Ein Beitrag zum Problem der Tiefseesande im westlichen Teil des äquatorialen Atlantiks

Zusammenfassung Es wurden in vorliegender Arbeit die Ergebnisse der sedimentpetrographischen Untersuchung von 5 Albatross -Lotkernen dargestellt, die aus dem westlichen äquatorialen Atlantik stammen und in denen zahlreiche Sandschichten auftreten. Die mineralogische Zusammensetzung des Sedimentmaterials ist allein von seiner kornmäßigen Zusammensetzung abhängig. Gleiche Korngrößenfraktionen sind gleich zusammengesetzt. Der Schwermineralgehalt der untersuchten Proben war ebenfalls qualitativ und quantitativ derselbe. Die Proben aus der Amazonasmündung enthielten eine andere Schwermineralverteilung.In den drei am meisten südöstlich gelegenen Lotkernen tritt je eine Schicht auf, die aus sehr gleichförmigem roten Ton-Blauschlick besteht, der von einer foraminiferenreichen Sandschicht unterlagert wird. In dieser Sandschicht wiesPhleger benthonische Flachwasserforaminiferen nach. Es wird angenommen, daß es sich in allen drei Lotkernen um dieselbe Schicht handelt. Aus der Mächhtigkeitsänderung der Tonschicht und der Änderung der Korngröße des darunterlagernden Sandes wird geschlossen, daß Sand und Ton durch Suspensionsströme transportiert wurden. Als Herkunftsgebiet des Sandmaterials wird der südamerikanische Kontinent angenommen.Herrn Professor Dr.Carl W. Correns zum 60. Geburtstag gewidmet.     

Melting and subsolidus reactions in the system K2O-CaO-Al2O3-SiO2-H2O

Beginning of melting and subsolidus relationships in the system K₂O-CaO-Al₂O₃-SiO₂-H₂O have been experimentally investigated at pressures up to 20 kbars. The equilibria discussed involve the phases anorthite, sanidine, zoisite, muscovite, quartz, kyanite, gas, and melt and two invariant points: Point [Ky] with the phases An, Or, Zo, Ms, Qz, Vapor, and Melt; point [Or] with An, Zo, Ms, Ky, Qz, Vapor, and Melt.The invariant point [Ky] at 675° C and 8.7 kbars marks the lowest solidus temperature of the system investigated. At pressures above this point the hydrated phases zoisite and muscovite are liquidus phases and the solidus temperatures increase with increasing pressure. At 20 kbars beginning of melting occurs at 740 °C. The solidus temperatures of the quinary system K₂O-CaO-Al₂O₃-SiO₂-H₂O are almost 60° C (at 20 kbars) and 170° C (at 2kbars) below those of the limiting quaternary system CaO-Al₂O₃-SiO₂-H₂O.The maximum water pressure at which anorthite is stable is lowered from 14 to 8.7 kbars in the presence of sanidine. The stability limits of anorthite+ vapor and anorthite+sanidine+vapor at temperatures below 700° C are almost parallel and do not intersect. In the wide temperature — pressure range at pressures above the reaction An+Or+Vapor = Zo+Ms+Qz and temperatures below the melting curve of Zo+Ms+Ky+Qz+Vapor, the feldspar assemblage anorthite+sanidine is replaced by the hydrated phases zoisite and muscovite plus quartz. CaO-Al₂O₃-SiO₂-H₂O. Knowledge of the melting relationships involving the minerals zoisite and muscovite contributes to our understanding of the melting processes occuring in the deeper parts of the crust. Beginning of melting in granites and granodiorites depends on the composition of plagioclase. The solidus temperatures of all granites and granodiorites containing plagioclases of intermediate composition are higher than those of the Ca-free alkali feldspar granite system and below those of the Na-free system discussed in this paper.The investigated system also provides information about the width of the P-T field in which zoisite can be stable together with an Al₂SiO₅ polymorph plus quartz and in which zoisite plus muscovite and quartz can be formed at the expense of anorthite and potassium feldspar. Addition of sodium will shift the boundaries of these fields to higher pressures (at given temperatures), because the pressure stability of albite is almost 10kbars above that of anorthite. Assemblages with zoisite+muscovite or zoisite+kyanite are often considered to be products of secondary or retrograde reactions. The P-T range in which hydration of granitic compositions may occur in nature is of special interest. The present paper documents the highest temperatures at which this hydration can occur in the earth's crust.     

1980 volcanic eruption reported on Marion Island

The first volcanic eruption in the recorded history of Marion Island (46°54′S, 37°45′E) occurred between February and October 1980 at a locality on the west coast. It was a minor event that passed unnoticed at the meteorological station 20 km distant. The discovery was made on November 4, by five expedition members who walked around the island. When examined in more detail on November 25, the lava was still warm in places and numerous fumaroles existed. Three blocky flows emanated from two adjacent cinder cones built-up on a pre-existing phreatomagmatic tuff cone known as Kaalkoppie. The largest flow covers an area of about seven hectares and a further two hectares have been inundated by ash. Another flow poured seawards to form a new beach front, blocking access to what was previously the largest elephant seal wallowing ground on the island. No earth tremors were felt and the activity seems to have ended for the time being.     

Markierungsversuche an Bach- und Regenbogenforellen im Bodensee als Beitrag zur systematischen Eingliederung von Forellen

Nearly 900 tagged trouts (brown and rainbow trouts) have been exposed at a distance of 300 m and 1,5–4,5 km from the shore. In the first case the recapture was more favour-able. According to the series 6 to 20% brown trouts and only 1% rainbow trouts were recaptured. The greater part has been caught in the lake; only from October to May the reports came from the rivers. Brown and rainbow trouts lost in the lake their reddish spots or the rainbrowstripe and became silver. The growth is nearly as quick as in the lake trout. After a critical review of our own results and those found in literature we came to the conclusion that there are no morphological differences between brown and lake trouts. It may be that there are genetically fixed differences in the biological-physiological behaviour. But even in this case a classification inSalmo trutta morpha lacustris andS. t. m. fario could not be justifiable—for practical reasons only-because, independantly, in the single lakes the development of lake trouts from populations of brown trouts has happened polyphyletically. Also, for genetically different populations, normally no classifications in subspecies are made. Probably, the difference in the colour and growth-easily striking the eye-misdirects to assume the form ‘morpha lacustris’.     

Aufenthalt der Fische im Bereich von Stauwehren

Ohne Zusammenfassung Der Deutschen Forschungsgemeinschaft sei für die Unterstützung der Arbeit gedankt.     

Oxidative stress in the mussel Mytella guyanensis from polluted mangroves on Santa Catarina Island,Brazil

Digestive glands of the mangrove mussel Mytella guyanensis, collected at one non-polluted site (site 1) and two polluted sites (sites 2 and 3), were analysed for different antioxidant defenses, lipid peroxidation and DNA damage. Thiobarbituric acid-reactive substance (TBARS) and 8-oxo-7,8-dihydro-2'-deoxyguanosine levels were enhanced at the polluted sites. With the exception of superoxide dismutase, the activities of catalase and glutathione peroxidase were also higher at the polluted sites. Greater increases were observed in glutathione reductase, glutathione S-transferase and etoxyresorufine-O-deethylase activities at the polluted sites. Conversely, reduced glutathione content was higher at the control site. Trace metal contents in mussels collected at polluted sites were increased compared to the control site, and there were strong positive correlations between TBARS and Cu and Pb contents. M. guyanensis is routinely exposed to an oxidative stress condition at both polluted sites, and considering xenobiotic bioaccumulation in bivalve molluscs, the mangrove mussel represents an excellent bioindicator for environmental monitoring studies.     

The behaviour of boron in a peraluminous granite-pegmatite system and associated hydrothermal solutions: a melt and fluid-inclusion study

Detailed analyses of melt and fluid inclusions combined with an electron-microprobe survey of boron-bearing minerals reveal the evolution of boron in a highly evolved peraluminous granite-pegmatite complex and the associated high- and medium-temperature ore-forming hydrothermal fluids (Ehrenfriedersdorf, Erzgebirge, Germany). Melt inclusions in granite represent embryonic pegmatite-forming melts containing about 10 wt% H₂O and 1.8 wt% B₂O₃. These melts are also enriched in F, P, and other incompatible elements such as Be, Sn, Rb, and Cs. Ongoing differentiation and volatile enrichment drove the system into a solvus, where two pegmatite-forming melts coexisted. The critical point is at about 712 °C, 100 MPa, 20 wt% H₂O and 4.1 wt% B₂O₃. Cooling and concomitant fractional crystallisation from 700 to 500 °C induced development of two conjugate melts, an H₂O-poor (A-melt) and an H₂O-rich melt (B-melt) along the opening solvus. Boron is a major element in both melts and is preferentially partitioned into the H₂O-rich melt. Temperature-dependent distribution coefficients D_boron^{B - melt/A - melt} D_{{\rm{boron}}}^{{\rm{B - melt/A - melt}}} are 1.3 at 650 °C, 1.5 at 600 °C, and 1.8 at 500 °C. In both melts, boron concentrations decreased during cooling because of exsolution of a boron-rich hypersaline brine throughout the pegmatitic stage. Boromuscovite containing up to 8.5 wt% was another sink for boron at this stage. The end of the melt-dominated pegmatitic stage was attained at a solidus temperature of around 490 °C. Fluid inclusions of the hydrothermal stage reveal trapping temperatures of 480 to 370 °C, along with varying densities and highly variable B₂O₃ contents ranging from 0.20 to 2.94 wt%. A boiling system evolved, indicating a complex interplay between closed- and open-system behaviour. Pressure switched from lithostatic to hydrostatic and back, generating hydrothermal convection cells where meteoric waters were introduced and mixed with magmatic fluids. Boron-rich solutions originated from magmatic fluids, whereas boron-depleted fluids were mainly of meteoric origin. This highlights the potential of boron for discriminating fluids of different origin. Tin is continuously enriched during the evolution because tin and boron are cross-linked by formation of boron-, fluorine- and tin-fluorine-bearing complexes and is finally deposited within quartz-cassiterite veins during the transition from closed- to open-system behaviour. Boron does not only trace the complex evolution of the Ehrenfriedersdorf complex but exerts, together with H₂O, F and P, an important control on the physical and chemical properties of pegmatite-forming melts, and particularly on the formation of a two-melt solvus at low pressure. We discuss this with respect to experimental results on H₂O solubility and the critical behaviour of the haplogranite-water system which contained variable concentrations of volatiles.     

Partial fusion of basic granulites at 5 to 15 kbar: implications for the origin of TTG magmas

Partial fusion experiments with basic granulites (S6, S37) believed to represent the lower crust beneath the Eifel region (Germany) were performed at pressures from 5 to 15 kbar. Water-undersaturated experiments were carried out in the presence of 1 wt% H₂O plus 2.44 or 0.81 wt% CO₂ equivalent to mole fractions of H₂O/(H₂O + CO₂) of 0.5 and 0.75, respectively, of the volatile components added. At temperatures from 850 to 1100 °C the weight proportions of melt range from 7 to 30 %. Melt compositions change from trondhjemitic over tonalitic to dioritic with increasing degree of partial melting. Crystalline residua are plagioclase/pyroxene dominated at 5 kbar to garnet/pyroxene dominated at 15␣kbar. Dehydration melting was studied in granulite S35 similar in composition to S6. The magmatic precursors of the granulite xenoliths used in this study had geochemical characteristics of cumulate gabbro (metagabbro S37) and evolved melts (metabasalts S6, S35), respectively. Melts from granulite S37 match the major element compositions of natural trondhjemites and tonalites. At 5 kbar, their Al₂O₃ is relatively low, similar to tonalites from ophiolites. At 15 kbar, Al₂O₃ in the melts is high due to the near absence of plagioclase in the crystalline residua. The Al₂O₃ concentrations in 15 kbar melts from S6 (˜20 wt%) are higher than in natural tonalites. Depth constraints on the formation of tonalitic magmas in the continental crust are provided by REE (rare earth element) patterns of the synthetic melts calculated from the known REE abundances in metagabbro S37 and metabasalt S6 assuming batch melting and using partition coefficients from the literature. The REE patterns of tonalites from active continental margins and Archean trondhjemite-tonalite-granodiorite␣associations low in REE with La_N (chondrite normalised) from 10 to 30 and Yb_N from 1 to 2 are reproduced at pressures of 10 and 12.5 kbar from metagabbro S37 which displays a slightly L(light)REE enriched pattern with La_N = 8 and Yb_N = 3. Natural tonalites with La_N from 30 to 100 require a source richer in REE than granulite S37. At 15 kbar, H(heavy)REE_N in melts from granulite S37 are depressed below the level observed in natural tonalites due to the high proportion of garnet (>30 wt%) in the residue. Melts from metabasalt S6 (enriched in REE with La_N = 38 and Yb_N = 16) do not match the REE characteristics of natural tonalites under any conditions. Received: 1 July 1994 / Accepted: 11 September 1996