M and Mg values in igneous rocks: proposed usage and a comment on currently employed Fe2O3 corrections

It is proposed that the ‘M value’ of an igneous rock should be 100Mg/(Mg + ΣFe) and that the ‘Mg value’ should be 100Mg/(Mg + Fe²⁺). A plea is made to standardize any necessary corrections for Fe₂O₃ so that $\text{Fe}{}_2\text{O}{}_3\text{(Fe}{}_2\text{O}{}_3\text{+ FeO)}\text{= 02}$ for basic rocks.     

Li-bearing, disordered Mg-rich tourmaline from a pegmatite-marble contact in the Austroalpine basement units (Styria, Austria)

Pale-blue to pale-green tourmalines from the contact zone of Permian pegmatites to mica schists and marbles from different localities of the Austroalpine basement units (Rappold Complex) in Styria, Austria, are characterized. All these Mg-rich tourmalines have small but significant Li contents, up to 0.29 wt% Li₂O, and can be characterized as dravite, with FeO contents of ?~?0.9–2.7 wt%. Their chemical composition varies from ^X (Na_0.67Ca_0.19?K_0.02?_0.12) ^Y (Mg_1.26Al_0.97Fe²⁺ _0.36Li_0.19Ti⁴⁺ _0.06Zn_0.01?_0.15) ^Z (Al_5.31?Mg_0.69) (BO₃)₃ Si₆O₁₈ ^V (OH)₃? ^W [F_0.66(OH)_0.34], with a?=?15.9220(3), c?=?7.1732(2) Å to ^X (Na_0.67Ca_0.24?K_0.02?_0.07) ^Y (Mg_1.83Al_0.88Fe²⁺ _0.20Li_0.08Zn_0.01Ti⁴⁺ _0.01?_0.09) ^Z (Al_5.25?Mg_0.75) (BO₃)₃ Si₆O₁₈ ^V (OH)₃? ^W [F_0.87(OH)_0.13], with a?=?15.9354(4), c?=?7.1934(4) Å, and they show a significant Al-Mg disorder between the Y and the Z sites (R1?=?0.013–0.015). There is a positive correlation between the Ca content and?<?Y-O?>?distance for all investigated tourmalines (r?≈?1.00), which may reflect short-range order configurations including Ca and Fe²⁺, Mg, and Li. The tourmalines have X_Mg (X_Mg?=?Mg/Mg?+?Fe_total) values in the range 0.84–0.95. The REE patterns show more or less pronounced negative Eu and positive Yb anomalies. In comparison to tourmalines from highly-evolved pegmatites, the tourmaline samples from the border zone of the pegmatites of the Rappold Complex contain relatively low amounts of total REE (~8–36 ppm) and Th (0.1–1.8 ppm) and have low La_N/Yb_N ratios. There is a positive correlation (r?≈?0.91) between MgO of the tourmalines and the MgO contents of the surrounding mica schists. We conclude that the pegmatites formed by anatectic melting of mica schists and paragneisses in Permian time. The tourmalines crystallized from the pegmatitic melt, influenced by the metacarbonate and metapelitic host rocks.     

Noritic dykes of southern West Greenland: early Proterozoic boninitic magmatism

Two major swarms of early Proterozoic (ca. 2.1 Ga) basic dykes occur within the Archaean craton of southern West Greenland. One swarm comprises ophitic and sub-ophitic tholeiitic dolerites, while the other (the BN dyke swarm) constitutes mainly norites in which pyroxenes and olivine are enclosed by plagioclase oikocrysts. The close geochemical similarity between a quenched norite and the coarser-grained varieties indicates that the composition of the latter type has not been significantly modified by crystal accumulation. The BN dykes are geochemically distinctive, most having high MgO (ca. 16%), Cr and Ni contents in conjunction with relatively high SiO₂, light rare-earth (REE) and large ion lithophile (LIL) element concentrations. The texture, mineral chemistry and petrochemistry of the quenched noritic dyke all bear strong resemblances to those features in modern boninitic lavas. The BN dykes also correspond to proposed parental liquids of the Bushveld Complex and other major layered basic igneous intrusions. The two dyke swarms are petrogenetically distinct. The tholeiitic dolerites were derived from a relatively undepleted, primordial mantle while the noritic dykes originated from a metasomatized harzburgitic source. The wide-spread distribution of similar Proterozoic intrusions suggests crustal underplating by harzburgitic mantle on a world-wide scale at this time.     

Deadly oasis:Recurrent annihilation of Cretaceous desert bryophyte colonies;the role of solar,climate and lithospheric forcing

Many oases(wet interdunes)are sedimentary systems characterized by high-frequency water-level oscillations,marked changes in salinity and intense biological activity at their margins.They are considered to be one of the most challenging environments on Earth for ecosystem development.These dynamic,depositional settings are usually unfavourable for fossilization and subsequent preservation of vegetal remains.This paper describes bryophyte(liverwort)assemblages occurring in three successive horizons interpreted to represent(i)recurrent early successional phases of biological soil crust colonization of wet interdune margins or(ii)exceptional preservation of floating or riparian liverworts in oasis pond waters associated with a progressive fall of the interdune water level.The record of in situ colonization surfaces characterized by delicate(e.g.lignin-free)three-dimensional structures represents an exceptional type of preservation herein associated with a rapid variation in phreatic interdune water level and the subsequent establishment of anoxic and reducing conditions.The occurrence of exceptionally preserved liverwort colonies coincides with the sedimentary record of,at least,three seismite levels in the oasis.Data gathered from the site suggests that the water table of the oasis was controlled by a combination of(i)a positive creation of accommodation space due to subsidence associated with movement on syn-sedimentary extensional faults,and(ii)the rise and fall of the oasis water table controlled by the oscillations of the groundwater system due to orbital changes which appear to drive the variability of the climate system.Rising groundwater levels flooded the oasis soil crusts and lead to the exceptional recurrent preservation of liverwort colonies at the oasis margins.Alternatively,considering the hypothesis of floating or riparian liverworts in the oasis pond waters,the fall in the level of the oasis water table placed the floating liverworts in contact with the oasis bottom sediments.This fall in the level of the oasis water table could indicate a cessation of accommodation space by syn-sedimentary extensional faults and/or a regional lowering of the groundwater system level associated with drought periods.Preliminary results indicate that oasis lamination between liverwort colonies records decadal and sub-decadal cyclicity,related with 11-year Schwabe sunspot and sub-decadal NAO cyclicities,conferring for every sedimentary cycle between liverwort colonies a duration of approximately 200 years,that otherwise matches the expected recurrence period for the De Vries cycle of solar activity.     

Historical Trends of Benthic Invertebrate Biodiversity Spanning 182 Years in a Southern New England Estuary

Benthic invertebrates support numerous ecosystem functions and services including shellfish production, energy flow to fishes, and biogeochemical cycles. The decline of marine biodiversity worldwide has raised concerns about effects on ecosystems. To examine biodiversity trends of Narragansett Bay over time, a list was compiled of all benthic invertebrate species collected from the bay since 1834. The list covers 104 studies spanning 182 years and currently holds 1214 unique taxa from 21 phyla, the majority of all animal phyla on Earth. A permuted estimator of number of species suggested there are about 300 more yet to be discovered. Widely varying sampling gear and sieve mesh sizes precluded the use of abundance data. Instead, multidimensional scaling and taxonomic distinctness were used with presence-absence data to examine biodiversity trends. The changes in community composition and decline of benthic biodiversity (p?<?0.01) since 1855 are what would be expected of a community that gradually deteriorated in the face of increasing anthropogenic stressors. Taxonomic distinctness had negative correlations (p?<?0.05) with human population in the watershed, total nitrogen inputs, and inputs of metals. This loss of benthic biodiversity has implications for ecosystem functions and services. As some of the stressors waned in the last two or three decades, following passage of environmental legislation in the 1970s, biodiversity appeared to show a partial recovery. An inventory of species, how it has changed over time, and understanding what caused those changes are important for assessing whether remediation programs are achieving improved water quality and ecosystem health.     

The Sea Empress oil spill (Wales, UK): effects on Common Scoter Melanitta nigra in Carmarthen Bay and status ten years later

Carmarthen Bay, UK, regularly supports internationally important numbers (>16,000) of non-breeding Common Scoters Melanitta nigra. The spill of 72,000 tonnes of crude oil from the Sea Empress in 1996 affected birds both through direct mortality and likely pollution of key food resources. Numbers were greatly reduced following the spill, whilst changes in the distribution of birds within Carmarthen Bay suggested that potentially sub-optimal foraging zones were used. However, ten years after the incident, numbers of Common Scoter were no different to those recorded immediately before the spill. Compared to some other spills, rapid revival is evident. Numbers increased to pre-spill levels within three winters and distributional changes suggested a concurrent return to previously contaminated feeding areas, implying that the ecosystem had regenerated sufficiently to support its top predator. The importance of prolonged, standardised monitoring of bird numbers and distribution as indicators of ecological recovery from environmental damage is emphasised.     

Field observations of nearshore bar formation

The formation of an inner nearshore bar was observed during a high‐energy event at the sandy beach of Vejers, Denmark. The bar accreted in situ during surf zone conditions and the growth of the bar was associated with the development of a trough landward of the bar. Measurements of hydrodynamics and sediment fluxes were obtained from electromagnetic current meters and optical backscatter sensors. These process measurements showed that a divergence in sediment transport occurred at the location of the developing trough, and observed gradients in cross‐shore net sediment flux were consistent with the morphological development. The main cause for the flux gradients were cross‐shore gradients in offshore‐directed mean current (undertow) speed which depended upon local relative wave height and local bed slope. Copyright © 2007 John Wiley & Sons, Ltd.     

Use of point scale models to improve conceptual understanding in complex aquifers: An example from a sandstone aquifer in the Eden valley,Cumbria, UK

Understanding catchment functioning is increasingly important to enable water resources to be quantified and used sustainably, flood risk to be minimized, as well as to protect the system from degradation by pollution. Developing conceptual understanding of groundwater systems and their encapsulation in models is an important part of this understanding, but they are resource intensive to create and calibrate. The relative lack of data or the particular complexity of a groundwater system can prevent the development of a satisfactory conceptual understanding of the hydrological behaviour, which can be used to construct an adequate distributed model. A time series of daily groundwater levels from the Permo-Triassic sandstones situated in the River Eden Valley, Cumbria, UK have been analysed. These hydrographs show a range of behaviours and therefore have previously been studied using statistical and time series analysis techniques. This paper describes the application of AquiMOD, impulse response function (IRF) and combined AquiMOD-IRF methods to characterize the daily groundwater hydrographs. The best approach for each characteristic type of response has been determined and related to the geological and hydrogeological framework found at each borehole location. It is clear that AquiMOD, IRF and a combination of AquiMOD with IRF can be deployed to reproduce hydrograph responses in a range of hydrogeological settings. Importantly the choice of different techniques demonstrates the influence of differing processes and hydrogeological settings. Further they can distinguish the influences of differing hydrogeological environments and the impacts these have on the groundwater flow processes. They can be used, as shown in this paper, in a staged approach to help develop reliable and comprehensive conceptual models of groundwater flow. This can then be used as a solid basis for the development of distributed models, particularly as the latter are resource expensive to build and to calibrate effectively. This approach of using simple models and techniques first identifies specific aspects of catchment functioning, for example influence of the river, that can be later tested in a distributed model.     

Correcting bias in rainfall inputs to a semi-distributed hydrological model using downstream flow simulation errors

The focus of this study is on bias correcting semi-distributed rainfall inputs into a hydrological model applied in the Okavango River basin in southern Africa, where there are very few local observations and heavy reliance is placed on global rainfall datasets. While the hydrological model, before rainfall bias correction, is able to represent the broad characteristics of the sub-basin streamflow responses, as demonstrated by good agreement between observed and simulated flow duration curves, there are many years where the annual volumes are over- or underestimated. The long records of observed flow at downstream stations are successfully used to bias correct the rainfall inputs to the upstream sub-basins using an analysis of their individual contributions to downstream flow and their annual rainfall–runoff response ratios. The results show improved simulations for the relatively shorter observation periods at the upstream gauging stations.     

Precipitation stable isotope variability and subcloud evaporation processes in a semi‐arid region

The stable isotopic (²H/¹H and ¹⁸O/¹⁶O) composition of precipitation has been used for a variety of hydrological and paleoclimate studies, a starting point for which is the behaviour of stable isotopes in modern precipitation. To this end, daily precipitation samples were collected over a 7‐year period (2008–2014) at a semi‐arid site located at the Macquarie Marshes, New South Wales (Australia). The samples were analysed for stable isotope composition, and factors affecting the isotopic variability were investigated. The best correlation between δ ¹⁸O of precipitation was with local surface relative humidity. The reduced major axis precipitation weighted local meteoric water line was δ ²H = 7.20 δ ¹⁸O + 9.1. The lower slope and intercept (when compared with the Global Meteoric Water Line) are typical for a warm dry climate, where subcloud evaporation of raindrops is experienced. A previously published model to estimate the degree of subcloud evaporation and the subsequent isotopic modification of raindrops was enhanced to include the vertical temperature and humidity profile. The modelled results for raindrops of 1.0 mm radius showed that on average, the measured D‐excess (=δ ²H ? 8 δ ¹⁸O) was 19.8‰ lower than that at the base of the cloud, and 18% of the moisture was evaporated before ground level (smaller effects were modelled for larger raindrops). After estimating the isotopic signature at the base of the cloud, a number of data points still plotted below the global meteoric water line, suggesting that some of the moisture was sourced from previously evaporated water. Back trajectory analysis estimated that 38% of the moisture was sourced over land. Precipitation samples for which a larger proportion of the moisture was sourced over land were ¹⁸O and ²H‐enriched in comparison to samples for which the majority of the moisture was sourced over the ocean. The most common weather systems resulting in precipitation were inland trough systems; however, only East Coast Lows contributed to a significant difference in the isotopic values. Copyright © 2016 Australian Nuclear Science and Technology Organisation. Hydrological Processes. © 2016 John Wiley & Sons, Ltd.