrumentally recorded on an extensive array of coastal tidal gauges and supplemented by current velocity data from two sites. While the tsunami's first arrival was on the morning of March 12 in New Zealand, the strongest effects occurred throughout that afternoon and into the following day. Tsunami effects consisted primarily of rapid changes in water level and associated strong currents that affected numerous bays, harbors, tidal inlets and marine facilities, particularly on the northern and eastern shores of the North Island. The tsunami caused moderate damage and significant overland flooding at one location. The tsunami signal was clearly evident on tide gauge recordings for well over 2 days, clearly illustrating the extended duration of far field tsunami hazards. Real time analysis and modelling of the tsunami through the night of March 11, as the tsunami crossed the Pacific, was used as a basis for escalating the predicted threat level for the northern region of New Zealand. A comparison to recorded data following the tsunami shows that these real time prediction models were accurate despite the coarse near-shore bathymetry used in the assessment, suggesting the efficacy of such techniques for future events from far-field sources.     

Constraining water age dynamics in a south-eastern Australian catchment using an age-ranked storage and stable isotope approach

Improving our knowledge of the travel times of water through catchments is critical for the management and protection of water resources and to improve our understanding of fundamental catchment behaviour. In this study we use the age-ranked storage framework StorAge Selection (SAS) to investigate travel times in the Corin catchment, a headwater catchment in the south-east of Australia covered by native Eucalyptus species. Few studies have applied the SAS framework globally and in energy-intensive areas where catchment losses are heavily in favour of evapotranspiration relative to streamflow. A combination of observed and modelled values of oxygen-18 (δ¹⁸O ), the stable isotope in water, are used to constrain storage selection preferences of streamflow and evapotranspiration and the size of the catchment active storage. The highest performing parameter combinations that could reproduce δ¹⁸O in streamflow were dependent on a strong preference for young water in evapotranspiration, and a mixture of weak young and old water preference in streamflow. The mean travel time of streamflow over the study period 2007–2019, weighted by the flow rate, is limited to within a probable range of 2.81–9.77 years. The size of the active storage, a key parameter in the SAS framework, was poorly identified, and in combination with the isotopic inputs into the model, contributed to the uncertainty of the results. We discuss the implications of the results with respect to the study area, as well as within the context of SAS research globally and identify ways to improve the modelling process.