Volume diffusion of Ytterbium in YAG: thin-film experiments and combined TEM–RBS analysis

In this study, we address volume diffusion of ytterbium in yttrium aluminum garnet (YAG) using thin-film single crystal diffusion couples. We employ analytical transmission electron microscopy (ATEM) as a tool for combined microstructural and microchemical analysis and compare the results to Rutherford backscattering (RBS) analysis. Given the high spatial resolution of the method, we focus on microstructural changes of the thin-film diffusant source during the diffusion anneal. We evaluate the potential influence of the associated changes in its transport properties on the evolution of concentration profiles in the single crystal substrate. This approach allows us to test the reliability of determination of volume diffusion coefficients from thin-film diffusion experiments. We found that for the chosen experimental setting, the influence of thin-film re-crystallization is small when compared with the experimental uncertainty and good estimates for the volume diffusion coefficients of Yb in YAG can be obtained using standard assumptions. Both Yb-concentration profiles analyzed with ATEM and with RBS give similar results. At 1,450°C and 1 bar, we infer log D _Yb (m²/s) values of −19.37 ± 0.07 (TEM) and −19.84 ± 0.02 (RBS). Although the change in thin-film transport properties associated with successive crystallization during the diffusion anneal does not play a major role for our experimental setup, this effect cannot generally be ignored.     

Über eine durch Raphidonema spiculiforme nov. spec. verursachte Wasserblüte und ihre experimentelle Untersuchung

Ohne Zusammenfassung mit 43 Abbildungen     

Kurzer Bericht über die sedimentpetrographische Untersuchung zweier Lotkerne der Albatross-Expedition

Ohne Zusammenfassung     

The effects of stock size and environmental variability on Cape hake recruitment in Namibia: an unsolved puzzle (a comment on Kainge et al. 2013)

Measuring and forecasting recruitment are central to the understanding and management of fish stocks. Kainge et al. (2013) studied the effect of spawning stock size and environmental fluctuations on the recruitment levels of the Cape hake Merluccius capensis in Namibia. However, their study contains some flaws that undermine the conclusion that Cape hake recruitment is under the influence of upwelling in summer. Until those flaws are properly addressed, this conclusion, in our view, should be treated with caution.     

Molecular identification of ascaridoid nematodes from the deep-sea onion-eye grenadier (Macrourus berglax) from the East Greenland Sea

Macrourus berglax from the East Greenland Sea was studied for the presence of ascaridoid nematodes in 2001, 2002 and 2003. The fishes were collected between 278 and 413 m water depth using a benthopelagic net. Based on the amplification of the internal transcribed spacer ITS-1, 5.8S, ITS-2 and flanking sequences (=ITS+), three ascaridoid nematode species were identified. The prevalence of infestation during the 3 years ranged from 42.9% to 62.9% and 22.9% to 40.0% for the anisakids Anisakis simplex (s.s.) and Pseudoterranova decipiens (s.s.), respectively, and from 28.6% to 60.0% for the raphidascarid Hysterothylacium aduncum. A total of 18 specimens, two of each species and examination year, revealed no sibling species, suggesting a limited distribution of other ascaridoid siblings into the deep sea. The ITS-1, 5.8S and ITS-2 sequences of A. simplex (s.s.) from the East Greenland Sea did not differ from previously published sequence data (GenBank) from other regions in the Atlantic and Pacific oceans. The sequences of P. decipiens (s.s.) corresponded most closely to those of specimens from Richardson Bay, western Pacific, and differed in four positions (0.5%). They corresponded least to those of specimens from Japan (1.5%). The sequence data for H. aduncum differed in two positions in the ITS-1 (0.2%) and three positions in the ITS-2 (0.3%) from sequences from Japan. A high genetic similarity between the regions can be explained by (a) extensive final host migration in the case of A. simplex (s.s.), (b) an overlapping distribution of final host populations along the continental shelves for P. decipiens (s.s.) and (c) a low host specificity and large population size in the intermediate and final hosts for H. aduncum. The occurrence of the identified species in the macrourid fish underlines the potential of cosmopolitan ascaridoid nematodes to distribute not only horizontally but also vertically in the deep sea.     

Voltammetric estimation of iron(III) thermodynamic stability constants for catecholate siderophores isolated from marine bacteria and cyanobacteria

Thermodynamic stability constants have been estimated for the complexation of iron(III) with catecholate-type siderophores isolated from the marine bacterium Alteromonas luteoviolacea and from the marine cyanobacterium Synechococcus sp. PCC 7002. Stability constants were determined utilizing the “chelate scale” of Taylor et al. (1994). The scale is based upon a linear relationship between the reduction potentials and the pH-independent thermodynamic stability constants for known iron(III) complexes. Log K values for the alterobactin B ferric iron complex are 43.6 ± 1.5 at pH 8.2 and 37.6 ± 1.2 at pH 6, consistent with a shift from bis-catecholate to monosalicylate/monocatecholate iron coordination with decreasing pH. Synechococcus isolates PCC 7002 Nos. 1 and 3 formed iron(III) complexes with stability constants of approximately 38.1 ± 1.2 and 42.3 ± 1.5, respectively. The binding strengths of the iron(III) complexes examined in this study are quite high, suggesting that catecholate siderophores may play a role in the solubilization and biological uptake of iron in the marine environment.     

Quantitative solar spectroscopy

Quantitative solar spectroscopy must be based on calibrated instrumentation. The basic requirement of a calibration, i.e., a comparison between the instrument under test and a primary laboratory standard through appropriate procedures, will be briefly reviewed, and the application to modern space instruments will be illustrated. Quantitative measurements of spectral radiances with high spectral and spatial resolutions as well as spectral irradiances yield detailed information on temperatures, electron densities, bulk and turbulent motions, element abundances of plasma structures in various regions of the solar atmosphere – from the photosphere to the outer corona and the solar wind. The particular requirements for helioseismology and magnetic‐field observations will not be covered in any depth in this review. Calibration by a laboratory standard is necessary, but not sufficient, because an adequate radiometric stability can only be achieved together with a stringent cleanliness concept that rules out a contamination of the optical system and the detectors as much as possible. In addition, there is a need for calibration monitoring through inter‐calibration and other means (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Euv Spectroscopy of the Sunspot Region Noaa 7981 Using Soho – II. Velocities and Line Profiles

We have studied the dynamics in the sunspot transition region between the chromosphere and the corona and investigated the extension of the flow field into the corona. Based on EUV spectra of a medium size sunspot and its surroundings, NOAA 7981, observed with CDS and SUMER on SOHO, we derive line-of-sight velocities and study the line profiles for a series of emission lines.The flow field in the low corona is found to differ markedly from that in the transition region. In the transition region the relative line-of-sight velocity shows an upflow in the umbra and relatively large areas with downflow that cover part of the penumbra. The spatial extent of these areas with upflow and downflow increases with increasing temperature in the transition region, but the whole flow field changes character as the temperature increases from the upper transition region to the low corona. Based on a calibration of the SUMER wavelength scale we find that the entire sunspot transition zone appears to be moving downwards towards the chromosphere. The relation between this finding and the general tendency for transition-region lines to show a net red shift is discussed.Several of the transition-region spectral line profiles are observed to show two line components with Gaussian shape and line-of-sight velocities that differ markedly. Several of the line profiles that are composed of two spectral line components occur close to the dividing line between up- and downflow. A discussion of this observation is presented. In small regions with spatial extent of a few arc sec we detect enhanced continuum emission underlying explosive events. The similarities between explosive events with continuum emission and the moustaches observed in H close to sunspots are so striking that we are tempted to introduce the notation transition-region moustaches.     

The SUMER Data in the SOHO Archive

We have released an archive of all observational data of the VUV spectrometer Solar Ultraviolet Measurements of Emitted Radiation (SUMER) on SOHO that have been acquired until now. The operational phase started with ‘first light’ observations on 27 January 1996 and will end in 2014. Future data will be added to the archive when they become available. The archive consists of a set of raw data (Level 0) and a set of data that are processed and calibrated to the best knowledge we have today (Level 1). This communication describes step by step the data acquisition and processing that has been applied in an automated manner to build the archive. It summarizes the expertise and insights into the scientific use of SUMER spectra that has accumulated over the years. It also indicates possibilities for further enhancement of the data quality. With this article we intend to convey our own understanding of the instrument performance to the scientific community and to introduce the new, standard FITS-format database.     

Multiple-Thread Model of a Prominence Observed by Sumer and eit on Soho

A quiescent polar crown prominence was observed at Meudon in Hα and Ca ii lines, and by EIT and SUMER on board SOHO in UV lines from 9 to 10 March 1996. SUMER observed the prominence continuously in a scanning mode between 21:40 UT on 9 March, and 18:13 UT on 10 March, in the nitrogen line N v (λ1238) with a 1 arc sec² resolution. Altogether 190 prominence images (121×108 pixels) were obtained. These are presented in a movie. The prominence is highly dynamic. Large-scale features, such as mixed loop systems and dark cavities are changing on time scales of a few hours. Filamentary structure is evident and is changing within a few frames of the movie. A lifetime of 20–25 min for the fine structure has been found by the autocorrelation method. We have statistically analysed the three moments of the N v line in the prominence: line intensity, Doppler shift and linewidth, in the context of a multiple-thread model. We find that the data are consistent with a model where the prominence is assumed to be an ensemble of small threads. In the brightest parts of the prominence it is possible that there are many unresolved threads (15–20) along the line of sight with diameters smaller than a few hundred kilometers. The filling factor is probably very small and in that case the structures occupy only a fraction of the volume. Supplementary material to this paper is available in electronic form at http://dx.doi.org/10.1023/A:1005151015043